Regulated Li Solvation via Competitive Coordination Mechanism of Organic Cations for High Voltage and Fast Charging Lithium Metal Batteries.

Li solvation exerted a decisive effect on electrolyte physicochemical properties. Suitable tuning for Li solvation enabled batteries to achieve unexpected performance. Here, we introduced inert organic cations to compete with Li for combining electrolyte molecules to modulate Li coordination in the electrolyte.

Glycerol monolaurate improves intestinal morphology and antioxidant status by suppressing inflammatory responses and nuclear factor kappa-B signaling in lipopolysaccharide-exposed chicken embryos.

Medium-chain fatty acids and their derivatives are natural ingredients that support immunological functions in animals. The effects of glycerol monolaurate (GML) on intestinal innate immunity and associated molecular mechanisms were investigated using a chicken embryo model. Sixty-four Arbor Acres broiler embryos were randomly allocated into four groups.

Like-Charge PISA: Polymerization-Induced Like-Charge Electrostatic Self-Assembly.

We report the use of l-aspartic acid chiral ionic hydrogen bonds to drive liquid-liquid phase separation (LLPS) and precision two-dimensional electrostatic self-assembly in photo-RAFT aqueous polymerization-induced self-assembly (photo-PISA). Homopolymerization can yield salt-resistant, 3 nm ultrafine fibril-structured 5 nm ultrathin lamellae LLPS, a left-to-right-handed chirality transition, and a droplets-to-lamellae transition. Like-charge block copolymerization leads to supercharged yet identical fibril-structured ultrathin lamellae, also, LLPS, the left-to-right chirality transition and the droplets-to-lamellae transition.

Improved Gravitational Search Algorithm Based on Adaptive Strategies.

The gravitational search algorithm is a global optimization algorithm that has the advantages of a swarm intelligence algorithm. Compared with traditional algorithms, the performance in terms of global search and convergence is relatively good, but the solution is not always accurate, and the algorithm has difficulty jumping out of locally optimal solutions. In view of these shortcomings, an improved gravitational search algorithm based on an adaptive strategy is proposed.

A Nonlinear Finite-Time Robust Differential Game Guidance Law.

In this paper, a robust differential game guidance law is proposed for the nonlinear zero-sum system with unknown dynamics and external disturbances. First, the continuous-time nonlinear zero-sum differential game problem is transformed into solving the nonlinear Hamilton-Jacobi-Isaacs equation, a time-varying cost function is developed to reflect the fixed terminal time, and the robust guidance law is developed to compensate for the external disturbance. Then, a novel neural network identifier is designed to approximate the unknown nonlinear dynamics with online weight tuning.

Effects of intracerebroventricular injection of corticotrophin releasing factor on the gene expression of ghrelin and corticotrophin releasing factor receptors in broiler chickens.

Objective: This study aimed to investigate the effects of corticotropin-releasing factor (CRF) on the feed intake of broiler chickens and explore its influencing mechanism.

Methods: The study included two trials. In trial 1, 32 male broiler chickens (Arbor Acres, Gallus gallus domesticus) were given ventricle buried tubes, and they were allowed to recover for 3 days.

Two-dimensional polymerization-induced electrostatic self-assembly a C12-polyelectrolyte lamellar template.

We present a template strategy for precision synthesis of "complex coacervates-in-dodecyl atmosphere" ultrathin lamellae possessing exceptional shape-preservation and charge-tolerance properties.

Probiotic Effects of DSM5749 on Growth Performance and Intestinal Microecological Balance of Laying Hens.

This study was conducted to investigate the effects of DSM5749 on the production performance and intestinal health in laying hens. A total of 32-week-old laying hens (Hyline Brown) were randomly assigned to two dietary groups (10 replicates of 27 laying hens), namely, basal diet and basal diet complemented with 200 g/t (3.2 × 10 CFU/kg).

Nanostructured Multiphase Condensation of Complex Coacervates in Polymerization-Induced Electrostatic Self-Assembly.

We present the nanostructured multiphase condensation of complex coacervates in the dynamic evolving aqueous medium of liquid-liquid phase separation driven polymerization-induced electrostatic self-assembly (LLPS-PIESA). We show that the parent droplets evolve into nanostructured coacervate-in-coacervate multiphase condensates with diverse morphologies, such as dandelions, worms, lamellae, vesicles, and vesicle polymers, upon the kinetically dictated recruitment of anionic free chains, cationic growing chains, and nascent clusters from the dynamic evolving aqueous medium of LLPS-PIESA, under the interplay of electrostatic and arginine-like salt bridge interactions.

Liquid-Phase Condensation via Macromolecular Crowding in Polymerization-Induced Electrostatic Self-Assembly.

Macromolecular crowding plays a key role in liquid-phase condensation of proteins and membraneless organelles yet is largely unexplored for artificial liquid materials. Herein, we present a strategy for direct access to multiphase liquid condensates with individual charged/neutral subdomains, by introducing macromolecular crowding to our previous protocol of liquid-liquid phase-separation-driven polymerization-induced electrostatic self-assembly (LLPS-PIESA). We show that reversible addition fragmentation chain transfer (RAFT) aqueous dispersion photo-copolymerization of a charged monomer with a specific neutral monomer, in the presence of a polar macrochain transfer agent (CTA) and an oppositely charged polyion, can induce self-sorting and macromolecular crowding.

A spread model of COVID-19 with some strict anti-epidemic measures.

In the absence of specific drugs and vaccines, the best way to control the spread of COVID-19 is to adopt and diligently implement effective and strict anti-epidemic measures. In this paper, a mathematical spread model is proposed based on strict epidemic prevention measures and the known spreading characteristics of COVID-19. The equilibria (disease-free equilibrium and endemic equilibrium) and the basic regenerative number of the model are analyzed.

The impact of vaccination on the spread of COVID-19: Studying by a mathematical model.

The global spread of COVID-19 has not been effectively controlled, posing a huge threat to public health and the development of the global economy. Currently, a number of vaccines have been approved for use and vaccination campaigns have already started in several countries. This paper designs a mathematical model considering the impact of vaccination to study the spread dynamics of COVID-19.

Attitude Estimation Algorithm of Portable Mobile Robot Based on Complementary Filter.

In robot inertial navigation systems, to deal with the problems of drift and noise in the gyroscope and accelerometer and the high computational cost when using extended Kalman filter (EKF) and particle filter (PF), a complementary filtering algorithm is utilized. By combining the Inertial Measurement Unit (IMU) multi-sensor signals, the attitude data are corrected, and the high-precision attitude angles are obtained. In this paper, the quaternion algorithm is used to describe the attitude motion, and the process of attitude estimation is analyzed in detail.

Effects of dietary corticosterone on the central adenosine monophosphate-activated protein kinase (AMPK) signaling pathway in broiler chickens.

Glucocorticoids (GCs) induce the activation of the central adenosine 5'-monophosphate-activated protein kinase (AMPK) signaling pathway in birds. In this study, we aimed to investigate the effects of corticosterone (CORT) supplemented in diet on the central AMPK signaling pathway in broilers. The average daily gain was reduced by CORT treatment, and the average daily feed intake remained unchanged.

Polymerization-Induced Hierarchical Electrostatic Self-Assembly: Scalable Synthesis of Multicompartment Polyion Complex Micelles and Their Monolayer Colloidal Nanosheets and Nanocages.

Scalable synthesis of multicompartment polyion complex (PIC) systems has been achieved via visible light-initiated RAFT polymerization of cationic monomer in the presence of anionic diblock copolymer micelles in water at 25 °C. This polymerization-induced hierarchical electrostatic self-assembly (hierarchical PIESA) implements structural hierarchy via programmable self-assembly to form multicompartment PIC micelles and their monolayer colloidal nanosheets and nanocages. The anionic micelles play decisive roles in such a hierarchical PIESA to access biologically relevant yet otherwise inaccessible multicompartment PIC systems.

Noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles via polymerization-induced electrostatic self-assembly using an arginine-like monomer.

The noncovalent structural locking of thermoresponsive polyion complex micelles, nanowires, and vesicles can be implemented via hydrogen bonding assisted polyion complexation through polymerization-induced electrostatic self-assembly (PIESA) using an arginine-like cationic monomer.

Synthesis and Solution Self-Assembly Properties of Cyclic Rod-Coil Diblock Copolymers.

Typical cyclic diblock polymers are synthesized from their linear precursors via the ring-closure strategy in dilute conditions. Here we demonstrate a pseudo-high-dilution condition strategy for the efficient synthesis of cyclic rod-coil diblock copolymer from its linear precursor in selective solvents. The critical association concentration (CAC) of linear precursor is used for the control of unimer concentration during cyclization, while high copolymer synthetic concentrations are achieved via the dynamic equilibrium between unimers and micelles.

Polymerization-Induced Self-Assembly Promoted by Liquid-Liquid Phase Separation.

Polymerization-induced self-assembly (PISA) is a powerful method for the synthesis of polymeric kinetically frozen core nanoparticles. However, the PISA synthesis of biologically important polymeric fluidic materials is unexplored. Herein we present a liquid-liquid phase separation mode PISA.

Sequence-Controlled Polymerization-Induced Self-Assembly.

We herein present sequence-controlled polymerization-induced self-assembly (PISA) via photoswitchable reversible addition-fragmentation chain transfer (RAFT) copolymerization of oppositely-charged monomers using polyethylene glycol chain transfer agent in water at 25 °C. Thorough block copolymerization leads to a polymerization-induced electrostatic self-assembly named ABC-mode polymerization-induced electrostatic self-assembly (PIESA), by which PEGylated (PEG, polyethylene glycol) polyion complex (PIC) spheres, lamellae, and vesicles are achieved. We demonstrate the inherent spontaneous zwitterionic alternating copolymerization nature, which leads to the charge-dictated alternating or gradient zwitterionic sequence.

Adaptive Estimation and Cooperative Guidance for Active Aircraft Defense in Stochastic Scenario.

The active aircraft defense problem is investigated for the stochastic scenario wherein a defending missile (or a defender) is employed to protect a target aircraft from an attacking missile whose pursuit guidance strategy is unknown. For the purpose of identifying the guidance strategy, the static multiple model estimator (sMME) based on the square-root cubature Kalman filter is proposed, and each model represents a potential attacking missile guidance strategy. Furthermore, an estimation enhancement approach is provided by using pseudo-measurement.

Adaptive Fifth-Degree Cubature Information Filter for Multi-Sensor Bearings-Only Tracking.

Standard Bayesian filtering algorithms only work well when the statistical properties of system noises are exactly known. However, this assumption is not always plausible in real target tracking applications. In this paper, we present a new estimation approach named adaptive fifth-degree cubature information filter (AFCIF) for multi-sensor bearings-only tracking (BOT) under the condition that the process noise follows zero-mean Gaussian distribution with unknown covariance.

Compartmentalization and Unidirectional Cross-Domain Molecule Shuttling of Organometallic Single-Chain Nanoparticles.

Compartmentalization and unidirectional cross-domain molecule shuttling are omnipresent in proteins, and play key roles in molecular recognition, enzymatic reaction, and other living functions. Nanomachinery design emulating these biological functions is being considered as one of the most ambitious and challenging tasks in modern chemistry and nanoscience. Here, we present a biomimetic nanomachinery design using single-chain technology.