Highly efficient removal of organic contaminant with wide concentration range by a novel self-cleaning hydrogel: Mechanism, degradation pathway and DFT calculation.

A novel carbon nitride based self-cleaning hydrogel photocatalyst (KI-PCN gel, potassium and iodine co-doped carbon nitride confined in alginate) has been successfully constructed by a facile method. Fabricated photocatalyst showed enhanced synergistic adsorption-photocatalytic degradation property on a high concentration of methylene blue (HMB) because of enhanced carrier separation efficiency and improved light adsorption capacity of KI-PCN. As expected, the KI-PCN gel showed the highest apparent rate constant value K =0.