Seasonal dynamics of groundwater discharge: Unveiling the complex control over reservoir greenhouse gas emissions.

The pronounced topographical differences, giving rise to numerous water bodies, also endow these formations with substantial hydraulic gradients, leading to pronounced groundwater discharge within their low-lying, natural reservoir settings. However, the dynamics of groundwater discharge in reservoirs and their impact on greenhouse gas (GHG) production and emission under different conditions remain unclear. This study focuses on a reservoir in southeastern China, where we conducted seasonal field observations alongside microcosm incubation experiments to elucidate the relationship between greenhouse gas emissions and groundwater discharge.

New insights into the spatial variability of microbial diversity and density in peatlands exposed to various electron acceptors with an emphasis on methanogenesis and CO fluxes.

Peatlands are vital in the global carbon cycle, acting as significant sinks for carbon and releasing methane (CH) and carbon dioxide (CO) into the atmosphere. However, the complex interactions between environmental factors and the microbial communities responsible for these greenhouse gas emissions remain insufficiently understood. To address this knowledge gap, a pilot-scale mesocosm study was conducted to assess the impact of different terminal electron acceptors (TEAs), including sulfate (SO ), humic acid (HA), and goethite, on CH and CO emissions and microbial community structures in peatlands.

Microbial communities and functions are structured by vertical geochemical zones in a northern peatland.

Northern peatlands are important carbon pools; however, differences in the structure and function of microbiomes inhabiting contrasting geochemical zones within these peatlands have rarely been emphasized. Using 16S rRNA gene sequencing, metagenomic profiling, and detailed geochemical analyses, we investigated the taxonomic composition and genetic potential across various geochemical zones of a typical northern peatland profile in the Changbai Mountains region (Northeastern China). Specifically, we focused on elucidating the turnover of organic carbon, sulfur (S), nitrogen (N), and methane (CH).

Improving Sensitivity and Reproducibility of Surface-Enhanced Raman Scattering Biochips Utilizing Magnetoplasmonic Nanoparticles and Statistical Methods.

Surface-enhanced Raman scattering (SERS) technology has been widely recognized for its remarkable sensitivity in biochip development. This study presents a novel sandwich immunoassay that synergizes SERS with magnetoplasmonic nanoparticles (MPNs) to improve sensitivity. By taking advantage of the unique magnetism of these nanoparticles, we further enhance the detection sensitivity of SERS biochips through the applied magnetic field.

Temperature and organic carbon quality control the anaerobic carbon mineralization in peat profiles via modulating microbes: A case study of Changbai Mountain.

Peatlands account for a significant fraction of the global carbon stock. However, the complex interplay of abiotic and biotic factors governing anaerobic carbon mineralization in response to warming remains unclear. In this study, peat sediments were collected from a typical northern peatland-Changbai Mountain to investigate the behavior and mechanism of anaerobic carbon mineralization in response to depth (0-200 cm) and temperature (5 °C, 15 °C and 20 °C), by integrating geochemical and microbial analysis.

Role of microbial microbes in arsenic bioaccumulation and biotransformation in mice.

Although gut microbes can affect the accumulation and metabolism of arsenic (As), the microbes contributing to these processes remain largely unknown. Therefore, this study aimed to investigate the bioaccumulation and biotransformation of arsenate [As(V)] and arsenobetaine (AsB) in mice with a disordered gut microbiome. We used cefoperazone (Cef) to construct a mouse model of gut microbiome disruption along with 16S rRNA sequencing to elucidate the effect of gut microbiome destruction on the biotransformation and bioaccumulation of As(V) and AsB.

Application of microbial-induced carbonate precipitation (MICP) techniques to remove heavy metal in the natural environment: A critical review.

The occurrence of imbalanced heavy metals concentration due to anthropogenic hindrances in the aquatic and terrestrial environment has become a potential risk to life after circulating through different food chains. The microbial-induced carbonate precipitation (MICP) method has gradually received great attention from global researchers but the underlying mechanism of heavy metal mineralization is not well-understood and challenging, limiting the applications in wastewater engineering. This paper reviews the metabolic pathways, mechanisms, operational factors, and mathematical/modeling approaches in the MICP process.

[Effects of clay minerals on the transport of perfluorooctanoic acid in saturated porous media].

We examined the effects of representative clay minerals, montmorillonite (M) and kaolin (K), on perfluorooctanoic acid (PFOA) transport under saturated conditions. Results showed that low amounts of M or K addition increased and high addition amounts reduced PFOA retardation in quartz sand during the transport. With increasing addition of clay minerals (0-50%, weight ratio), the retardation factor of the M-added system increased from 1.

Application of Metabonomics in Substance Abuse Toxicology Research.

Abstrct: Metabonomics is a relative discipline that develops after genomics and proteomics, and it is an important component of systems biology. It uses high-throughput and high-sensitivity instruments to perform qualitative and quantitative analysis of all metabolic components in specific biological samples under limited conditions and combines with multivariate statistics to analyze and process the data to obtain information about physiological, pathological or toxicological changes in organisms. In recent years, because of the complicated mechanism of substance abuse and the continuous emergence of new psychoactive substances, metabonomics is increasingly used in substance abuse research.

Metabolomics-based comparative analysis of the effects of host and environment on metabolites and antioxidative activities.

(Kom.) Nakai is a well-known medicinal hemiparasite widely distributed in Asia. The synthesis and accumulation of its metabolites are affected by both environmental factors and the host plants, while the latter of which is usually overlooked.

Enhanced periphyton biodegradation of endocrine disrupting hormones and microplastic: Intrinsic reaction mechanism, influential humic acid and microbial community structure elucidation.

Endocrine-disrupting compounds (EDCs), as well as microplastics, have drawn global attention due to their presence in the aquatic ecosystem and persistence in wastewater treatment plants (WWTPs). In the present study, for simultaneous bio-removal of two EDCs, 17α-ethinylestradiol (EE2), bisphenol A (BPA), and a microplastic, polypropylene (PP) four kinds of periphytic biofilms were employed. Additionally, the effect of humic acid (HA) on the removal efficacy of these biofilms was evaluated.

Variations of inorganic ions and dissolved organic matter in different types of peat bogs and its ecological significance.

Peat bogs, which cover only 3% of the global land surface, store about 30% of the global soil carbon (C), and are important carbon pools in terrestrial ecosystems. Dissolved organic matter (DOM) is an important part of carbon cycle in peatland, and also an important participant in biogeo-chemical process of peat. The variation of redox ability of DOM and inorganic ions in surface water, groundwater, and pore water of two sampling peatland (minerotrophic fen, LB; ombrotrophic bog, OS) were analyzed using novel electrochemical method and stable carbon isotope.

Greenhouse gases emission control in WWTS via potential operational strategies: A critical review.

Greenhouse gases (GHGs; particularly, CO, CH, and NO) emission from wastewater treatment systems (WWTS) is one of the inevitable concerns for sustainable development. This indicator is directly linked with the carbon footprint and potential impacts of WWTS on climate change. In this view, various modeling, design, and operational tools have been introduced to mitigate the WWTS associated GHGs, at regional and global scales.

[Reconstruction of temporal and spatial trends of atmospheric pollution based on polychlorinated biphenyls concentration changes in ombrotrophic bogs].

To reconstruct the deposition rate of polychlorinated biphenyls (PCBs) in different historical periods and to examine the temporal and spatial trend of PCBs pollution, we analyzed the changes of PCBs concentration and deposition rate in peat cores and lake sediments, and evaluated the suitability of peat cores and lake sediments for studying PCBs deposition trend. Through the dating analysis of all samples, we found that peat bog could well record the historical sedimentation of PCBs. PCBs did not degrade in peat, and it was thus feasible to use peatland to examine the settlement of PCBs.

Plant succession and geochemical indices in immature peatlands in the Changbai Mountains, northeastern region of China: Implications for climate change and peatland development.

Peatlands cover a small portion of the Earth's land surface but hold ~30% of soil carbon (C) globally. However, few studies have focused on the early stage of peatland development, which is a key stage in the initial C sink function of peatlands. An immature peatland is vulnerable to changes in environmental conditions, e.

Bio-remediation approaches for alleviation of cadmium contamination in natural resources.

Cadmium (Cd) is a harmful heavy metal that can cause potent environmental and health hazards at different trophic levels through food chain. Cd is relatively non-biodegradable and persists for a long time in the environment. Considering the potential toxicity and non-biodegradability of Cd in the environment as well as its health hazards, this is an urgent issue of international concern that needs to be addressed by implicating suitable remedial approaches.

Nature rejuvenation: Long-term (1989-2016) vs short-term memory approach based appraisal of water quality of the upper part of Ganga River, India.

The deteriorating water quality (WQ) of the sacred north-flowing perennial Indian River, Ganga was a serious concern in recent decades for population adjoining to the river and policy planners. The present evaluation attempts to assess the long-term (1989-2016) physiochemical characteristics of WQ of river Ganga at five upstream locations (Uttarkashi, Tehri, Rudraprayag, Devprayag, and Rishikesh) of Uttarakhand, India using comprehensive pollution index (CPI) and environmetrics (PCA and CA). These methods were used to categorize, summarize expensive datasets, and grouping the similar polluted areas along the river stretches.

Exploring stereoselective excretion and metabolism studies of novel 2-(2-hydroxypropanamido)-5-trifluoromethyl benzoic acid enantiomers.

-/-2-(2-Hydroxypropanamido)-5-trifluoromethyl benzoic acid (-/-HFBA), as a novel COX inhibitor, was firstly reported to have remarkable anti-inflammatory and antiplatelet aggregation activities by our group. In our previous study, stereoselective differences in pharmacokinetics were found between HFBA enantiomers after oral and intravenous administration of each enantiomer to rats. The discrepancies might be associated with the excretion and metabolism of the two enantiomers.

Synthesis, pharmacological evaluation and molecular docking of novel R-/S-2-(2-hydroxypropanamido)-5-trifluoromethyl benzoic acid as dual anti-inflammatory anti-platelet aggregation agents.

R-/S-2-(2-hydroxypropanamido) benzoic acid (R-/S-HPABA), marine-derived anti-inflammatory antiplatelet drugs, were initially synthesised in our group. However, preliminary research showed that R-/S-HPABA were eliminated rapidly because of extensive hydroxylation metabolism of phenyl ring in vivo. In order to reduce significant hydroxylation metabolism to improve pharmacological activity and bioavailability, trifluoromethyl group was incorporated into R-/S-HPABA to synthesise R-/S-2-(2-hydroxypropanamido)-5-trifluoromethyl benzoic acid (R-/S-HFBA), respectively.

Efflux behavior of inorganic mercury and methylmercury in the marine copepod Tigriopus japonicus.

Marine copepods play an important role in transferring mercury to higher trophic levels in aquatic ecosystems. Exposure time is an important environmental parameter that potentially influences the bioaccumulation and biomagnification of Hg in copepods, which increases the uncertainty in risk assessments of Hg in food chains. In the present study, we employed the radiotracer technique to evaluate the efflux behavior of inorganic mercury [Hg(II)] and methylmercury (MeHg), and the effects of exposure time in a population of Tigriopus japonicus copepods.

Four new species of the genus Miridiba Reitter (Coleoptera: Scarabaeidae: Melolonthinae) from China.

Four new species of the genus Miridiba Reitter, 1902 from South China are described and illustrated: Miridiba (Miridiba) bannaensis Gao Fang, new species, M. (M.) kuatunensis Gao Fang, new species, M.