Noble-metal-free FeO/CoS nanosheets with oxygen vacancies as an efficient electrocatalyst for highly sensitive electrochemical detection of As(III).

The electrochemical method for highly sensitive determination of arsenic(III) in real water samples with noble-metal-free nanomaterials is still a difficult but significant task. Here, an electrochemical sensor driven by noble-metal-free layered porous FeO/CoS nanosheets was successfully employed for As(III) analysis, which was prepared via a facile two-step method involves a hydrothermal treatment and a subsequent sulfurization process. As expected, the electrochemical detection of As(III) in 0.

[The Latest Research Progress of Coupling between BiOX and Semiconductor Photocatalyst].

The heterojunction was formed between two kinds of coupling semiconductors , which improved the charge separation efficiency of system, widened the spectral response range of catalysts and improved photocatalytic propertirs of catalysts. The process of preparation of semiconductors coupling was easily affected by preparation methods and reaction temperature and so on, which would cause the changes in crystal structure and surface properties of coupling semiconductors, thus photocatalytic quantum efficiency of coupling semiconductors was increased. In this article, the following three aspects were mainly discussed.

[A Study on Preparation and Photocatalytic Activity of Mn-BiOCl].

Using Bi2O3 and MnC2 x 4H2O as raw materials, with HCl as solvent, photocatalysts of Mn-BiOCl with different molar ratio of Mn and Bi were prepared by a hydrolysis method. The obtained samples were characterized by XRD, HRTEM, TEM, UV-Vis DRS and SPS. The UV light photocatalytic activity of Mn-BiOCl was evaluated by using methyl orange as model compounds of photocatalytic reaction.

[Study on synthesis and matching degree of energy level of terbium complexes using o-fluoro-benzoic acid as ligand].

Tb(2-FBA)3 x 2H2O and Tb(2-FBA)3 phen were synthesized using o-fluoro-benzoic acid (2-FBA) as the first ligand, and 1,10-phenanthroline (phen) as the second ligand. Elemental analysis and IR spectra were employed to characterize the molecular composition of the two kinds of lanthanide complexes. The UV absorption spectra with same concentration show that the second ligand phen of Tb(2-FBA)3 phen absorbs the portion of the UV light instead of the first ligand 2-FBA.

[Study on preparations and fluorescent properties of rare earth complex with property of fluorescence sensor].

Europium chloride, 2-thienylformyltrifluoroacetone and sodium silicate were used to synthesize new-style rare earth complex (Eu-TNS). By adding into dichloromethane solution containing Eu-TNS, the fluorescent intensities were enhanced gradually and regularly. High-resolution mass spectrometry was used to detect the formula of Eu-TNS, which belongs to multi-core rare-earth complex.

[Synthesis and characterization of new lanthanide complexes using pipemidic acid (PPA) and dioxane as ligands].

Eu(PPA)3 dioxane and Tb(PPA)3 dioxane were synthesized by firstly adopting dioxane as second ligand and using pipemidic acid (PPA) as first ligand. In contrast with two kinds of binary lanthanide complexes Eu(PPA)3 and Tb(PPA)3, the photoluminescent intensities of Eu (PPA)3 dioxane and Tb (PPA)3 dioxane are much stronger, especially for that of Tb(PPA)3 dioxane. The enhancement of photoluminescent intensities of Eu(PPA)3 dioxane and Tb(PPA)3 dioxane is because of the replacement of dioxane for water bonded to Eu3+ and Tb3+, by which the energy loss through heat oscillation will be inhibited.

[Synthesis of SiO2 coated Eu(TTA)3phen and study on its fluorescent property].

New-style fluorescent material of SiO2/Eu(TTA)3 phen was synthesized by the method of dispersing Eu(TTA)3 phen in isopropanol and hydrolyzing TEOS. Fluorescence spectra showed that the emission intensities of SiO2/Eu(TTA)3 phen were much more stronger than that of Eu(TTA)3 phen by more than two times. At the same time, the peak at 617.

Synthesis of Galacto-oligosaccharide in Two-phase System.

35 of the total products of galacto-oligosaccharide (GOS) could be obtained from the two-phase system with cyclohexane and ethyl acetate as bulk organic phases and 15% phosphate buffer as aqueous phase. The effects of temperature pH of buffer lactose concentration galactose and glucose and the immobilization of enzyme on the synthesis of GOS were studied. It was found that the reaction temperature and initial lactose concentration didn'thave obvious effects while the addition of glucose and galactose somewhat affected the GOS yield and the GOS yields could reach 64.