Background: Many studies have indicated an association between maternal occupational exposure to hazardous agents, such as anticancer drugs and ionizing radiation, and an increased risk of adverse pregnancy outcomes, including stillbirths or miscarriages and physical abnormalities in offspring. However, the effects of recent advancements in protective measures to reduce these risks have not been clarified. Aim To investigate the current impact of parental occupational exposure to anticancer drugs and ionizing radiation on stillbirths or miscarriages as well as physical abnormalities under the circumstances of the developed safety protocols.
View Article and Find Full Text PDFPolyimide (PI) aerogel is a good thermal insulation material with the highest temperature resistance in practical application. But the mechanical strength of PI aerogels prepared by freeze-drying or thermoimide methods is weak. In this research, TPU was selected as an aging solution to solve the problem of the low mechanical strength of PI aerogel prepared by the freeze-drying method.
View Article and Find Full Text PDFBiomass aerogel is attractive in various applications due to their renewable, biodegradable and eco-friendly advantages. Herein, a novel beta molecular sieve/carboxymethyl cellulose/polyvinyl alcohol composite aerogel (beta/CP) is prepared by direct mixing and directional freeze-drying as an efficient gas adsorbent with hierarchical porosity. The beta molecular sieve is uniformly dispersed in the three-dimensional skeleton of the aerogel.
View Article and Find Full Text PDFRapid and safe disinfection and exudate management are two major challenges in infected wound care. Therefore, in this work, we developed a novel wound dressing encapsulating ZIF-8-derived carbon nanoparticles in a hydrophilic nanofiber sponge to address severe wound infection and heavy exudate problems. The dressing can effectively kill bacteria through chemo-photothermal synergistic therapy.
View Article and Find Full Text PDFPolyimide (PI) aerogel has surfaced in research and development as a result of its heat resistance, flame retardancy, and low dielectric constant. However, it is still a challenge to reduce the thermal conductivity while improving its mechanical strength and retaining hydrophobicity. Herein, the PI/thermoplastic polyurethane (TPU) composite aerogel was synthesized by coupling TPU with PI via a novel method of chemical imidization combined with freeze-drying technology.
View Article and Find Full Text PDFAdsorption natural gas (ANG) is a technology in which natural gas is stored on the surface of porous materials at relatively low pressures, which are promising candidates for adsorption of natural gas. Adsorbent materials with a large surface area and porous structure plays a significant role in the ANG technology, which holds promise in increasing the storage density for natural gas while decreasing the operating pressure. Here, we demonstrate a facile synthetic method for rational construction of a sodium alginate (SA)/ZIF-8 composite carbon aerogel (AZSCA) by incorporating ZIF-8 particles into SA aerogel through a directional freeze-drying method followed by the carbonization process.
View Article and Find Full Text PDFBiomass aerogels are attractive in various applications owing to their inherent advantages of renewability, biodegradability and eco-friendly. Herein, a novel composite aerogel of konjac glucomannan (KGM)/TEMPO-oxidized cellulose nanofibers (TOCNF)@HKUST-1 (KTA@HKUST-1) is prepared through a facile vacuum impregnation method combined with the directional freeze-drying process, which using KGM and TOCNF as raw materials. The structural analyses disclose that the KTA@HKUST-1 has a hierarchical porosity, in which HKUST-1 can provide micropores for adsorption, while the meso-/macropores from KTA act as high-speed channels to improve diffusion and mass transfer rate to transport CO components into the micropores of HKUST-1.
View Article and Find Full Text PDFThe interactions between organelles can maintain normal cell activity. Lysosomes, as waste disposal systems of cells, have many important interactions with the plasma membrane, especially in the repair of cracked plasma membrane. Unfortunately, a way to study the relationship between them synchronously is still lacking.
View Article and Find Full Text PDFDeveloping highly efficient and stable photocatalysts is an effective method to achieve COphotocatalytic reduction. Herein, PI/WOaerogel photocatalyst was prepared by chemical amide reaction coupled with an ethanol supercritical drying technique. The novel aerogel photocatalysts exhibit excellent photocatalytic performance for reducing COinto CO.
View Article and Find Full Text PDFCellulose derived carbon aerogel (CA) with unique three-dimensional network coated with polyaniline (PANI) on its surface is used as a scaffolding framework to anchor ZIF-8. The designed ZIF-8 derived porous carbon (ZC)/PANI@CA (ZPCA) hybrid carbon composite through a facile solution immersion chemical route and subsequent carbonization process is employed as electrode for supercapacitor, which has contributed a large specific surface area, a hierarchical porous structure and reasonable N content (up to 6.27 at.
View Article and Find Full Text PDFResponsive polymer-based sensors have attracted considerable attention due to their ability to detect the presence of analytes and convert the detected signal into a physical and/or chemical change. High responsiveness, fast response speed, good linearity, strong stability, and small hysteresis are ideal, but to gain these properties at the same time remains challenging. This paper presents a facile and efficient method to improve the photonic sensing properties of polymeric gels by using non-close-packed monolayer colloidal crystals (ncp MCCs) as the template.
View Article and Find Full Text PDF