Red Phosphorescent Platinum(II) Complexes with Tetradentate Pyridine-Containing Ligands for Organic Light Emitting Diodes.

Here, red phosphorescent platinum(II) complexes based on tetradentate pyridine-containing lig-ands are studied. To investigate their electroluminescent properties, multilayer devices were fabricated in the following sequence; ITO (180 nm)/4,4',4″-Tris[2-naphthyl(phenyl)amino]triphenylamine (2-TNATA) (30 nm)/, '-di(1-naphthyl)-,'-diphenyl-1,1'-biphenyl)4,4'-diamine (NPB) (20 nm)/ Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/4,4'-Bis(-carbazolyl)-1,1'-biphenyl (CBP) (20 nm)/Platinum(II) complex (20 nm)/1,3,5-Tris(1-Phenyl-1H-benzimidazol-2-yl)benzene) (TPBi) (40 nm)/Liq (2 nm)/Al (100 nm). In particularly, a device using platinum(II) complex based on -(3,5-di-tert-butylphenyl)-3-(pyridin-2-yl)--(3-(pyridin-2-yl)phenyl)benzenamineligand showed the efficient red emission, with a luminous efficiency, power efficiency, and external quantum efficiency of, and the Commission International de LEclairge (CIE) coordinates of 27.

Deep Blue Organic Light-Emitting Diodes Based on [7,7-Dimethyl-9-(10-phenylanthracen-9-yl)-7H-Indeno[1,2-f] Isoquinoline] Derivatives.

In this study, we synthesized and characterized two novel deep blue emitting materials based on indenoquinoline-substituted phenylanthracene derivatives. Multilayer organic light-emitting diodes were fabricated with the following sequence: indium-tin-oxide (ITO)/4,4',4″-tris[2-naphthyl(phenyl)amino (2-TNATA)/4,4'-bis(--naphthyl)--phenylamino) biphenyl (NPB)/Blue emitting material ( or )/Bathophenanthroline (Bphen)/lithium quinolate (Liq)/Al. A device using '7,7-dimethyl-9-(10-phenylanthracen-9-yl)-7H-indeno[1,2-f] isoquinoline ()' as an emitter showed the efficient emission with the luminous efficiency, power efficiency, and external quantum efficiency of 2.