Electrochemical and quantum chemical investigation on the adsorption behavior of a schiff base and its metal complex for corrosion protection of mild steel in 15 wt% HCl solution.

This work evaluates the effectiveness of Schiff base derivatives, namely, 2,2'-((1E,1'E)-((2,2-dimethylpropane-1,3-diyl)bis(azaneylylidene))bis(methaneylylidene))diphenol (DAMD) and (2-((E)-((3-(((E)-2-hydroxybenzylidene)amino)-2,2dimethylpropyl)imino)methyl)phenoxy) zinc (HDMZ), as corrosion inhibitors for mild steel in a 15 % HCl solution. By employing a blend of experimental assessments and theoretical computations, such as electrochemical tests, morphological observations, and theoretical simulations, the study achieved an impressive up to 94.6 % inhibition efficiency.

Reduction-immobilizing strategy of polymer-embedded sub-2 nm Cu nanoparticles with uniform size and distribution responsible for robust catalytic reactions.

Polymer-embedded metal nanoparticles are in great demand owing to their unique features, leading to their use in various important applications, including catalysis reactions. However, particle sintering and aggregation are serious drawbacks, resulting in a drastic loss of catalytic activity and recyclability. Herein, a reduction-immobilizing strategy of polymer-embedded sub-2 nm Cu nanoparticles offered highly controlled distribution and nanoparticle size within polymer structures with high fidelity.

Efficient multifunctional PPy-NTs/PEI@alginate@NiFeO magnetic beads for heavy metals removal: Experimental design and optimization interpretations.

A highly effective magnetic nanocomposite alginate beads (PPy-NTs/PEI@Alg@NiFeO) were synthesized using alginate as the encapsulation reagent and polypyrrole/polyethylene imine with nano NiFeO as a functional filler to remove toxic Zn and Pb from polluted water. A response surface methodology (RSM) was used to statistically assess the influences of pH and the adsorbent dose on the adsorption performance. PPy-NTs/PEI@Alg@NiFeO magnetic microbeads exhibited the optimal adsorption capacity q (18.

Hybrid method integrating adsorption and chemical precipitation of heavy metal ions on polymeric fiber surfaces for highly efficient water purification.

A lot of research has been focused on increasing the specific surface area of adsorbents over a long period of time to remove heavy metal ions from wastewater using the adsorbent. However, porous adsorbents with high specific surface area have demonstrated drawbacks in water purification processes, such as high pressure drop and limitations in the adsorption capacity of heavy metal ions. In recent years, a mechanism-based convergence method involving adsorption/chemical precipitation has emerged as a promising strategy to surmount the constraints associated with porous adsorbents.

Balloon-expandable cobalt chromium stent versus self-expandable nitinol stent for the Atherosclerotic Iliac Arterial Disease (SENS-ILIAC Trial) Trial: a randomized controlled trial.

Iliac artery angioplasty with stenting is an effective alternative treatment modality for aortoiliac occlusive diseases. Few randomized controlled trials have compared the efficacy and safety between self-expandable stent (SES) and balloon-expandable stent (BES) in atherosclerotic iliac artery disease. In this randomized, multicenter study, patients with common or external iliac artery occlusive disease were randomly assigned in a 1:1 ratio to either BES or SES.

Fabrication of Protective Organic Layer Using Schiff-Base Metal Complex Responsible for Excellent Corrosion Performance: Experimental and Theoretical Perspectives.

The effectiveness of a copper(II) complex with a Schiff base derived from 2-amino-4-phenyl-5-methylthiazole and salicylaldehyde (APMS) as a corrosion inhibitor for XC18 steel in an HCl solution was investigated. Experimental findings indicated a slight negative correlation between inhibition efficiencies in 1 M HCl and temperature but a positive correlation with both inhibitor concentration and immersion time, respectively. The weight loss measurement revealed that APMS achieved a maximum inhibition rate of 92.

Improving Mechanical and Corrosion Properties of 6061 Al Alloys via Differential Speed Rolling and Plasma Electrolytic Oxidation.

This study explores the combined potential of severe plastic deformation (SPD) via differential speed rolling (DSR) and plasma electrolytic oxidation (PEO) to enhance the material performance of 6061 Al alloys. To this end, DSR was carried out at a roll-speed-ratio of 1:4 to obtain ~75% total thickness reduction and a final microstructure of <1 µm. The rest of the samples were annealed to obtain various grain sizes of ~1, ~25, and ~55 μm.

A Novel Coating System Based on Layered Double Hydroxide/HQS Hierarchical Structure for Reliable Protection of Mg Alloy: Electrochemical and Computational Perspectives.

Growing research activity on layered double hydroxide (LDH)-based materials for novel applications has been increasing; however, promoting LDH layer growth and examining its morphologies without resorting to extreme pressure conditions remains a challenge. In the present study, we enhance LDH growth and morphology examination without extreme pressure conditions. By synthesizing Mg-Al LDH directly on plasma electrolytic oxidation (PEO)-treated Mg alloy surfaces and pores at ambient pressure, the direct synthesis was achieved feasibly without autoclave requirements, employing a suitable chelating agent.

Biodegradable Honeycomb-Mimic Scaffolds Consisting of Nanofibrous Walls.

The scaffold is a porous three-dimensional (3D) material that supports cell growth and tissue regeneration. Such 3D structures should be generated with simple techniques and nontoxic ingredients to mimic bio-environment and facilitate tissue regeneration. In this work, simple but powerful techniques are demonstrated for the fabrication of lamellar and honeycomb-mimic scaffolds with poly(L-lactic acid).

Unveiling the mechanisms behind high CO adsorption by the selection of suitable ionic liquids incorporated into a ZIF-8 metal organic framework: A computational approach.

There is growing focus on the crucial task of effectively capturing carbon dioxide (CO) from the atmosphere to mitigate environmental consequences. Metal-organic frameworks (MOFs) have been used to replace many conventional materials in gas separation, and the incorporation of ionic liquids (ILs) into porous MOFs has shown promise as a new technique for improving CO capture and separation. However, the driving force underlying the electronic modulation of MOF nanostructures and the mechanisms behind their high CO adsorption remain unclear.

Recent Advances in Multifunctional Reticular Framework Nanoparticles: A Paradigm Shift in Materials Science Road to a Structured Future.

Porous organic frameworks (POFs) have become a highly sought-after research domain that offers a promising avenue for developing cutting-edge nanostructured materials, both in their pristine state and when subjected to various chemical and structural modifications. Metal-organic frameworks, covalent organic frameworks, and hydrogen-bonded organic frameworks are examples of these emerging materials that have gained significant attention due to their unique properties, such as high crystallinity, intrinsic porosity, unique structural regularity, diverse functionality, design flexibility, and outstanding stability. This review provides an overview of the state-of-the-art research on base-stable POFs, emphasizing the distinct pros and cons of reticular framework nanoparticles compared to other types of nanocluster materials.

Effect of Ultrasonic Frequency on Structure and Corrosion Properties of Coating Formed on Magnesium Alloy via Plasma Electrolytic Oxidation.

This study explores the application of ultrasonic vibration during plasma electrolytic oxidation (PEO) to enhance the corrosion resistance of magnesium (Mg) alloy. To this end, three different ultrasonic frequencies of 0, 40, and 135 kHz were utilized during PEO. In the presence of ultrasonic waves, the formation of a uniform and dense oxide layer on Mg alloys is facilitated.

Moldflow Simulation and Characterization of Pure Copper Fabricated via Metal Injection Molding.

Metal injection molding (MIM) is a representative near-net-shape manufacturing process that fabricates advanced geometrical components for automobile and device industries. As the mechanical performance of an MIM product is affected by green-part characteristics, this work investigated the green part of pure copper processed with MIM using the injection temperature of ~180 °C and injection pressure of ~5 MPa. A computational analysis based on the Moldflow program was proposed to simulate the effectivity of the process by evaluating the confidence of fill, quality prediction, and pressure drop of three distinctive regions in the green part.

Effect of Reduction Sequence during Rolling on Deformed Texture and Anisotropy of Ferritic Stainless Steel.

This investigation studied the effect of reduction sequence during rolling of ferritic stainless steel on texture and anisotropy. A series of thermomechanical processes were performed on the present samples utilizing rolling deformation, with a total height reduction of 83% but with different reduction sequences, 67% + 50% (route A) and 50% + 67% (route B). Microstructural analysis showed that no significant difference was found in terms of the grain morphology between route A and route B.

Unraveling Bonding Mechanisms and Electronic Structure of Pyridine Oximes on Fe(110) Surface: Deeper Insights from DFT, Molecular Dynamics and SCC-DFT Tight Binding Simulations.

The development of corrosion inhibitors with outstanding performance is a never-ending and complex process engaged in by researchers, engineers and practitioners. The computational assessment of organic corrosion inhibitors' performance is a crucial step towards the design of new task-specific materials. Herein, the electronic features, adsorption characteristics and bonding mechanisms of two pyridine oximes, namely 2-pyridylaldoxime (2POH) and 3-pyridylaldoxime (3POH), with the iron surface were investigated using molecular dynamics (MD), and self-consistent-charge density-functional tight-binding (SCC-DFTB) simulations.

Characterization of Green Part of Steel from Metal Injection Molding: An Analysis Using Moldflow.

Metal injection molding (MIM) is a quick manufacturing method that produces elaborate and complex items accurately and repeatably. The success of MIM is highly impacted by green part characteristics. This work characterized the green part of steel produced using MIM from feedstock with a powder/binder ratio of 93:7.

Classical monocyte-derived macrophages as therapeutic targets of umbilical cord mesenchymal stem cells: comparison of intratracheal and intravenous administration in a mouse model of pulmonary fibrosis.

Background: Idiopathic pulmonary fibrosis (IPF) is a progressive fibrotic lung disease that has no cure. Although mesenchymal stem cells (MSCs) have been reported to ameliorate lung inflammation and fibrosis in mouse models, their mechanisms of action remain unknown. Therefore, we aimed to determine the changes in various immune cells, especially macrophages and monocytes, involved in the effects of MSC treatment on pulmonary fibrosis.

Development of Natural Plant Extracts as Sustainable Inhibitors for Efficient Protection of Mild Steel: Experimental and First-Principles Multi-Level Computational Methods.

In the present work, we present the superior corrosion inhibition properties of three plant-based products, Fraxinus excelsior (FEAE), Zingiber zerumbet (ZZAE), and Isatis tinctoria (ITAE), that efficiently inhibit the corrosion of mild steel in phosphoric acid. The anti-corrosion and adsorption characteristics were assessed using a combination of experimental and computational approaches. Weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy methods were used to evaluate the inhibitive performance of the inhibitors on the metal surface.

Improving Corrosion and Photocatalytic Properties of Composite Oxide Layer Fabricated by Plasma Electrolytic Oxidation with NaAlO.

The present work dealt with the development of a protective and functional oxide layer via one-step plasma electrolytic oxidation (PEO) on pure titanium by employing highly concentrated aluminate solution in a short processing time. A compositional analysis showed that AlTiO active compound was formed successfully by means of AlO incorporation when TiO was spontaneously developed with the aid of plasma swarms. The electrochemical performance showed the protective and functional capabilities of the layer, which was attributed to the respective amounts of AlO and AlTiO.

The Dynamic Contribution of Neutrophils in the Chronic Respiratory Diseases.

Asthma, chronic obstructive pulmonary disease, and idiopathic pulmonary fibrosis are representative chronic respiratory diseases (CRDs). Although they differ in terms of disease presentation, they are all thought to arise from unresolved inflammation. Neutrophils are not only the first responders to acute inflammation, but they also help resolve the inflammation.

Computational molecular-level prediction of heterocyclic compound-metal surface interfacial behavior.

It is difficult to comprehensively understand the interfacial mechanism (IM) of the adsorption of corrosion inhibitors (CIs) on metal surfaces solely through experiments and electronic structure parameters of isolated molecules. To better understand the molecular-level IM of CIs, a combination of atomistic simulations and first-principles calculations was used to obtain reliable information on the adsorption nature and intermolecular interactions during the actual interfacial behavior. The IM and property changes of two synthesized heterocyclic sustainable-green CIs, namely 4-{[(5-nitrofuran-2-yl)methylene]amino}-5-propyl-4H-1,2,4-triazole-3-thiol (NFPT and 4-{[(5-nitrofuran-2-yl)methylene]amino}-4H-1,2,4-triazole-3-thiol (NFT), were investigated on the Fe(110) surface using first-principles density functional theory (DFT) calculations and molecular dynamics (MD) simulations.

Concurrent Oxidation-Reduction Reactions in a Single System Using a Low-Plasma Phenomenon: Excellent Catalytic Performance and Stability in the Hydrogenation Reaction.

The catalytic activity and stability of metal nanocatalysts toward agglomeration and detachment during their preparation on a support surface are major challenges in practical applications. Herein, we report a novel, one-step, synchronized electro-oxidation-reduction "bottom-up" approach for the preparation of small and highly stable Cu nanoparticles (NPs) supported on a porous inorganic (TiO@SiO) coating with significant catalytic activity and stability. This unique embedded structure restrains the sintering of CuNPs on a porous TiO@SiO surface at a high temperature and exhibits a high reduction ratio (100% in 60 s) and no decay in activity even after 30 cycles (>98% conversion in 3 min).

Securely anchored Prussian blue nanocrystals on the surface of porous PAAm sphere for high and selective cesium removal.

Prussian blue (PB) has been well known as a pigment crystal to selectively sequestrate the radioactive cesium ion released from aqueous solutions owing to PB cage size similar to the cesium ion. Because the small size of PB is hard to deal with, the adsorbents containing PB have been prepared in the form of composites causing low sequestration efficiency of cesium. In this study, securely anchored PB nanocrystals on the surface of millimeter-sized porous polyacrylamide (PAAm) spheres (PB@PAAm) have been prepared by the crystallization of PB on the Fe adsorbed PAAm.