Spectrochim Acta A Mol Biomol Spectrosc
May 2010
Thioglycolic acid (TGA) capped CdTe quantum dots (QDs) with the diameter of 2-3nm were synthesized. The interaction between CdTe QDs and Nile blue (NB) was investigated by ultraviolet-visible (UV-vis) absorption, resonance Rayleigh scattering (RRS) and fluorescence spectroscopy. UV-vis absorption spectrum of CdTe QDs and NB obviously changed, showing that CdTe QDs could associate with NB to form a new complex.
View Article and Find Full Text PDFWhen gold nanoparticles were being prepared by sodium citrate reduction method, citrate anions self-assembled on the surface of gold nanoparticles to form supermolecular complex anions with negative charges, and protonated raloxifene (Ralo) was positively charged and could bind with the complex anions to form larger aggregates through electrostatic force and hydrophobic effects, which could result in the remarkable enhancement of the resonance Rayleigh scattering intensity (RRS), and the appearance of new RRS spectra. At the same time, the second-order scattering (SOS) and frequency-doubling scattering (FDS) intensities were also enhanced. The maximum wavelengths were located near 370 nm for RRS, 520 nm for SOS, and 350 nm for FDS, respectively.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
December 2006
The support vector machine (SVM) is a new learning technique based on the statistical learning theory. In the present paper, forty Panax quinquefolium L. samples were used as experimental materials.
View Article and Find Full Text PDFGuang Pu Xue Yu Guang Pu Fen Xi
November 2005
The nano-photochemical reaction of polyethyelene glycol (PEG)-Au3+ was studied by resonance scattering and absorption spectrophotometry, and transmission electron microscopy. Influence of various factors on the preparation of gold nanoparticles was considered. There is a correlation between the molecular mass of PEG and the size of gold nanoparticles.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
October 2005
Liquid phase gold nanoparticles with different diameters and colors can be prepared using sodium citrate reduction method by controlling the amounts of sodium citrate. The mean diameters of gold nanoparticles are measured by transmission electron microscope (TEM). Gold nanoparticles with different sizes have specific absorption spectra.
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