Publications by authors named "Yoshiaki Kuboi"
Article Synopsis
- Catenanes are attracting interest due to their unique properties, especially topological chirality, but most research has focused on simple, monocyclic catenanes while more complex structures are rare due to synthetic challenges.
- This study presents a new one-pot method to synthesize a trimeric cage-catenane with high yield through dynamic imine condensation, aided by beneficial π-π stacking interactions.
- The research demonstrates that while the individual cage structures can interconvert, the trimeric version is favored, and despite using achiral components, the resulting catenane displays topological chirality, confirmed by advanced analytical techniques.
Herein, we report the first example of chiral donor-acceptor cage DA-2 displaying efficient circularly polarized thermally activated delayed fluorescence (CP-TADF) with || values up to 2.1 × 10 and PLQY of 32%. A small Δ of 0.
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