Rapidly molded sodium alginate/soy protein adhesive hydrogel with 808-nm laser inhibition of infected wounds.

Infected wounds produce pus and heal slowly. To address this issue, we developed a rapid-setting SP/SA@BP-C hydrogel by combining sodium alginate (SA) and soy protein (SP) with black phosphorus (BP) grafted with clarithromycin (Cla) and incorporating Ca for chelation. This hydrogel dressing exhibits excellent photothermal (PT) and photodynamic (PD) bacteriostatic effects without biotoxicity, making it suitable for treating infected wounds.

Structure and molecular-level transformation for oxidation of effluent organic matters by manganese oxides.

As important organic components in water environments, effluent organic matters (EfOMs) from wastewater treatment plants are widely present in Mn-rich environments or engineered treatment systems. The redox interaction between manganese oxides (MnO) and EfOMs can lead to their structural changes, which are crucial for ensuring the safety of water environments. Herein, the reactivities of MnO with EfOMs were evaluated, and it was found that MnO with high specific surface area, active high-valent manganese content and lattice oxygen content (i.

Molecular-level transformations of dissolved black carbon in UV-based advanced oxidation processes.

Dissolved black carbon (DBC) released from biochar, is an essential group in the dissolved organic matter (DOM) pool and is widely distributed in aquatic environments. In various advanced oxidation processes (AOPs), DBC exhibits enhanced free radical scavenging compared to typical DOM, attributed to its smaller molecular weight and more compacted aromatic structure; however, the molecular-level transformations of DBC in different AOPs, such as UV/HO, UV/PDS, and UV/Chlorine, remain unclear. This study employed a DBC derived from wheat biochar for experimentation.

Association between Serum Lactate Dehydrogenase Level and 30-day Mortality in Patients with Intracranial Hemorrhage with Acute Leukemia in the Induction Phase: A Cohort Study.

 This study aimed to identify the association between lactate dehydrogenase (LDH) levels and 30-day mortality in patients with intracranial hemorrhage (ICH) with acute leukemia during the induction phase.  This cohort study included patients with acute leukemia with ICH during induction. We evaluated serum LDH levels upon admission.

Enhancing water quality and ecosystems of reclaimed water-replenished river: A case study of Dongsha River, Beijing, China.

The use of reclaimed water for urban river replenishment has raised concerns regarding its impact on water quality and aquatic ecosystems. This study aims to reveal the improvements seen in an urban river undergoing a practical water eco-remediation after being replenished with reclaimed water. A one-year monitoring of water quality, phytoplankton, and zooplankton was carried out in Dongsha River undergoing eco-remediation in Beijing, China.

Occurrence of iodinated contrast media (ICM) in water environments and their control strategies with a particular focus on iodinated by-products formation: A comprehensive review.

Iodinated contrast media (ICM), one of the pharmaceutical and personal care products (PPCPs), are frequently detected in various water bodies due to the strong biochemical stability and recalcitrance to conventional water treatment. Additionally, ICM pose a risk of forming iodinated by-products that can be detrimental to the aquatic ecosystem. Consequently, effectively removing ICM from aqueous environments is a significant concern for environmental researchers.

O plasma-modified carbon nanotube for sulfamethoxazole degradation via peroxymonosulfate activation: Synergism of radical and non-radical pathways boosting water decontamination and detoxification.

Sulfamethoxazole (SMX), a widely used antibiotic, has triggered increasing attention due to its extensive detection in wastewater effluent, causing serious ecological threats. Herein, a carbon-based heterogeneous catalyst was developed by the O plasma-etching process, regulating oxygen-containing functional groups (OFGs) and defects of carbon nanotubes (O-CNT) to activate peroxymonosulfate (PMS) for highly efficient SMX abatement. Through adjusting the etching time, the desired active sites (i.

Unveiling the enhancement mechanisms of algogenic extracellular organic matters on chlortetracycline photodegradation: Constitutive relationships of compound components and reactive oxygen species generation.

Algogenic extracellular organic matters (EOMs) have been found to play a crucial role in the photodegradation of antibiotics. However, the specific molecular structure compositions of EOMs have not been fully characterized, and the intrinsic association between the structure and the production of ROS remains unclear. In this study, EOMs from Chlorella Vulgaris were characterized using FT-ICR-MS.

Unveil the mechanism of photosensitized fluoroquinolones enhancing chlortetracycline photodegradation under simulated sunlight: Batch experiments and DFT calculation.

Fluoroquinolones (FQs), as the most commonly used antibiotics, are ubiquitous in the aquatic environment. The FQs' self-sensitization process could generate reactive oxygen species (ROS), which could react with other coexisting organic pollutants, impacting their transformation behaviors. However, the FQs' influences and mechanisms on the photochemical transformation of coexisting antibiotics are not yet revealed.

Cobalt doped nitrogen-vacancies-rich CN with optimizing local electron distribution boosts peroxymonsulfate activation for tetracycline degradation: Multiple electron transfer mechanisms.

Heterogeneous photocatalysis coupled with peroxymonosulfate (PMS) activation is considered as an advanced water purification technology for emerging contaminates degradation. In this study, Cobalt (Co) doped nitrogen-vacancies-rich CN photocatalysts (Co/Nv-CN) were designed to activate PMS for tetracycline removal. The photo-chemical oxidation system displayed superior advantage, in which the observed rate constant of tetracycline degradation (0.

Importance of Chain Length in Propagation Reaction on OH Formation during Ozonation of Wastewater Effluent.

During the ozonation of wastewater, hydroxyl radicals (OH) induced by the reactions of ozone (O) with effluent organic matters (EfOMs) play an essential role in degrading ozone-refractory micropollutants. The OH yield provides the absolute OH formation during ozonation. However, the conventional "tert-Butanol (BuOH) assay" cannot accurately determine the OH yield since the propagation reactions are inhibited, and there have been few studies on OH production induced by EfOM fractions during ozonation.

Coupled mixotrophic denitrification and utilization of refractory organics driven by Mn redox circulation for significantly enhanced nitrogen removal.

Coupled mixotrophic denitrification and degradation of organics driven by redox transition of Mn for nitrogen removal has attracted much attention. Herein, this study explored the removal performance and mechanisms for nitrogen and refractory organics from secondary effluent in up-flow MnOx biofilter. Results showed that the removal of organics and nitrate was significantly enhanced by the synergistic process of heterotrophic denitrification and Mn(II)-driven autotrophic denitrification (MnAD), which were originated from the facilitation of Mn circulation.

Carbon-defect-driven persulfate activation for highly efficient degradation of extracellular DNA contaminant: Radical oxidation and electron transfer pathways.

Extracellular DNA (eDNA), as a dynamic repository for antibiotic-resistant genes (ARGs), is a rising threat to public health. This work used a ball-milling method to enhance defect structures of activated carbon, and carbon defects exhibited an excellent capacity in persulfate (PS) activation for model eDNA and real ARGs degradation. The eDNA removal by defect-rich carbon with PS was 2.

Cyanocobalamin promotes muscle development through the TGF-β signaling pathway.

Cyanocobalamin (CNCbl, the compound name of Vitamin B12) is the only mineral vitamin that is essential for growth and development and cannot be produced by animals. Some studies have found that CNCbl can promote the proliferation and migration of C2C12 cells, but the mechanism by which it affects muscle development is still unknown. In this study, we elucidated the effect of CNCbl on muscle development and studied its underlying mechanism.

A novel constructed wetland based on iron carbon substrates: performance optimization and mechanisms of simultaneous removal of nitrogen and phosphorus.

In recent years, the combination of iron carbon micro-electrolysis (ICME) with constructed wetlands (CWs) for removal of nitrogen and phosphorus has attracted more and more attention. However, the removal mechanisms by CWs with iron carbon (Fe-C) substrates are still unclear. In this study, the Fe-C based CW (CW-A) was established to improve the removal efficiencies of nitrogen and phosphorus by optimizing the operating conditions.

Effect of allelochemicals sustained-release microspheres on the ingestion, incorporation, and digestion abilities of Daphnia magna Straus.

Allelochemicals sustained-release microspheres (ACs-SMs) exhibited great inhibition effect on algae, however, few studies have focused on ACs-SMs toxicity on invertebrate. In this study, the effects of single high-concentration ACs (15 mg/L, SH-ACs), repeated low-concentration ACs (3 × 5 mg/L, RL-ACs) and ACs-SMs containing 15 mg/L ACs exposure on the ingestion, incorporation, and digestion of Daphnia magna Straus (DS) were investigated by stable isotope N labeling method. Meanwhile, the diversity and abundance of microflora in DS guts were determined by 16S rRNA genes and cloning methods.