Ultrahigh antipsychotics selective accumulation and efficient photocatalytic degradation using a novel 2D BiOIO-based molecularly imprinted photocatalyst.

Adsorption-assisted photocatalytic degradation of pollutants is an effective method to improve degradation efficiency. However, most adsorptive photocatalysts are not selective and cannot efficiently remove low-concentration targets in complex systems, which limit their practical application. Therefore, a novel molecularly imprinted photocatalyst (MI-BiOIO) with high selectivity and adsorption capacity was prepared using two-dimensional BiOIO nanosheet as the matrix.

Comparative analysis of chemical constituents in the stems and roots of different Ephedra species and their in vitro anti-acute lung injury effects.

Ephedra, the sole genus in the Ephedraceae family, comprises 75 species distributed across Asia, North America, and South America. Ephedrae herba, a well-established traditional Chinese medicine, has been used in clinical practice for over two millennia. Ephedra is widely used to treat asthma, colds, and coughs.

Indole-3-Propionic Acid Attenuates Neuroinflammation and Cognitive Deficits by Inhibiting the RAGE-JAK2-STAT3 Signaling Pathway.

Cognitive disorders such as Alzheimer's disease (AD) are highly prevalent and place heavy burdens on society. Neuroinflammation is a driver of cognitive impairment, with no effective drugs. Indole 3-propionic acid (IPA) is a tryptophan metabolite mainly produced by, which exhibits multiple functions, including antioxidant, anti-inflammatory, antiaging, and neuroprotective properties.

Comparative effects of selenium-enriched lactobacilli and selenium-enriched yeast on performance, egg selenium enrichment, antioxidant capacity, and ileal microbiota in laying hens.

Background: Organic selenium (Se) has gained recognition in poultry nutrition as a feed additive to boost production and Se deposition in eggs and tissues, owing to its high bioavailability, efficient tissue accumulation and minimal toxicity. Selenium-enriched yeast (SeY) is a well-established source, while selenium-enriched lactobacilli (SeL), a newer alternative, offers the added benefits of probiotics. This study examined the effects of SeY and SeL on egg quality, antioxidant capacity, Se deposition, and gut health in laying hens.

Horseradish peroxidase/hydrogen peroxide-driven photothermally enhanced hydrogel loaded with black rice extract for treating infected skin wound.

Bacterial infection of the damaged skin area hinders the wound healing process. Photothermal antibacterial therapy has attracted increasing attention. As green, safe, and possessing various bioactive properties, natural plant extracts are a good choice.

A novel hierarchical porous ZIF-8 for effective removal of three non-steroidal anti-inflammatory drugs simultaneously from environment.

Metal organic frameworks (MOFs) adsorbents have significant advantages to remove contaminates. While their microporous structure is not conducive to entry of larger molecules, making it difficult to simultaneously utilize the inner and outer surfaces of the pores to achieve higher adsorption capacity. In this work, the hexadecyltrimethylammonium bromide was employed as soft template to prepare a novel hierarchical porous ZIF-8 (HP-ZIF-8) in water.

Glucose-triggered NIR-responsive photothermal antibacterial gelatin/dextran hydrogel simultaneously targeting the high glucose and infection microenvironment in diabetic wound.

The treatment of diabetic wounds with bacterial infection is a major challenge in the medical field. Microenvironment-responsive hydrogel dressings have shown great advantages, and photothermal antibacterial therapy is a potential antimicrobial strategy to avoid the generation of resistant bacteria. In this work, a glucose-triggered near-infrared (NIR)-responsive photothermal antibacterial hydrogel was designed and named GOGD based on a cascade reaction of glucose oxidation and polyphenol polymerization.

Influence of Sulfur Fumigation on Angelicae Dahuricae Radix: Insights from Chemical Profiles, MALDI-MSI and Anti-Inflammatory Activities.

Background: Angelicae Dahuricae Radix (ADR) is used as both a traditional Chinese medicine and a food ingredient in China and East Asian countries. ADR is generally sun-dried post-harvest but is sometimes sulfur-fumigated to prevent decay and rot. Although there are some studies on the effect of sulfur fumigation on ADR, they are not comprehensive.

Piezochromic Luminescence of Pyrene Derivatives Polymorphism Around Excimer Forming Process.

Pyrene aggregates, as classic luminescent materials, are of great interest from a scientific viewpoint owing to the development of optoelectronic materials. In this study, we designed a compound 1,4,5-triphenyl-2-(pyren-1-yl)-4,5-dihydro-1H-imidazole (IM-PY) which was achieved with two crystalline polymorphs (IMPY-G and IMPY-B). They exhibit the green emission and the blue emission, respectively, both with pyrene serving as the luminescent core.

[A supplementary detection method and supervision strategy for adulteration of Panacis Quinquefolii Radix in Ginseng Radix et Rhizoma and its preparations].

Ginseng Radix et Rhizoma and its preparations are often adulterated with Panacis Quinquefolii Radix. Based on the research on Ginseng Radix et Rhizoma and Panacis Quinquefolii Radix, the causes and analytical method of adulteration were determined. A UPLC-MS/MS method was developed for the detection of Panacis Quinquefolii Radix mixed in Ginseng Radix et Rhizoma, with pseudoginsenoside F_(11) as the marker.

Crystallographic symmetry increasing in the pressure-induced phase transition of the hydrogen-bonded organic crystal 1-methylhydantoin.

In situ high-pressure Raman spectroscopy and synchrotron angular dispersive x-ray diffraction techniques, combined with first-principles calculations, have been performed to investigate the 1-methylhydantoin (C4H6N2O2, 1-MH) molecular crystal. High-pressure experiments have shown that phase I (monoclinic system) begins to transform into phase II (orthorhombic system) at pressures above 4.0 GPa, and the transformation range is from 4.

A newly NH-UiO-66 composite functionalized by molecularly imprinted polymer for selective and rapid removal of sulfamethoxazole.

Metal-organic frameworks (MOFs) are used as novel adsorption materials owing to their large surface area and tunable pore size. However, the lack of selectivity considerably limits their application. Consequently, designing functionalized MOFs with specific recognition abilities is essential for enhancing their adsorption performance.

Construction of eco-friendly dual carbon dots ratiometric fluorescence probe for highly selective and efficient sensing mercury ion.

In present work, blue carbon dots (b-CDs) were derived from ammonium citrate and guanidine hydrochloride, and red carbon dots (r-CDs) were stemmed from malonate, ethylenediamine and meso‑tetra (4-carboxyphenyl) porphin based on facile hydrothermal method. Eco-friendly ratiometric fluorescence probe was innovatively constructed to effectively measure Hg utilizing b-CDs and r-CDs. The developed probe displayed two typical emission peaks at 450 nm from b-CDs and 650 nm from r-CDs under the excitation at 360 nm.

The oxidative potential of fine ambient particulate matter in Xinxiang, North China: Pollution characteristics, source identification and regional transport.

Atmospheric fine particulate matter (PM) can trigger the production of cytotoxic reactive oxygen species (ROS), which can trigger or exacerbate oxidative stress and pulmonary inflammation. We collected 111 daily (∼24 h) ambient PM samples within an urban region of North China during four seasons of 2019-2020. PM samples were examined for carbonaceous components, water-soluble ions, and elements, together with their oxidative potential (represent ROS-producing ability) by DTT assay.

Distribution of active ingredients and quality control of Forsythia suspensa with AP-MALDI mass spectrometry imaging.

The fruits of Forsythia suspensa (F. suspensa) have been used as a traditional Chinese medicine for 2000 years. Currently, the quality control of F.

Maximizing pollutant removal and greenhouse gas emission reduction in vertical flow constructed wetlands: an orthogonal experimental approach.

Owing to the impact of the effluent C/N from the secondary structures of urban domestic wastewater treatment plants, the denitrification efficiency in constructed wetlands (CWs) is not satisfactory, limiting their widespread application in the deep treatment of urban domestic wastewater. To address this issue, we constructed enhanced CWs and conducted orthogonal experiments to investigate the effects of different factors (C/N, fillers, and plants) on the removal of conventional pollutants and the reduction of greenhouse gas (GHG) emission. The experimental results indicated that a C/N of 8, manganese sand, and calamus achieved the best denitrification efficiencies with removal efficiencies of 85.

Exploration of chemical components and metabolite synthesis pathways in eight species based on HS-GC-MS and UPLC-Q-TOF-MS.

Objective: , widely used in clinical practice as a medicinal herb, belongs to the genus in the family Ephedraceae. However, the presence of numerous varieties and variants requires differentiation for accurate identification.

Methods: In this study, we employed headspace gas chromatography mass spectrometry (HS-GC-MS), ultra-high performance liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (UPLC-Q-TOF-MS), and global natural products social molecular networking (GNPS) for chemical component identification.

Different regulation strategies of anaerobic digestion by AC/CaO and FeO/CaO: Reactive oxygen species induction, methanogenic performance, and microbial response.

This study examined the combination of activated carbon and magnetite with calcium peroxide in enhancing the anaerobic digestion (AD) performance of food waste (FW). The individual mechanisms of these two approaches were also clarified. The results indicated that AC/CaO achieved the highest specific methane yield of 434.

The Influence of Rhenium Content on Helium Desorption Behavior in Tungsten-Rhenium Alloy.

To investigate the influence of different rhenium contents on the helium desorption behavior in tungsten-rhenium alloys, pure tungsten and tungsten-rhenium alloys were irradiated with helium under the same conditions. All irradiated samples were characterized using TDS and DBS techniques. The results indicate that the addition of rhenium can reduce the total helium desorption quantity in tungsten-rhenium alloys and slightly accelerate the reduction in the concentration of vacancy-type defects accompanying helium dissociation.

Fast and eco-friendly synthesis of carbon dots from pinecone for highly effective detection of 2,4,6-trinitrophenol in environmental samples.

2,4,6-Trinitrophenol (TNP) has high explosive risks and biological toxicity, and there has been considerable concern over the determination of TNP. In the present work, fluorescent carbon dots (CDs) stemmed from a green carbon source of pinecone by the facile hydrothermal approach. A novel environment- friendly fluorescent probe was developed to efficiently detect TNP by using the obtained CDs with remarkable fluorescence stability.

The association between parental warmth and children's prosocial behaviour: A moderated mediation analysis.

Prosocial behaviour is a bedrock of humane societies. Although previous studies have shown that parental style is an important contributing factor for children's prosocial behaviour, the psychological mechanism underlying this association in specific cultural background remains unclear. Based on the ecological systems theory, this study sought to explore the influence of parental warmth on children's prosocial behaviour, and the mediating effect of self-efficacy, as well as the moderating role of teachers' incentive evaluation in the link between self-efficacy and children's prosocial behaviour.

Exploring the Effects of Nano-CaCO on the Core-Shell Structure and Properties of HDPE/POE/Nano-CaCO Ternary Nanocomposites.

To address the dilemma of the stiffness and toughness properties of high-density polyethylene (HDPE) composites, titanate coupling agent-treated CaCO nanoparticles (nano-CaCO) and ethylene-octene copolymer (POE) were utilized to blend with HDPE to prepare ternary nanocomposites via a two-sequence-step process. Meanwhile, a one-step process was also studied as a control. The obtained ternary nanocomposites were characterized by scanning electron microscopy (SEM), Advanced Rheometrics Expansion System (ARES), Dynamic Mechanical Analysis (DMA), wide-angle X-ray diffraction analysis (WXRD), and mechanical test.