Int J Environ Res Public Health
March 2022
Four types of tourmalines (TMs, S1, S2, S3 and S4) for activating persulfate (PS) to degrade sulfamethazine (SMT) were compared to find the most efficient catalyst. The four TMs were mesoporous materials with abundant functional groups, but were different in terms of size, composition, specific surface area, contact angle, and zero potential point. The removal of SMT in S1, S2, S3 and S4 systems with PS at the optimum reaction conditions ([SMT] = 5 mg/L, [PS] = 4 mM, [TM] = 5 g/L, pH = 5, and T = 25 °C) were 99.
View Article and Find Full Text PDFSulfate radical based advanced oxidation processes have been extensively studied for the degradation of environmental contaminants. Iron-based materials such as ferrous, ferric, ZVI, iron oxides, sulfides etc., and various natural iron minerals have been explored for activating persulfate to generate sulfate radicals.
View Article and Find Full Text PDFThe application of laboratory-generated biochar and activated carbon adsorbents in gold iodized solution for the recycling of waste mobile phone printed circuit boards (WMPCBs) is investigated. This research aims to solve problems associated with the existing gold recovery technologies of WMPCBs. Currently, the disposal of WMPCBs is expensive, involves complex processes, and contributes to secondary pollution.
View Article and Find Full Text PDFThis study investigated the removal of Orange II by an electro-Fenton process using a novel recirculation flow-through reactor. The hydrogen peroxide was generated in-situ on the activated carbon fiber (ACF) modified with carbon black and polytetrafluoroethylene (PTFE). The modified ACF cathode was characterized by scanning electron microscopy (SEM) and nitrogen adsorption-desorption study.
View Article and Find Full Text PDFNorth China Plain area (NCP) is one of the most densely populated and heavily polluted regions in the world. In the last five years, frequently happened fine particulate matter (PM) serious pollution events were one of the top environmental concerns in China. As PM concentrations are highly influenced by synoptic flow patterns and local meteorological conditions, a two-stage hierarchical clustering method based on dynamic principal component analysis (DPCA) and standard k-means clustering algorithm was employed to classify synoptic wind fields into 6 patterns over the NCP area using the data of 5 PM seasons (Sept.
View Article and Find Full Text PDFThe present work studied, for the first time, the removal of organic pollutants from a high-salinity reverse osmosis (RO) concentrate by electro-Fenton approach using a graphite-felt as cathode. To gain insights into the process, the in situ generation of hydrogen peroxide was also investigated. The COD removal efficiency and energy consumption were optimized by investigating the effects of some important operating parameters such as ferric ion concentration, initial pH and cathodic potential.
View Article and Find Full Text PDFSpherical silver and gold nanoparticles with narrow size distributions were conveniently synthesized in aqueous solution by a novel electrochemical method. The technological keys to the electrochemical synthesis of monodispersed metallic nanoparticles lie in the choice of an ideal stabilizer for the metallic nanoclusters and the use of a rotating platinum cathode. Poly(N-vinylpyrrolidone) (PVP) was chosen as the stabilizer for the silver and gold clusters.
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