PVA-enhanced green synthesis of CMC-based lithium adsorption films.

The titanium-based lithium ion sieve (HTO), renowned for its exceptional adsorption performance and cyclic stability, was utilized in addressing the global shortage of lithium resources. However, the recovery and reuse efficiency of HTO in powder form is relatively low, which limits its application in industrial fields. To address this issue, this study utilized carboxymethyl cellulose (CMC) as the principal matrix material, while polyvinyl alcohol (PVA) played a dual function as both matrix and crosslinker, negating the necessity for supplementary crosslinking materials.

High-Strength, Thermally Stable, and Processable Wood Fiber/Polyamide Composites for Engineering Structural Components.

Hybrid wood fiber/plastic composites offer a high-value-added utilization for agroforestry waste, which also providing a promising solution for reducing white pollution. However, the interface incompatibility between natural wood fibers and polymers significantly impairs the mechanical properties of the composites. Herein, a straightforward procedure is proposed to solve this problem, involving the removal of low-thermal-stability hemicellulose from wood fibers by hydrothermal pretreatment, followed by compositing with polyamide to produce hydrothermally treated wood fiber/polyamide composites (HWPACs).

Double-layer carboxymethyl chitosan/sulfoethylated cellulose/cellulose nanofiber foams with a photothermally enhanced ionic concentration gradient for hydrovoltaic energy harvesting.

The generation of electricity from water, which contains enormous amounts of energy, has attracted significant attention in recent years. However, the development of devices consisting of materials with the required mechanical stability, suitable structures, and wide ion concentration gradients for operation in direct contact with water remains challenging. Herein, we report the preparation of three-dimensional foam structures based on covalent cross-linking and freeze-drying using cellulose and chitosan derivatives as raw materials.

The expression and clinical significance of ARHGAP25 in osteosarcoma based on bioinformatics analysis.

ARHGAP25, a member of the ARHGAP family, encodes a negative regulator of Rho-GTPase that is important for actin remodeling, cell polarity, and cell migration. ARHGAP25 is down-regulated in a variety of solid tumors and promotes cancer cell growth, migration, and invasion. However, nothing is understood about ARHGAP25's biological function in osteosarcoma.

Cellulose nanocrystal thermal smart molecular brushes with upper critical aggregation temperature.

Grafting thermo-responsive polymers onto cellulose nanocrystals (CNCs) and achieving critical temperature regulation has drawn significant research interest. The thermal transition behavior of CNCs can be controlled by adjusting the polymer molecular brushes on the CNCs surface. We synthesized poly((2-dimethylamino) ethyl methacrylate) (PDMAEMA) grafted CNCs via surface-initiated reversible addition-fragmentation chain transfer, followed by modifying PDMAEMA brushes into poly-3-dimethyl(methacryloyloxyethyl) ammonium propane sulfonate (PDMAPS) brushes via quaternization.

Finite Element Analysis of the Effect of Femoral Prosthesis Varus and Valgus Angle Installation on the Lateral Compartment in Unicompartmental Knee Arthroplasty.

Background: This study used finite element analysis (FEA) to investigate the effect of varus and valgus angle on the lateral compartment in unicompartmental knee arthroplasty (UKA).

Methods: One patient who underwent UKA was enrolled as the subject. Thirteen working conditions of the femoral prosthesis were simulated at varus and valgus angles of 0°, 2°, 4°, 6°, 8°, 10°, and 12°.

In situ growth of Zr-based metal-organic frameworks on cellulose sponges for Hg and methylene blue removal.

Metal-organic frameworks (MOFs) are characterised by high porosity levels and controllable structures, making them ideal adsorbents for wastewater. However, obtaining substrate materials with mechanical stability, excellent pore accessibility, and good processability for compositing MOF crystal powders to adsorb multiple pollutants in complex aqueous environments is challenging. In this study, porous MOFs@ modified cellulose sponge (MCS) composites were fabricated using MCS as a scaffold to provide anchoring sites for the coordination of Zr ions and further in situ synthesis of MOFs, namely UiO-66@MCS and UiO-66-NH@MCS, which effectively removed heavy metal ions and organic dyes.

Water quality improvement project for initial rainwater pollution and its performance evaluation.

Efficiently addressing initial rainwater pollution is crucial for mitigating urban water pollution. However, the performance evaluation of initial rainwater pollution control project is rarely introduced. In this study, the architecture of effective comprehensive engineering measures for improving the water quality of initial rainwater in Anhui Province, China, was described.

Water quality variation and driving factors quantitatively evaluation of urban lakes during quick socioeconomic development.

Rapid urbanisation has caused a significant impact on the ecological environment of urban lakes in the world. To maintain the harmonious development of urban progress and water quality, it is essential to evaluate water quality variation and explore the driving factors quantitatively. A comprehensive evaluation method with cluster analysis and Kriging interpolation was used to explore the spatiotemporal variation in a typical urban lake in China, Chaohu Lake, from 2011 to 2020.

Pollution source identification and abatement for water quality sections in Huangshui River basin, China.

Accurately obtaining the pollution sources and their contribution rates is the basis for refining watershed management. Although many source analysis methods have been proposed, a systematic framework for watershed management is still lacking, including the complete process of pollution source identification to control. We proposed a framework for identification and abatement of pollutants and applied in the Huangshui River Basin.

Co-assembly of stearoylated cellulose nanocrystals and GO (or CNTs) for the construction of superhydrophobic hierarchical structure with enhanced photothermal conversion.

The development of photothermal materials with high photothermal-conversion efficiencies is important in a range of applications, such as power generation, sterilization, desalination, and energy-production. To date, a few reports have been published related to improving the photothermal conversion performances of photothermal materials based on self-assembled nanolamellae. Herein, hybrid films of co-assembled stearoylated cellulose nanocrystals (SCNCs) and polymer-grafted graphene oxide (pGO)/polymer-grafted carbon nanotubes (pCNTs) were prepared.

Decoupling in international business: The 'new' vulnerability of globalization and MNEs' response strategies.

What can MNEs learn from the COVID-19 pandemic? IB scholars have provided ample insights into this question with many focusing on risk management. Complementing these insights, we argue that MNEs should also consider the long-lasting effect that COVID-19, had on the institutional logic underlying globalization. The U.

Combined analysis of multi-omics reveals the potential mechanism of flower color and aroma formation in .

Introduction: Maiden & Betche is a domesticated high-value nut crop. The development of nut flower affects the fruit setting rate, yield and quality of nuts. Therefore, in this experiment, two varieties with different flower color, flowering time, flowering quantity and nut yield (single fruit weight) were selected as the research objects.

Scale effects of land use on river water quality: a case study of the Tuojiang River Basin, China.

Assessing the scale effects of land use on water quality is of great significance for effectively controlling nonpoint source (NPS) pollution in river basins. In this study, redundancy analysis (RDA) and stepwise multiple linear regression (SMLR) analysis were applied to assess the effects of land use on water quality across multiscales in the Tuojiang River Basin. All monitoring sections were classified into three groups according to the characteristics of land use and cluster analysis of water quality.

Click chemistry-induced modification of acrylated cellulose nanocrystals for application in PVA-based nanocomposites.

The surface functionalization of cellulose nanocrystals (CNC) is crucial for promoting their diverse applications, especially regarding their use as sustainable biobased polymer reinforcements. In this study, we develop poly (vinyl alcohol) (PVA)-CNC composites with improved tensile strength and gas-barrier performance using CNC-based nanofillers. Acrylated CNCs (ACNCs) were prepared from cellulose via one-pot acid hydrolysis/Fischer esterification; subsequently, surface modification was performed through a thiol-ene reaction to obtain surface-thiolated ACNCs, namely, DACNC, MACNC, and PACNC.

Flexible Janus wood membrane with asymmetric wettability for high-efficient switchable oil/water emulsion separation.

Janus membranes have attracted much attention for switchable oil/water separation because they have opposite wetting behavior on each side. However, it remains a challenge to fabricate Janus membranes with asymmetric wettability from biomass by simple methods. Herein, we prepared a flexible Janus wood (JW) membrane by cutting the natural wood along the longitudinal direction, followed by a facile top-down approach.

Water-Quality Assessment and Pollution-Risk Early-Warning System Based on Web Crawler Technology and LSTM.

The openly released and measured data from automatic hydrological and water quality stations in China provide strong data support for water environmental protection management and scientific research. However, current public data on hydrology and water quality only provide real-time data through data tables in a shared page. To excavate the supporting effect of these data on water environmental protection, this paper designs a water-quality-prediction and pollution-risk early-warning system.

Comparative analysis of water quality prediction performance based on LSTM in the Haihe River Basin, China.

As the most water shortage and water polluted area in China, the water quality prediction is of utmost needed and important in Haihe River Basin for its water resource management. The long short-term memory (LSTM) has been a widely used tool for water quality forecast in recent years. The performance and adaptability of LSTM for water quality prediction of different indicators needs to be discussed before it adopted in a specific basin.

Flexoelectricity-Enhanced Photovoltaic Effect in Self-Polarized Flexible PZT Nanowire Array Devices.

In this investigation, we report the flexoelectricity-enhanced photovoltaic (FPV) effect in a flexible Pb(ZrTi)O nanowire (PZT NW) array/PDMS (polydimethylsiloxane) nanocomposite. The simulation result of density functional theory (DFT) indicated that the FPV effect in PZT NWs can be greatly affected by the interactions of the strain gradients with the internal field generated by self-polarization. We found that when the nanocomposite film was curved down, the photovoltaic current of the aligned PZT-NW/PDMS composite increased by 84.

Spatiotemporal heterogeneities and driving factors of water quality and trophic state of a typical urban shallow lake (Taihu, China).

Water quality deterioration and eutrophication of urban shallow lakes are global ecological problems with increasing concern and greater environmental efforts. In this study, spatiotemporal changes of water quality and eutrophication were assessed by trophic level index (TLI), cluster analysis, and spatial interpolation methods in Lake Taihu and its sub-lakes from 2015 to 2019. Results showed that the Taihu had poor water quality and maintained a light-eutropher state overall, mainly astricted by the total nitrogen (TN) and the total phosphorus (TP).

Aliphatic chains grafted cellulose nanocrystals with core-corona structures for efficient toughening of PLA composites.

To promote the replacement of nondegradable petrochemical-based polymers with green polylactic acid (PLA) materials, aliphatic chains-grafted cellulose nanocrystals (ECNCs) were prepared and used as nanofillers to overcome the disadvantage of poor toughness of PLA. ECNCs with core-corona structures were obtained by modifying cellulose nanocrystals (CNC) with valeryl chloride, octanoyl chloride, dodecanoyl chloride, and stearoyl chloride. ECNCs consists of a cellulose crystalline core and a soft esterified corona layer with aliphatic chains.

Basin-Scale Pollution Loads Analyzed Based on Coupled Empirical Models and Numerical Models.

Pollutant source apportionment is of great significance for water environmental protection. However, it is still challenging to accurately quantify pollutant loads at basin-scale. Refined analytical methods combined the pollution discharge coefficient method (PDCM), field observation, and numerical model (Soil & Water Assessment Tool, SWAT) to make quantitative source appointment in the Tuojiang River, a key tributary of the upper Yangtze River.

Spatial-temporal distribution and evolutionary characteristics of water environment sudden pollution incidents in China from 2006 to 2018.

Sudden water pollution incidents (SWPI) are random and harmful, which is a problem that cannot be ignored in ecological environment governance and economic development. Identifying spatial-temporal distribution characteristics of SWPI is essential for the disaster prevention and the early warning of water environment. The Kernel Density (DE) and spatial mean center of SWPI transfer curve were used to explore the characteristics with the dataset of 1174 cases from 2006 to 2018 in China.

Effect of a deep learning-based system on the miss rate of gastric neoplasms during upper gastrointestinal endoscopy: a single-centre, tandem, randomised controlled trial.

Background: White light endoscopy is a pivotal first-line tool for the detection of gastric neoplasms. However, gastric neoplasms can be missed during upper gastrointestinal endoscopy due to the subtle nature of these lesions and varying skill among endoscopists. Here, we aimed to evaluate the effect of an artificial intelligence (AI) system designed to detect focal lesions and diagnose gastric neoplasms on reducing the miss rate of gastric neoplasms in clinical practice.

HTO/Cellulose Aerogel for Rapid and Highly Selective Li Recovery from Seawater.

To achieve rapid and highly efficient recovery of Li from seawater, a series of HTiO/cellulose aerogels (HTO/CA) with a porous network were prepared by a simple and effective method. The as-prepared HTO/CA were characterized and their Li adsorption performance was evaluated. The obtained results revealed that the maximum capacity of HTO/CA to adsorb Li was 28.