MoS coupled with ball milling co-modified sludge biochar to efficiently activate peroxymonosulfate for neonicotinoids degradation: Dominant roles of SO, O and surface-bound radicals.

An efficient catalyst of molybdenum disulfide (MoS) coupled with ball milling modified sludge biochar (BMSBC) was prepared to efficiently activate peroxymonosulfate (PMS) for neonicotinoids elimination. As expected, 95.1% of imidacloprid (IMI) was degraded by PMS/BMSBC system within 60 min and it was accompanied by the outstanding mineralization rate of 71.

Ferrate (VI) oxidation of sulfamethoxazole enhanced by magnetized sludge-based biochar: Active sites regulation and degradation mechanism analysis.

Developing non radical systems for antibiotic degradation is crucial for addressing the inefficiency of conventional radical systems. In this study, novel magnetic-modified sludge biochar (MASBC) was synthesized to significantly enhance the oxidative degradation of sulfamethoxazole (SMX) by ferrate (Fe (VI)). In the Fe (VI)/MASBC system, 90.

Hydrothermal N-doping, magnetization and ball milling co-functionalized sludge biochar design and its selective adsorption of trace concentration sulfamethoxazole from waters.

This study aimed to design an efficient and easily collected/regenerated adsorbent for trace concentration sulfamethoxazole (SMX) removal to eliminate its negative impacts on human health, reduce the risk of adsorbed SMX release and boost the reusability of adsorbent. Various multiple modified sludge-derived biochars (SBC) were synthesized in this work and applied to adsorb trace level SMX. The results demonstrated that hydrothermal N-doping, magnetization coupled with ball milling co-functionalized SBC (BMNSBC) displayed the greater adsorption ability for SMX.

Efficient degradation of sulfadiazine by UV-triggered electron transfer on oxalic acid-functionalized corn straw biochar for activating peroxyacetic acid: Performance, mechanism, and theoretical calculation.

A novel UV/oxalic acid functionalized corn straw biochar (OCBC)/peroxyacetic acid (PAA) system was built to degrade sulfadiazine from waters. 94.7 % of SDZ was removed within 30 min by UV/OCBC/PAA.

In situ activation of peroxymonosulfate with bioelectricity for sulfamethoxazole sustainable removal.

Conventional electrochemical activation of peroxymonosulfate (PMS) is not very cost-effective and practical by the excessive input of energy. The electricity generated by photosynthetic microalgae fuel cells (MFCs) is utilized to activate PMS, which would achieve the combination of green bioelectricity and advanced oxidation processes for sustainable pollutants degradation. In this study, a novel dual-chamber of MFCs was constructed by using microalgae as anode electron donor and PMS as cathode electron acceptor, which was operating under both close-circuit and open-circuit conditions.

Spatiotemporal variation, fluxes and risk evaluation of neonicotinoid insecticides within the midsection of Yangtze River, China: An exploration as ecological protection threshold.

Neonicotinoid insecticides (NNIs) have attracted global concern due to its extensive use in agricultural activities and their potential risks to the animal and human health, however, there is limited knowledge on the regional traits and ecological risks of NNIs in the aquatic environments. We herein investigated the occurrence of NNIs within the midsection of Yangtze River in China, offering the inaugural comprehensive report on NNIs within this region. In this study, eleven NNIs were analyzed in 108 river water and sediment samples from three seasons (normal, dry and wet season).

Facile synthesis of ball-milling and oxalic acid co-modified sludge biochar to efficiently activate peroxymonosulfate for sulfamethoxazole degradation: O and surface-bound radicals.

A novel approach of ball milling and oxalic acid was employed to modify sludge-based biochar (BOSBC) to boost its activation performance for peroxymonosulfate (PMS) towards efficient degradation of sulfamethoxazole (SMX). 98.6% of SMX was eliminated by PMS/BOSBC system within 60 min.

Annual flux estimation and source apportionment of PCBs and PBDEs in the middle reach of Yangtze River, China.

This work is the first time to investigate the annual flux, spatiotemporal changes and sources of PCBs and PBDEs in water and sediment from the middle reach of Yangtze River (Wuhan, China), which was particularly based on the monthly monitoring data in a one-year-round study. The concentrations of PCBs and PBDEs in water were View Article and Find Full Text PDF

One-pot preparation of layered double oxides-engineered biochar for the sustained removal of tetracycline in water.

Tetracycline (TC) and sugarcane bagasse had both exerted enormous strain on environmental security. In this work, new composite adsorbent designed by impregnating bio-waste bagasse with magnesium-aluminum layered double oxides (BC-MA) was innovatively brought forward for TC removal. Benefiting from the abundant adsorption sites supplied by developed pores structure (0.

Spatiotemporal distribution, sources apportionment and ecological risks of PAHs: a study in the Wuhan section of the Yangtze River.

This study investigated the sources, contamination and ecological risks of polycyclic aromatic hydrocarbons (PAHs) based on their spatiotemporal distribution in aquatic environment in the Wuhan section of the Yangtze River (WYR). The fugacity ratio evaluation indicated that sediment was secondary release sources of two- and three-ring PAHs and sinks of four- and five-ring PAHs. The total concentrations of PAHs (ΣPAHs) ranged from 2.

Efficient degradation of sulfamethoxazole in various waters with peroxymonosulfate activated by magnetic-modified sludge biochar: Surface-bound radical mechanism.

First time, this study synthesized a magnetic-modified sludge biochar (MSBC) as an activator of peroxymonosulfate (PMS) to eliminate sulfamethoxazole (SMX). The removal efficiency of SMX reached 96.1% at t = 60 min by PMS/MSBC system.

Estimating Sources, Fluxes, and Ecological Risks of Antibiotics in the Wuhan Section of the Yangtze River, China: A Year-Long Investigation.

To our knowledge, ours is the first study to investigate the annual fluxes, environmental fate, and ecological risks of five categories of antibiotics from the Wuhan section of the Yangtze River (China). All the 24 antibiotics we tested for were detected in water, with total concentrations of 17.11-867.

Fe-Al bimetallic oxides functionalized-biochar via ball milling for enhanced adsorption of tetracycline in water.

The clusters formed by modified materials on its surface makes the application of functionalized biochars in adsorption face a great challenge. Here, a facile ball milling technology was innovatively proposed to tailor Fe-Al oxides-laden bagasse biochar to fabricate a novel adsorbent (BMFA-BC). Benefited from the increased exposure of Fe-Al oxides and, more importantly, enhanced functional groups by ball milling, the adsorption capacity of BMFA-BC for aqueous tetracycline reached up to 116.

Ball milling and acetic acid co-modified sludge biochar enhanced by electrochemistry to activate peroxymonosulfate for sustainable degradation of environmental concentration neonicotinoids.

Neonicotinoids pose potential serious risks to human health even at environmental concentration and their removal from water is considered as a great challenge. A novel ball milling and acetic acid co-modified sludge biochar (BASBC) was the first time synthesized, which performed superior physicochemical characteristics including larger surface area, more defect structures and functional groups (e.g.

Molten-salts assisted preparation of iron-nitrogen-carbon catalyst for efficient degradation of acetaminophen by periodate activation.

Highly efficient and stable heterogeneous catalysts were desired to activate periodate (PI) for sustainable pollution control. Herein, iron-nitrogen-carbon catalyst was synthesized using a facile molten-salts mediated pyrolysis strategy (denoted as FeNC-MS) and employed to activate PI for the degradation of acetaminophen (ACE). Compared with iron-nitrogen-carbon catalyst prepared by direct pyrolysis method (marked as FeNC), FeNC-MS exhibited superior catalytic activity due to its large specific surface area (1600 m g) and the abundance of FeN sites.

Removal of cadmium in aqueous solutions using a ball milling-assisted one-pot pyrolyzed iron-biochar composite derived from cotton husk.

A novel iron-biochar composite adsorbent was produced via ball milling-assisted one-pot pyrolyzed BM-nZVI-BC 800. Characterization proved that nano zero valent iron was successfully embedded in the newly produced biochar, and the nZVI payload was higher than that of traditional one-pot pyrolyzed methods. BM-nZVI-BC 800 provided a high adsorption performance of cadmium reaching 96.

Understanding the nonradical activation of peroxymonosulfate by different crystallographic MnO: The pivotal role of Mn content on the surface.

Manganese oxide-activated persulfate plays a critical role in water purification and in situ chemical oxidation processes, but the underlying mechanism needs to be further revealed. Herein, the detailed mechanism of MnO with various crystallographic structures (α-, β-, γ-, and δ-MnO) towards peroxymonosulfate (PMS) activation was investigated. PMS activated by tunnel structured α-, β-, and γ-MnO showed higher acetaminophen (ACE) removal than layer structured δ-MnO with the removal efficiency following an order of α-MnO (85%) ≈ γ-MnO (84%) > β-MnO (65%) > δ-MnO (31%).

Efficient removal of Imidacloprid and nutrients by algae-bacteria biofilm reactor (ABBR) in municipal wastewater: Performance, mechanisms and the importance of illumination.

Neonicotinoids, such as Imidacloprid (IMI), are frequently detected in water and wastewater, posing a threat on both the environment and the health of living things. In this work, a novel algae-bacteria biofilm reactor (ABBR) was constructed to remove IMI and conventional nutrients from municipal wastewater, aiming to explore the removal effect and advantage of ABBR. Results showed that ABBR achieved 74.

Insights on ball milling enhanced iron magnesium layered double oxides bagasse biochar composite for ciprofloxacin adsorptive removal from water.

Both ciprofloxacin (CIP) and sugarcane bagasse have brought enormous pressure on environmental safety. Here, an innovative technique combining Fe-Mg-layered double oxides and ball milling was presented for the first time to convert bagasse-waste into a new biochar adsorbent (BM-LDOs-BC) for aqueous CIP removal. The maximum theoretical adsorption capacity of BM-LDOs-BC reached up to 213.

Novel insights into the mechanism of periodate activation by heterogeneous ultrasonic-enhanced sludge biochar: Relevance for efficient degradation of levofloxacin.

In this study, a novel heterogeneous ultrasonic (US)-enhanced sludge biochar (SBC) activated periodate (PI) system was established and explored for the rapid removal of levofloxacin in the aqueous environment. This study focused on the mechanisms of US-enhanced SBC co-activation of PI for levofloxacin degradation. The results indicated that US and SBC exhibited a remarkable synergistic reinforcing activation effect on PI compared to single PI activation systems.

Efficient adsorptive removal of fluoroquinolone antibiotics from water by alkali and bimetallic salts co-hydrothermally modified sludge biochar.

Fluoroquinolones are one of most commonly used antibiotics for preventing and treating bacterial infections and their unsatisfactory removal by conventional wastewater treatment technology have aroused widespread attention. A novel adsorbent of KMSBC was the first time synthesized and tested to adsorb three typical fluoroquinolone antibiotics of CIP, NOR and OFL from water. The characterization analysis showed that KMSBC possessed the superior porous structure, abundant functional groups and greater graphitic degree.

Nitrogen concentration acting as an environmental signal regulates cyanobacterial EPS excretion.

As an important carbon (C) storage in biological soil crusts (BSCs), exopolysaccharides (EPSs) are not only a part of the desert C cycle, but also the key materials for cyanobacteria to resist desert stress. In this study, the influence of initial N concentrations (10, 25 and 50 mg L designated as N10, N25 and N50 respectively) on Microcoleus vaginatusis growth and the excretion of EPSs including RPS (released exopolysaccharides) and CPS (capsule exopolysaccharides) were evaluated at different growth periods. In logarithmic period, higher ratio of biomass to EPSs indicated by (DW-CPS)/EPSs was observed in the N50 group with the highest N concentration (about 40 mg L) in the medium, while no difference was observed among the three groups in stationary period when the N concentrations of medium were lower than 25 mg L.

An efficient, green and sustainable potassium hydroxide activated magnetic corn cob biochar for imidacloprid removal.

The extensive use of imidacloprid (IMI) has led to its being frequently detected in natural water, also caused the potential damage to the ecosystem. Development of efficient, green and sustainable technique is demanded to eliminate this problem. A novel biochar (KMCBC) derived from agriculture waste of corn cob was first time co-modified by potassium hydroxide (KOH), ferric chloride (FeCl) and zinc chloride (ZnCl), which showed the greater adsorption amount (410 mg g at 298 K) for imidacloprid (IMI).

Efficient degradation of diclofenac sodium by periodate activation using Fe/Cu bimetallic modified sewage sludge biochar/UV system.

Iron/copper bimetallic nanoparticles based sludge biochar (Fe/Cu-SBC) was prepared by using a modified co-precipitation route. The Fe/Cu-SBC system prepared was subsequently applied to activate periodate (IO) to degrade diclofenac sodium (DCF) by using UV light at room temperature (25 °C). The physicochemical properties of both SBC and Fe/Cu-SBC such as morphology, physical properties, crystal structures and functional groups were examined.