Unlabelled: Zur (zinc uptake regulator) is a significant member of the Fur (ferric uptake regulator) superfamily, which is widely distributed in bacteria. Zur plays crucial roles in zinc homeostasis and influences cell development and environmental adaptation in various species. is a Gram-negative enteric that pathogen usually serves as a model organism in pathogenicity studies.
View Article and Find Full Text PDFHydrogen autotrophic bioreduction of antimonate (Sb(V)) to antimonite (Sb(III)) is an alternative approach for removing antimony (Sb) from water. This study investigated Sb(V) reduction kinetics and the effects of various parameters on the Sb(V) removal performance in a hydrogen autotrophic reaction system (HARS). Sb(V) reduction in the HARS was well fitted to the Michaelis-Menten model, showing a positive correlation between the reaction rate and biomass.
View Article and Find Full Text PDFAntimony (Sb), a toxic metalloid, has serious negative effects on human health and its pollution has become a global environmental problem. Bio-reduction of Sb(V) is an effective Sb-removal approach. This work, for the first time, demonstrates the feasibility of autotrophic Sb(V) bio-reduction and removal coupled to anaerobic oxidation of elemental sulfur (S).
View Article and Find Full Text PDFIn this study, sycamore flocs (SF), which caused environmental and health problems, were utilized to prepare biochar. SFB obtained under the conditions of activation agent KCO, pyrolysis temperature 900℃ and m(KCO):m(BC) 2 had the strongest adsorption capacity (730 mg/g) for oxytetracycline hydrochloride (OTC-HCl). The pseudo-second-order kinetic model and Langmuir model described the adsorption kinetics and isotherms best.
View Article and Find Full Text PDFAt present, tetracycline hydrochloride (TCH) is a widely used antibiotic, and is often detected in water, posing a serious harm to human and ecological health. In this study, spent bleaching earth (SBE) was pyrolyzed to obtain spent bleaching earth carbon (SBE@C) and the nano Fe/SBE@C prepared after zero-valent iron loading was adopted to remove TCH in water for the first time. The combination of nano Fe/SBE@C and PS, the strong adsorption of SBE@C coupled with the oxidation of free radicals could achieve TCH efficient removal.
View Article and Find Full Text PDFThe sulfur autotrophic reduction (SAR) process is promising in co-reduction of perchlorate and nitrate from aqueous solution. To further understand the reaction process, we developed a sulfur autotrophic fluidized bed reactor where the proceeding extent of sulfur (S) disproportionation was predicted by Response surface methodology (RSM) for the first time. Three fundamental reaction parameters including the hydraulic retention time (HRT), co-existing nitrate concentration ([Formula: see text]) and recirculation ratio (R) were considered for reactor optimization.
View Article and Find Full Text PDFIn this study, the novel mesoporous carbonized material (HSBE/C) was prepared from clay/carbon composite (SBE/C) treated with hydrofluoric acid (HF) for the first time, and was employed to efficiently adsorb bisphenol A (BPA) in water. Specifically, SBE/C was derived from the pyrolysis of spent bleaching earth (SBE), an industrial waste. HF removed SiO from SBE/C and increased the specific surface area of HSBE/C (from 100.
View Article and Find Full Text PDFIn this study, the synergetic adsorption and Fenton-like degradation of tetracycline hydrochloride (TCH) by magnetic spent bleaching earth carbon (Mag-SBE@C) with HO were developed and performed, with 91.5% of TCH degradation efficiency and 42.1% of TOC removal efficiency.
View Article and Find Full Text PDFThe environmentally friendly clay/carbon composite (SBE/C) was prepared by one-step pyrolysis under N atmosphere at 700°C of spent bleaching earth (SBE) from the industrial waste of the refined oil industry. SBE/C was tested to remove anionic dye Eosin Y from aqueous water. The results revealed that SBE/C had larger specific surface area than SBE, and the equilibrium adsorption capacity of SBE/C (11.
View Article and Find Full Text PDFThis study investigated the effect of a recoverable sulphuric acid and sodium hydroxide-modified pinewood (MOP) as a bulking agent during sewage sludge and sawdust composting (MOPC), with a control experiment using unpretreated pinewood (UNP; UNPC) as the bulking agent. Results show that addition of MOP effectively promoted the degradation of organic matter during composting. The maximum temperature increased by 1.
View Article and Find Full Text PDFThe utilization of spent bleaching earth (SBE)-based materials for adsorption of pollutants from water and wastewater has received growing attention. In this work, a comparative study of magnetic spent bleaching earth carbon (Mag-SBE@C) and spent bleaching earth carbon (SBE@C) was performed to remove tetracycline hydrochloride (TCH) from aqueous solutions. Mag-SBE@C exhibits the larger adsorption capacity (0.
View Article and Find Full Text PDFA combined heterotrophic-sulfur-autotrophic system (CHSAS) was established to simultaneously reduce perchlorate and nitrate in water. In this system, the OH produced by the acetate heterotrophic part (H-part) could be neutralized with the H produced by the sulfur autotrophic part (S-part); thus, the pH of the final effluent could keep neutral. In addition, the S-part could further reduce the pollutants and residual carbon from the H-part to achieve a high performance.
View Article and Find Full Text PDFA novel Moving-Bed Biofilm Reactor (MBBR), based on proton-exchange membrane electrolysis, was developed and tested for perchlorate transformation. The bacteria growing on the carrier in the cathode chamber could use in situ-generated hydrogen to reduce perchlorate to chloride via electrolysis; the resulting chloride ions and chloride ions in raw water were then oxidized into chlorine by anode reaction to disinfect the final effluent and improve water quality. For a ClO concentration of 10.
View Article and Find Full Text PDFIn this study, spent bleaching earth (SBE) and pyrolyzed SBE (SBE@C) were tested for their capacity to remove tetracycline hydrochloride (TCH) from aqueous solution. The maximum adsorption capacity obtained by the Langmuir model is 0.114 mmol/g for SBE@C and 0.
View Article and Find Full Text PDFThis study investigates the sulfur (S) disproportionation tendencies in a sulfur packed bed reactor for perchlorate bio-autotrophic reduction at different temperatures. The reactor was operated with over 99% efficiency for 21.00 ± 1.
View Article and Find Full Text PDFIn this study, cow dung biochar (CDB) and ferric chloride-modified CDB (Fe@CDB) were synthesized to remove low concentration perchlorate from water. The pseudo-second-order kinetics model was used and satisfactorily described perchlorate removal onto CDB and Fe@CDB. The Langmuir model fit the experimental isotherm data better than the Freundlich model.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
June 2018
The 1:1 complexes of two unsaturated esters with 2,2,2-trifluoroethanol (TFE) were investigated experimentally and computationally. The experimental observations of the spectral shifts of the OH-stretching vibrational transitions were obtained at 113cm for TFE-methyl acrylate (MA) and 92cm for TFE-vinyl acetate (VA). There are three docking sites in the two unsaturated esters for the incoming TFE.
View Article and Find Full Text PDFBioprocess Biosyst Eng
January 2018
An anaerobic/aerobic moving-bed biofilm (A/O-MBBR) reactor system was constructed, and the treatment efficiency of aqueous antibiotics in wastewater was investigated. The effects of antibiotics on the microbial communities in the A/O-MBBR were also investigated. Under the optimized reaction conditions, removal of tetracycline antibiotics (TCs) was studied in a series of experiments.
View Article and Find Full Text PDFThis study investigated the simultaneous removal of perchlorate and nitrate from aqueous solution in an up-flow sulfur autotrophic reduction reactor. A nitrate and perchlorate containing pollution solution was treated with a remarkable removal efficiency greater than 97%. The concentration of nitrate was 22.
View Article and Find Full Text PDFHydrogen autotrophic reduction of perchlorate have advantages of high removal efficiency and harmless to drinking water. But so far the reported information about the microbial community structure was comparatively limited, changes in the biodiversity and the dominant bacteria during acclimation process required detailed study. In this study, perchlorate-reducing hydrogen autotrophic bacteria were acclimated by hydrogen aeration from activated sludge.
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