Background: Although matrine is widely used, its absorption and transport mechanisms in crops remain unexplored. In this study, three methods including foliar application, hydroponics and seed immersion were used to investigate whether matrine molecules could enter into plants through different channels, and to further resolve its transport characteristics. The systemic activity of matrine also was evaluated.
View Article and Find Full Text PDFChemical functionalization is essential for tuning the physical-chemical characters and broadening the potential applications of covalent organic frameworks (COFs). Based on the multistep postsynthetic modification strategy, Eu (III)-functionalized 3D COF (Eu-3D-COF) was prepared by grafting of Eu (III) onto the carboxyl-funtionalized 3D-COF (COOH-3D-COF). With micropores dominated microspheres structure, Eu-3D-COF exhibited superior adsorption affinity to multi-rings contained quinones based on the π-π interaction, coordination and hydrogen-bonding interactions, especially to 9,10-phenanthrenequinone (PQ) whose adjacent carbonyl oxygens resulting preferable synergistic chelation interaction with Eu(III) was responsible for the maximum adsorption capacity, which was confirmed by instrumental characterizations.
View Article and Find Full Text PDFWe simulated larval feeding behavior in seed blends of non-Bt and Bt maize to determine if seed blends create more favorable conditions for heterozygous-resistant insects over their Bt-susceptible counterparts. Survival, growth, development, and progeny production of four genotypes of the fall armyworm, Spodoptera frugiperda, Bt-susceptible (aabb), Cry1A.105 heterozygous resistant (Aabb), Cry2Ab2 heterozygous resistant (aaBb), and Cry1A.
View Article and Find Full Text PDFEighteen novel benzamidine derivatives containing 1,2,3-triazole moieties were synthesized. The in vitro and in vivo fungicidal acitivities of the title compounds and the arylamidine intermediates against Colletotrichum lagenarium and Botrytis cinerea were tested. The synthesized benzamidines exhibited weak antifungal activities in vitro against the tested fungi, but some of the compounds showed excellent activities in vivo to the same strains.
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