Pyrethroid insecticides are the most commonly used household insecticides and pose substantial risks to marine aquatic organisms. many studies have detected pyrethroid insecticides in the waters and estuaries of the western United States, but their distributions within western Pacific estuaries have not been reported. Accordingly, we used high-throughput organic analyses combined with high volume solid-phase extraction to comprehensively assess 13 pyrethroid insecticides in East China Sea estuaries and the Huangpu River.
View Article and Find Full Text PDFIt is a challenging issue to investigate the combined pollution of heavy metals and polycyclic aromatic hydrocarbons (PAHs) in urban soils. The purpose of this study was to determine the concentrations of these two pollutants in soils in Shenyang, Fushun, and Fushun New District, to analyze their distribution, their interaction, and co-contamination levels. The concentrations of heavy metals were measured by inductively coupled plasma mass spectrometry (ICP-MS), while the concentrations of 21 kinds of PAH were analyzed by gas chromatography-mass spectrometry (GC-MS).
View Article and Find Full Text PDFChina produced and consumed a large amount of per- and polyfluoroalkyl substances (PFASs). whose persistency and possible toxicity to organisms have raised public health concerns. Analyzing influent wastewater could help to assess the composition and mass load of PFASs discharged into a wastewater treatment plant (WWTP) from its catchment.
View Article and Find Full Text PDFThe Shen-Fu region is an important urban area in northeast China. We report on a study of the distribution of polybrominated diphenyl ethers (PBDEs) in representative topsoil from this region. In the summer of 2016, 72 soil samples from three cities (Shenyang, Fushun, and Shen-Fu New City) were collected, which covered four land use types:urban, rural residential, cultivated, and woodland.
View Article and Find Full Text PDFTo study the vertical distribution characteristics of polycyclic aromatic hydrocarbons (PAHs) in the soils from different land use types during urbanization, three land use types (urban land, cultivated land, and woodland) were selected in the eastern part of Shenyang, where urbanization is occurring rapidly. In each case, five soil samples were obtained from different depths (0-1 m). Change in the concentrations of PAHs, vertical migration factors, and the distribution and sources of PAHs were analyzed in the vertical soil profiles.
View Article and Find Full Text PDFTo protect the safety of water used by the residents in Shen-Fu New City, which is undergoing the process of urbanization, 49 groundwater samples were collected along the Hunhe River Basin and 16 US EPA priority control polycyclic aromatic hydrocarbons (PAHs) were analyzed. The occurrence, distribution characteristics, sources, and potential health risk of drinking the groundwater were also assessed in this study. The results show that PAHs were detected in all samples.
View Article and Find Full Text PDFThe concentration levels, toxic equivalency (TEQ) concentrations, and carcinogenic and non-carcinogenic risks of dioxin-like polychlorinated biphenyls in shore soil from the 40 national key monitoring sections along the entire Yellow River were comprehensively studied. The results showed that the concentrations of Σ in the soil were between 0.37-7.
View Article and Find Full Text PDFTo study the effects of urbanization on concentration, sources, and health risks of polycyclic aromatic hydrocarbons (PAHs), 95 topsoil samples were collected from Liaoning Province. For this assessment, 21 PAHs were analyzed via gas chromatography-mass spectrometry and discussed. The results show the total concentrations of the 21 PAHs in background, Shen-Fu, Shen-Yang, and Fu-Shun were 1496.
View Article and Find Full Text PDFBy investigating the uptake of 16 priority polycyclic aromatic hydrocarbons (PAHs) and five heavy metals from soils to maize at the farmlands with industrial wastewater irrigation, this study revealed the effects of heavy metals on PAHs uptake in terms of co-contamination. The results of 15 investigated soils showed medium contamination level and the vertical PAHs distribution in soils indicated that 2-3 rings PAHs with low octanol-water partition coefficient (log K < 4.5) were easier to transport in soils, causing a great potential risk immigrating to the groundwater.
View Article and Find Full Text PDFThe concentration level of polycyclic aromatic hydrocarbon (PAHs) in topsoil from Shenfu New City in urbanization was studied. 54 topsoil samples were collected from Shenfu New City and 4 different land uses (urban land, rural land, forest land, cultivated land) were included. The concentration of PAHs in different land uses was analyzed, the sources of soil PAHs were analyzed by using diagnostic ratios and principal component analysis, and the ecological risks were calculated using toxic equivalency concentrations of BaP and the incremental lifetime cancer risk(ILCR)model.
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