A Dynamic H-Bonding Network Enables Stimuli-Responsive Color-Tunable Chiral Afterglow Polymer for 4D Encryption.

The development of stimuli-responsive and color-tunable chiral organic afterglow materials has attracted great attention but remains a daunting challenge. Here, a simple yet effective strategy through the construction of a dynamic H-bonding network is proposed to explore the multi-color stimuli-responsive chiral afterglow by doping a self-designed chiral phosphorescent chromophore into a polyvinyl alcohol matrix. A stimuli-responsive deep blue chiral afterglow system with a lifetime of up to 3.

Enabling robust blue circularly polarized organic afterglow through self-confining isolated chiral chromophore.

Creating circularly polarized organic afterglow system with elevated triplet energy levels, suppressed non-radiative transitions, and effective chirality, which are three critical prerequisites for achieving blue circularly polarized afterglow, has posed a formidable challenge. Herein, a straightforward approach is unveiled to attain blue circularly polarized afterglow materials by covalently self-confining isolated chiral chromophore within polymer matrix. The formation of robust hydrogen bonds within the polymer matrix confers a distinctly isolated and stabilized molecular state of chiral chromophores, endowing a blue emission band at 414 nm, lifetime of 3.