Lanthanide terbium complex: synthesis, electrochemiluminescence (ECL) performance, and sensing application.

In this study, a new lanthanide terbium complex, Tb(pzda)3(NO3)3·nH2O, was synthesized by a hydrothermal method and characterized by Fourier transform infrared spectroscopy (FT-IR) and energy-dispersive X-ray spectroscopy (EDS). It was found that the as-synthesized Tb-complex exhibited good electrochemiluminescence (ECL) behavior in the presence of triethanolamine (TEOA) in a HAc-NaAc buffer solution on a glassy carbon electrode. The possible reaction mechanism has been discussed based on the fluorescence spectra and ECL spectra.

Determination of bergenin based on the electrochemiluminescence quenching of tris(2,2'-bipyridine)-ruthenium(II).

Quenching effects of bergenin, based on the electrochemiluminescence (ECL) of the tris(2,2'-bipyridyl)-ruthenium(II) (Ru(bpy)3(2+))/tri-n-propylamine (TPrA) system in aqueous solution, is been described. The quenching behavior can be observed with a 100-fold excess of bergenin over Ru(bpy)3(2+). In the presence of 0.

Determination of p-aminobenzenesulfonic acid based on the electrochemiluminescence quenching of tris (2,2'-bipyridine)-ruthenium (II).

This study describes the quenching effects of p-aminobenzenesulfonic acid (p-ABSA) based on electrochemiluminescence (ECL) of the tris (2,2(') -bipyridyl)-ruthenium(II)(Ru(bpy)3 (2+))/tri-n-propylamine (TPrA) system in aqueous solution. Quenching behaviours were observed with a 200-fold excess of p-ABSA over Ru(bpy)3 (2+). In the presence of 0.

Quenching of the electrochemiluminescence of tris(2,2'-bipyridine)-ruthenium(II) by sodium diphenylamine-4-sulfonate.

Efficient quenching electrochemiluminescence (ECL) of the tris(2,2'-bipyridine)ruthenium(II)/tripropylamine (Ru(bpy)(3)(2+)/TPrA) system by a novel quencher, sodium diphenylamine-4-sulfonate (SDS), has been investigated. The quenching behaviors can be observed with a 100-fold excess of SDS over Ru(bpy)(3)(2+). The mechanism of quenching is believed to involve energy transfer from the excited-state Ru(bpy)(3)(2+*) to the dimer of SDS, which was formed after the electrochemical oxidation of SDS at the electrode surface.