[Synthesis of a novel rare earth light conversion agent and study on its compatibility in plastics].

2-octyl-1, 3-diphenol-1, 3-propdione was synthesized by phase transfer catalysis and its Sm complexes were prepared. These compounds were characterized by IR, EA, UV and 1H NMR; Sm complex and its mixture doped with PE and PVC show photoluminescence at 650 nm. There is excellent compatibility between Sm complex and plastics by the addition of long carbon chain.

[Study on the effect of alpha-allyl on luminescence properties of rare earth complexes with acetylacetone].

3-Allyl-2,4-pentanedione (APD) was synthesized and its rare earth complexes were prepared. The compounds were characterized by EA, IR and 1H NMR. The sensitization of acetylacetone was changed by allyl, which became a novel ligand of Eu.