Impact of cold plasma-assisted Non-thermal deamidation and glycosylation on the construction of sugar derivative-zein conjugates for enhancing pickering foam stability: Technical principles and molecular interactions.

There is an urgent need for stable, plant-based Pickering foams to address the growing consumer demand for sustainable, low-calorie, aerated sweet foods. This study employed a cold plasma-assisted deamidation and glycosylation (CPDG) approach to promote hydrophilic reassembly of zein, resulting in the formation of sugar derivative-zein conjugates. This was accomplished by coupling deamidated zein with polyhydroxy sugars including sucralose (Suc), maltitol (Mal), mannitol (Man), and stevioside (Ste).

Experimental investigation into the Impact of Cyclic High Low Pressure Water Immersion on the Pore structure and Mechanical properties of coal.

The extraction of coal seams with high gas content and low permeability presents significant challenges, particularly due to the extended period required for gas extraction to meet safety standards and the inherently low extraction efficiency. Hydraulic fracturing technology, widely employed in the permeability enhancement of soft and low-permeability coal seams, serves as a key intervention. This study focuses on the high-rank raw coal from the No.

Structural design and evolution of one-dimensional Cu hydrogen-bonded organic framework for catalyzing the rapid decomposition of ammonium perchlorate.

Enhancing the decomposition rate of ammonium perchlorate (AP), the most common oxidizer in solid propellants, is important for improving propellant performance. Metal organic frameworks (MOFs) have been developed as key materials for catalyzing AP decomposition, as they can achieve good dispersion of active sites through in-situ decomposition. Despite having considerable potential, the structural transformation process and catalytic performance of MOFs in AP decomposition are still unclear, which seriously hinders their application in the field of AP decomposition.

Effect of Rice Protein on the Gelatinization and Retrogradation of Rice Starch with Different Moisture Content.

Rice protein and moisture content are pivotal in the gelatinization and retrogradation processes of rice starch. This study aimed to explore the influence of rice protein on these processes by preparing rice starch gels with varying moisture levels and incorporating rice protein. At a high moisture content of 1:6, rice protein exhibited a minimal effect on the gelatinization properties of rice starch but significantly retarded the retrogradation of the starch gel.

Ultrasonic-assisted plasma-activated water extraction of polysaccharide from Hemerocallis citrina Baroni: Structural characterization and antioxidant mechanism in vitro.

Natural polysaccharides derived from Hemerocallis citrina Baroni exhibit significant biological activity. To enhance extraction efficiency and antioxidant activity, ultrasonic-assised plasma-activated water (PAW) was utilized to extract polysaccharides from Hemerocallis citrina Baroni. PAW demonstrated enhanced permeability and diffusion capabilities due to a reduced percentage of fully hydrogen-bonded structures, along with optimal pH (3.

Interfacial Electric Field Enhanced Free-Standing VO/rGO Aerogel Anode with Ultra High Mass Energy Density for Aqueous Ammonium Ion Battery.

Aqueous batteries have become a promising means of energy storage due to its environmental friendliness. Nevertheless, it often exhibits limited energy density that hinder their application. Considering that ammonium ion (NH ) has a low mass and a small hydration radius, aqueous ammonium ion batteries (AAIBs) are expected to solve the problem of low energy density.

Dual modification of cobalt silicate nanobelts by CoO nanoparticles and phosphorization boosting oxygen evolution reaction properties.

Oxygen evolution reaction (OER) process is the "bottleneck" of water splitting, and the low-cost and high-efficient OER catalysts are of great importance and attractive but they are still challenging. Herein, a dual modification strategy is developed to tune and enrich the structure of cobalt silicate (CoSiO) showing boosted OER properties. Cobalt oxide (CoO) decorated CoSiO nanobelts, denoted as CS, is firstly prepared using a Co-based precursor by a facile hydrothermal reaction.

Alkaline electrolyzed water-assisted ultrasonic extraction of lutein from daylily (Hemerocallis spp.): Structural preservation and activity evaluation.

During lutein extraction, isomerization from all-trans to cis form reduced stability and antioxidant capacity. Alkaline electrolyzed water (AEW), with its reduced-state and small molecular clusters, effectively extracted bioactive substances and inhibited oxidation. Thus, an AEW-assisted ultrasonic extraction method was used to extract lutein from daylily.

Tactfully regulating the ESIPT and TICT mechanism in the AIE-active multifunctional triphenylamine Schiff-base compound (TPASB) by methyl substitution.

The triphenylamine Schiff-base (TPASB) with dual proton transfer sites (N…H-O [R1] and N…H-O [R2]), which is crucial in the field of optoelectronic materials. Herein, a novel molecular design strategy for preparing of TPASB-1 and TPASB-2 via the selective methylation of the hydroxyl group at the R2 or R1 position was proposed. The analysis of electronic structures and potential energy surfaces revealed that a single excited state intramolecular proton transfer (ESIPT) process of TPASB occurs only at R1.

Structure engineering of nickel silicate/carbon composite with boosted electrochemical performances for hybrid supercapacitors.

In the wake of the carbon-neutral era, the exploration of innovative materials for energy storage and conversion has garnered increasing attention. While nickel silicates have been a focal point in energy storage research, their application in supercapacitors (SCs) has been relatively underreported due to poor conductivity. A newly designed architecture, designated as rGO@NiSiO@NiO/C (abbreviated for reduced graphene oxide (rGO), nickel silicate (NiSiO), nickel oxide/carbon (NiO/C)), has been developed to enhance the electrochemical performance of NiSiO.

Ring-shaped odor coding in the antennal lobe of migratory locusts.

The representation of odors in the locust antennal lobe with its >2,000 glomeruli has long remained a perplexing puzzle. We employed the CRISPR-Cas9 system to generate transgenic locusts expressing the genetically encoded calcium indicator GCaMP in olfactory sensory neurons. Using two-photon functional imaging, we mapped the spatial activation patterns representing a wide range of ecologically relevant odors across all six developmental stages.

Highly efficient photocatalyst fabricated from the recycling of heavy metal ions in wastewater for dye degradation.

Water pollution and energy crisis are becoming global and strategic issues that people are closely concerned about. Green and energy-saving photocatalytic technology is developing rapidly in solving global energy crises and environmental pollution problems. Therefore, we propose the "kill two birds with one stone" strategy to design efficient photocatalysts for dye wastewater treatment by utilizing heavy metal ions in wastewater.

Surface engineering of zinc plate by self-growth three-dimensional-interconnected zinc silicate nanosheets effectively guiding the deposition of zinc ion for aqueous Zn metal battery.

Among battery technologies, aqueous zinc ion batteries (AZIBs) have hit between the eyes in the next generation of extensive energy storage devices due to their outstanding superiority. The main problem that currently restricts the development of AZIBs is how to obtain stable Zn anodes. In this study, taking the improvement of a series of problems caused by the physically attached artificial interfacial layer on Zn anode as a starting point, a nanosheet morphology of ZnSiO (denoted as ZnSi) is constructed by self-growth on Zn foil (Zn@ZnSi) by a simple hydrothermal reaction.

Topochemical behavior of ferrocene embedded in VO·nHO with weak hydrogen bonding enhancing ammonium-ion storage.

Aqueous ammonium ion batteries (AAIBs) are garnering increasing attention due to their utilization of abundant resources, cost-effectiveness, safety, and unique energy storage mechanism. The pursuit of high-performance cathode materials has become a pressing issue. In this study, we propose and synthesize ferrocene-embedded hydrated vanadium pentoxide (Fer/VOH) for implementation in AAIBs.

Concerning for the solvent-polarity-dependent conformational equilibrium and ESIPT mechanism in Pz3HC system: A novel insight.

In this report, we propose a new insight into the interaction between the solvent-polarity-dependent conformational equilibrium and excited state intramolecular proton transfer (ESIPT) behavior of Pz3HC system in four different polar solvents (polarity order: ACN > THF > TOL > CYC). Using quantum chemistry method, we first announce a coexistence mechanism between Pz3HC-1 and Pz3HC-3 in the ground state in four solvents based on the Boltzmann distribution. In particular, Pz3HC-1 is the principal configuration in non-polar solvent, but Pz3HC-3 is the principal configuration in polar solvent.

Anion Structure Regulation of Cobalt Silicate Hydroxide Endowing Boosted Oxygen Evolution Reaction.

Transition metal silicates (TMSs) are attempted for the electrocatalyst of oxygen evolution reaction (OER) due to their special layered structure in recent years. However, defects such as low theoretical activity and conductivity limit their application. Researchers always prefer to composite TMSs with other functional materials to make up for their deficiency, but rarely focus on the effect of intrinsic structure adjustment on their catalytic activity, especially anion structure regulation.

One-step hydrothermal synthesis of vanadium dioxide/carbon core-shell composite with improved ammonium ion storage for aqueous ammonium-ion battery.

Aqueous nonmetallic ion batteries have garnered significant interest due to their cost-effectiveness, environmental sustainability, and inherent safety features. Specifically, ammonium ion (NH) as a charge carrier has garnered more and more attention recently. However, one of the persistent challenges is enhancing the electrochemical properties of vanadium dioxide (VO) with a tunnel structure, which serves as a highly efficient NH (de)intercalation host material.

Mild steam treatment: Enhancing the rehydration performance of instant rice noodles by changing the physicochemical properties and gel structure of rice starch.

The "instant" quality of instant rice noodles is significantly affected by slow rehydration during cooking. This happens as a result of the native rice starch's low ability to gelatinize as well as the high shear and pressure utilized in industries during the widely used extrusion molding process. In order to address this issue, the rice flour was pretreated with mild steam (MS) technology.

Photophysical Properties of ()-1-(4-(Diethyla-mino)-2-hydroxybenzylidene)-4,4-dimethylthiosemicarbazide Compound and Its Triple Fluorescence Emission Mechanism: A Theoretical Perspective.

In view of the application prospects in biomedicine of ()-1-(4-(diethyla-mino)-2-hydroxybenzylidene)-4,4-dimethylthiosemicarbazide (DAHTS), the behavior of excited-state dynamics and photophysical properties were studied using the density functional theory/time-dependent density functional theory method. A series of studies indicated that the intramolecular hydrogen-bond (IHB) intensity of DAHTS was enhanced after photoexcitation. This was conducive to promoting the excited-state intramolecular proton-transfer (ESIPT) process.

Highly stable and antifungal properties on the oilseed rape of Cu(MoO)(OH) nanoflakes prepared by simple aqueous precipitation.

In the last few decades, nanoparticles have been a prominent topic in various fields, particularly in agriculture, due to their unique physicochemical properties. Herein, molybdenum copper lindgrenite Cu(MoO)(OH) (CM) nanoflakes (NFs) are synthesized by a one-step reaction involving α-MoO and CuCO⋅Cu(OH)⋅xHO solution at low temperature for large scale industrial production and developed as an effective antifungal agent for the oilseed rape. This synthetic method demonstrates great potential for industrial applications.

Asymmetric total synthesis strategies of halichlorine and pinnaic acid.

Halichlorine and pinnaic acid are structurally related natural alkaloids isolated from different marine organisms. These two marine alkaloids bearing a 6-azaspiro[4.5]decane skeleton demonstrate a wide range of biological effects.

Improving cement production process with data-augmented sequence to sequence-Wasserstein generative adversarial networks model for accurate prediction of f-CaO.

This paper proposes a method to address the issue of insufficient capture of temporal dependencies in cement production processes, which is based on a data-augmented Seq2Seq-WGAN (Sequence to Sequence-Wasserstein Generate Adversarial Network) model. Considering the existence of various temporal scales in cement production processes, we use WGAN to generate a large amount of f-CaO label data and employ Seq2Seq to solve the problem of unequal length input-output sequences. We use the unlabeled relevant variable data as the input to the encoder of the Seq2Seq-WGAN model and use the generated labels as the input to the decoder, thus fully exploring the temporal dependency relationships between input and output variables.

Paying Comprehensive Attention to the Temperature-Dependent Dual-Channel Excited-State Intramolecular Proton Transfer Mechanism of Fluorescence Ratio Probe BZ-DAM.

The mechanism of fluorescence detection of diethyl chlorophosphate (DCP) based on 2-substituted benzothiazole (BZ-DAM) was studied by a theoretical calculation method. It should not be ignored that both the BZ-DAM and the detection product BZ-CHO have two excited-state intramolecular proton transfer (ESIPT) channels. Density functional theory (DFT) and time-dependent DFT (TDDFT) theory were used to study the photophysical mechanism of two compounds in two channels in (acetonitrile) ACN solvent, and the temperature dependence of the two channels was given.