Structural reconstruction of electrocatalysts plays a pivotal role in catalytic performances for CO reduction reaction (CORR), whereas the behavior is by far superficially understood. Here, we report that CO accessibility results in a universal self-adaptive structural reconstruction from CuO to Cu@CuO composites, ending with feeding gas-dependent microstructures and catalytic performances. The CO-rich atmosphere favors reconstruction for CORR, whereas the CO-deficient one prefers that for hydrogen evolution reaction.
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