Imidazole Encapsulation Enabled by Confinement for I and CHI Coremoval.

Nitrogen-rich small molecules are frequently doped into porous materials to enhance their iodine adsorption properties. To explore how imidazole confinement in metal-organic frameworks (MOFs) affects iodine adsorption, we obtained a UiO-66-based composite by embedding imidazole in UiO-66 pores via solid-phase adsorption (Im@UiO-66). Characterization confirmed that imidazole was successfully confined within the UiO-66 pores, with each unit of UiO-66 accommodating up to 27 imidazole molecules.

Deposition of Imidazole into Mesoporous Zirconium Metal-Organic Framework for Iodine Capture.

Efficient capture of radioiodine is essential for the protection of the ecological environment and the sustainable development of nuclear energy generation. Metal-organic frameworks (MOFs) and their derivatives provide alternative potential for overcoming the limitations of traditional iodine adsorbents. Herein this work, imidazole (Im) is dispersed into a robust mesoporous zirconium MOF by the heat deposition method, forming a high-uniformity composite .

Attribute-based multi-user collaborative searchable encryption in COVID-19.

With the outbreak of COVID-19, the government has been forced to collect a large amount of detailed information about patients in order to effectively curb the epidemic of the disease, including private data of patients. Searchable encryption is an essential technology for ciphertext retrieval in cloud computing environments, and many searchable encryption schemes are based on attributes to control user's search permissions to protect their data privacy. The existing attribute-based searchable encryption (ABSE) scheme can only implement the situation where the search permission of one person meets the search policy and does not support users to obtain the search permission through collaboration.

MOF-Derived Long Spindle-like Carbon-Coated Ternary Transition-Metal-Oxide Composite for Lithium Storage.

FeO is a promising alternative for next-generation lithium-ion batteries (LIBs). However, its poor cycle stability due to the large volume effect during cycling and poor conductivity hinders its application. Herein, we have successfully designed and prepared a carbon-coated ternary transition-metal-oxide composite (noted as (FeCoNi)O@C), which is derived from FeCoNi-MOF-74 (denoted as FeCoNi-211-24).

Confinement Effect and Efficiency of Concentrically Loaded RACFCST Stub Columns.

Recycled aggregate concrete-filled steel tubular (RACFST) columns are widely recognized as efficient structural members that can reduce the environmental impact of the building industry and improve the mechanical behavior of recycled aggregate concrete (RAC). The objective of this study is to investigate the behavior of recycled aggregate concrete-filled circular steel tubular (RACFCST) stub columns subjected to the axial loading. Three-dimensional finite element (FE) models were established using a triaxial plastic-damage constitutive model of RAC considering the replacement ratio of recycled aggregates.

The asymmetric effect of technology shocks on CO2 emissions: a panel analysis of BRICS economies.

Technological innovation positively contributes to economic development in BRICS countries; their environmental consequences cannot be ignored. Thus, it is imperious to explore the impact of technological shocks on environmental quality. We used ARDL and NARDL models to draw empirical consensus on the data set from 1990 to 2019 for BRICS economies.

Sources of cellular oxidative potential of water-soluble fine ambient particulate matter in the Midwestern United States.

We investigated the spatiotemporal distribution and sources of cellular oxidative potential (OP) in the Midwest US. Weekly samples were collected from three urban [Chicago (IL), Indianapolis (IN), and St. Louis (MO)], one rural [Bondville (IL], and one roadside site [Champaign (IL)] for a year (May 2018 to May 2019), and analyzed for water-soluble cellular OP using a macrophage reactive oxygen species (ROS) assay.

Numerical Investigation of the Composite Action of Axially Compressed Concrete-Filled Circular Aluminum Alloy Tubular Stub Columns.

This paper studied the composite action of concrete-filled circular aluminum alloy tubular (CFCAT) stub columns under axial compression. A fine-meshed finite three-dimensional (3D) solid element model making use of a tri-axial plastic-damage constitutive model of concrete and elastoplastic constitutive model of aluminum alloy was established. A parametric study utilizing the verified finite element (FE) model was carried out and the analytical results were exploited to investigate the composite actions of concrete-filled circular aluminum alloy tubular stub columns subjected axial compression.

Dynamic Feature of Incipient Polymer Collapse below the Theta Point.

We study the dynamics of a polymer chain with gradually changing the solvent quality from good to poor by dissipative particle dynamics simulation. We find several spectral modes related to internal motions of intrachain interaction. Approaching the coil-to-globule transition point, all fast modes of spectrum ω > 1 (ns) disappear.

Neural, electrophysiological and anatomical basis of brain-network variability and its characteristic changes in mental disorders.

SEE MATTAR ET AL DOI101093/AWW151 FOR A SCIENTIFIC COMMENTARY ON THIS ARTICLE: Functional brain networks demonstrate significant temporal variability and dynamic reconfiguration even in the resting state. Currently, most studies investigate temporal variability of brain networks at the scale of single (micro) or whole-brain (macro) connectivity. However, the mechanism underlying time-varying properties remains unclear, as the coupling between brain network variability and neural activity is not readily apparent when analysed at either micro or macroscales.

Differential alterations of resting-state functional connectivity in generalized anxiety disorder and panic disorder.

Generalized anxiety disorder (GAD) and panic disorder (PD) are most common anxiety disorders with high lifetime prevalence while the pathophysiology and disease-specific alterations still remain largely unclear. Few studies have taken a whole-brain perspective in the functional connectivity (FC) analysis of these two disorders in resting state. It limits the ability to identify regionally and psychopathologically specific network abnormalities with their subsequent use as diagnostic marker and novel treatment strategy.