Microfluidic-Aerosol Hyphenated Synthesis of Metal-Organic Framework-Derived Hybrid Catalysts for CO Utilization.

A new and efficient technique is developed by combining the hyphenated microfluidic- and aerosol-based synthesis with the coupled differential mobility analysis for the effective and continuous synthesis and simultaneous analysis of metal-organic frameworks (MOFs)-derived hybrid nanostructured products. HKUST-1, a copper-based MOF, is chosen as the representative to fabricate Cu-based hybrid catalysts for reverse water-gas shift (RWGS) reaction, an effective route for CO utilization. The effect of precursor concentration and carrier selection on the properties of the resulting products, including mobility size distribution, crystallization degree, surface area, and metal dispersion are investigated, as well as the correlation between the material properties of the synthesized catalysts and their catalytic performance in RWGS reaction in terms of conversion ratio/rate, selectivity, and operational stability.

Real-Time Quantifying Microdroplet Synthesis of Metal-Organic Framework Colloids Using Gas-Phase Electrophoresis.

A hyphenated electrospray-differential mobility analysis (ES-DMA) was developed for providing a high-resolution, real-time quantitative analysis on the metal-organic framework (MOF) colloids produced via the concept of microfluidic flow chemistry. Zeolitic imidazolate framework-8 was chosen as the representative MOF of the study. The results show that the physical size and number concentration of the MOF colloid were successfully characterized by the hyphenated ES-DMA during the microdroplet synthetic process, with 3 nm and 4% of measurement uncertainties, respectively.