The nanoscopic deformation of ⟨111⟩ nanotwinned copper nanopillars under strain rates between 10/s and 5 × 10/s was studied by using in situ transmission electron microscopy. The correlation among dislocation activity, twin boundary instability due to incoherent twin boundary migration and corresponding mechanical responses was investigated. Dislocations piled up in the nanotwinned copper, giving rise to significant hardening at relatively high strain rates of 3-5 × 10/s.
View Article and Find Full Text PDFWe observed the small-size-induced hardening and plasticity of brittle ionic MgO as a result of abnormally triggered dislocation gliding on a non-charge-balanced slip system. The indentation tests of ⟨111⟩ MgO pillars revealed an increased hardness with decreasing pillar size, and the tips of the pillars that were ≤200 nm were plastically deformed. The in situ compression tests of ⟨111⟩ MgO nanopillars in transmission electron microscopy verified aligned dislocation-mediated plasticity on the {111}⟨110⟩ and {100}⟨110⟩ systems rather than the charge-balanced {110}⟨110⟩ slip system.
View Article and Find Full Text PDFThe fabrication and characteristics of Ce/Cr-doped crystal fibers employing drawing tower technique are reported. The fluorescence spectrum of the Ce/Cr fibers at the core diameter ranging from 10 to 21 µm exhibited a 200-nm near-Gaussian broadband emission which enabled to provide an axial resolution of 1.8-μm and a power density of 79.
View Article and Find Full Text PDFIn this paper, Lu3Al5O12:Ce3+ and CaAlSiN3: Eu2+ co-doped glass are presented as color conversion materials for white light-emitting diodes (WLEDs). Through adjusting the thickness of the glass phosphors, the chromaticity and CCT of the WLEDs follows the Planckian locus well. The WLEDs show CCT ranging from ~4000K to ~7000K with high CRI ranging from 83 to 90 due to the wide emission spectrum from the proposed glass phosphors.
View Article and Find Full Text PDFNew broadband glass phosphors with excellent thermal stability were proposed and experimentally demonstrated for white light-emitting-diodes (WLEDs). The novel glass phosphors were realized through dispersing multiple phosphors into SiO₂ based glass (SiO₂-Na₂O-Al₂O₃-CaO) at 680°C. Y₃Al₅O₁₂:Ce³⁺ (YAG), Lu₃Al₅O₁₂:Ce³⁺ (LuAG), and CaAlSiN₃: Eu²⁺ (nitride) phosphor crystals were chosen respectively as the yellow, green, and red emitters of the glass phosphors.
View Article and Find Full Text PDFWe report multi-component high-entropy materials as extraordinarily robust diffusion barriers and clarify the highly suppressed interdiffusion kinetics in the multi-component materials from structural and thermodynamic perspectives. The failures of six alloy barriers with different numbers of elements, from unitary Ti to senary TiTaCrZrAlRu, against the interdiffusion of Cu and Si were characterized, and experimental results indicated that, with more elements incorporated, the failure temperature of the barriers increased from 550 to 900°C. The activation energy of Cu diffusion through the alloy barriers was determined to increase from 110 to 163 kJ/mole.
View Article and Find Full Text PDFIn situ nanoscopic observations of healthy and osteoporotic bone nanopillars under compression were performed. The structural-mechanical property relationship at the atomic scale suggests that cortical bone performance is correlated to the feature, arrangement, movement, distortion, and fracture of hydroxyapatite nanocrystals. Healthy bone comprising tightly bound mineral nanocrystals shows high structural stability with nanoscopic lattice distortions and dislocation activities.
View Article and Find Full Text PDFThe fluorescence enhancement in broadband Cr-doped fibers (CDFs) fabricated by a drawing tower with a redrawn powder-in-tube preform is proposed and demonstrated. The CDFs after heat treatment exhibited Cr⁴⁺ emission enhancement with spectral density of 200 pW/nm, verified by the formation of α-Mg₂SiO₄ nanocrystalline structures in the core of CDFs. The high fluorescence achievement in the CDFs is essential to develop a broadband CDF amplifier for next-generation optical communication systems.
View Article and Find Full Text PDFThe fabrication of a Cr-doped fiber using a drawing-tower method with Cr:YAG as the core of the preform is presented. The Cr-doped YAG preform was fabricated by a rod-in-tube method. By employing a negative pressure control in drawing-tower technique on the YAG preform, the Cr-doped fibers with a better core circularity and uniformity, and good interface between core and cladding were fabricated.
View Article and Find Full Text PDFWe report on the first fabrication of a Cr-doped fiber using a drawing-tower method with Cr:YAG as the core of the preform. Both Cr3+ and Cr4+ ions coexist in the Cr-doped fiber, and the amplified spontaneous emission (ASE) spectrum shows a broadband emission of 1.2 to 1.
View Article and Find Full Text PDF