For the first time, simple and facile fabrication of a magnetic alginate microadsorbent via piezoelectric inkjet technology was developed for the selective removal of Cs via magnetic separation. Through the ejection of an alginate solution containing potassium ferrocyanide and magnetic nanoparticles (MNPs) into a Cu solution via an inkjet device, the fabrication of a copper ferrocyanide-embedded magnetic alginate microadsorbent (CuFC-MAM) with an average size of 39.38 μm was easily achieved in a one-pot fabrication process; here, the Cu ions acted as both a cross-linker for the gelation of alginate and a Cu source for the in situ synthesis of CuFC with potassium ferrocyanide.
View Article and Find Full Text PDFComposite membranes with a polyvinyl alcohol (PVA) selective layer composed of well-dispersed hydrophilic kaolinite particles coated on a polyvinylidene fluoride (PVDF) support were developed. They were applied to the pervaporation dehydration of the industrially important epichlorohydrin (ECH)/isopropanol (IPA)/water ternary mixture. In comparison with raw kaolinite (RK), hydrophilic kaolinite (HK) enhanced the mechanical properties, hydrophilicity, and thermal stability of the PVA selective layer, as confirmed by universal testing, the contact angle, and TGA analyses, respectively.
View Article and Find Full Text PDFPolyacrylic acid (PAA) grafted CN sheet (P-g-CN) was synthesized to enhance the dispersive properties of carbon nitride (CN) in the membrane. A successful PAA grafting to the CN was confirmed from FTIR, TGA, and Zeta potential and XRD analyses. The A PVA membrane embedded P-g-CN, including a covalently constructed polymer-filler network, was developed to separate ethanol-water mixtures using pervaporation (PV).
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