Vanadium-based catalysts have been commercially used in selective catalytic reduction (SCR), owing to their high catalytic activity and effectiveness across a wide temperature range; however, their catalytic efficiency decreases at lower temperatures under exposure to SO. This decrease is largely due to ammonium sulfate generation on the catalyst surface. To overcome this limitation, we added ammonium nitrate to the VO-WO/TiO catalyst, producing a VO-WO/TiO catalyst with nitrate functional groups.
View Article and Find Full Text PDFArgyrodite solid electrolytes such as lithium phosphorus sulfur chloride (LiPSCl) have recently attracted great attention due to their excellent lithium-ion transport properties, which are applicable to all-solid-state lithium batteries. In this study, we report the improved ionic conductivity of an argyrodite solid electrolyte, LiPSCl, in all-solid-state lithium batteries via the co-doping of chlorine (Cl) and aluminum (Al) elements. Electrochemical analysis was conducted on the doped argyrodite structure of LiPSCl, which revealed that the substitution of cations and anions greatly improved the ionic conductivity of solid electrolytes.
View Article and Find Full Text PDFWe demonstrated highly efficient selective catalytic reduction catalysts by adopting the polyol process, and the prepared catalysts exhibited a high nitrogen oxide (NO) removal efficiency of 96% at 250 °C. The VO and WO catalyst nanoparticles prepared using the polyol process were smaller (~10 nm) than those prepared using the impregnation method (~20 nm), and the small catalyst size enabled an increase in surface area and catalytic acid sites. The NO removal efficiencies at temperatures between 200 and 250 °C were enhanced by approximately 30% compared to those of the catalysts prepared using the conventional impregnation method.
View Article and Find Full Text PDFPurpose: There have been few reports regarding same-day discharge following uncomplicated procedures such as cerebral angiography and neurointervention. We present same-day experience with cerebral angiography and neurointervention during the past three years.
Materials And Methods: Four hundred and fifty-three patients underwent cerebral angiography or neurointervention at Asan Medical Center between January 2009 and December 2011.