Complexity of quantum phases of matter is often understood theoretically by using gauge structures, as is recognized by the [Formula: see text] and U(1) gauge theory description of spin liquids in frustrated magnets. Anomalous Hall effect of conducting electrons can intrinsically arise from a U(1) gauge expressing the spatial modulation of ferromagnetic moments or from an SU(2) gauge representing the spin-orbit coupling effect. Similarly, in insulating ferro and antiferromagnets, the magnon contribution to anomalous transports is explained in terms of U(1) and SU(2) fluxes present in the ordered magnetic structure.
View Article and Find Full Text PDFWe developed a metallic pressure cell made of 56Ni-40Cr-4Al (Ni-Cr-Al) alloy for use with a non-destructive pulse magnet and a magnetic susceptibility measurement apparatus with a proximity detector oscillator (PDO) in pulsed magnetic fields of up to 51 T under pressures of up to 2.1 GPa. Both the sample and sensor coil of the PDO were placed in the cell so that the magnetic signal from Ni-Cr-Al would not overlay the intrinsic magnetic susceptibility of the sample.
View Article and Find Full Text PDFExperimental studies into the forced magnetostriction, magnetization, and temperature dependence of permeability in NiMnIn and NiMnSn ferromagnetic Heusler alloys were performed according to the spin fluctuation theory of itinerant ferromagnetism proposed by Takahashi. We investigated the magnetic field () dependence of magnetization () at the Curie temperature , and at = 4.2 K, which concerns the ground state of the ferromagnetic state.
View Article and Find Full Text PDFThe ability to switch a molecule between different magnetic states is of considerable importance for the development of new molecular electronic devices. Desirable properties for such applications include a large-spin ground state with an electronic structure that can be controlled via external stimuli. Fe is a cyanide-bridged stellated cuboctahedron of mixed-valence Fe ions that exhibits an extraordinarily large = 45 spin ground state.
View Article and Find Full Text PDFExperimental investigations into the field dependence of magnetization and the relationship between magnetization and magnetostriction in NiMnGa (x = 0.00, 0.02, 0.
View Article and Find Full Text PDFThe cyanide-bridged [CoFe] one-dimensional chain, [Co(II)((R)-pabn)][Fe(III)(Tp)(CN)3](BF4)·MeOH·2H2O, where (R)-pabn = (R)-N2,N(2')-bis(pyridin-2-ylmethyl)-1,1'-binaphthyl-2,2'-diamine and Tp = hydrotris(pyrazolyl)borate, exhibits magnetic and electric bistabilities originating from an electron transfer coupled spin transition between Fe-CN-Co pairs. The use of L-edge X-ray absorption spectroscopy (XAS) in combination with L-edge X-ray magnetic circular dichroism (XMCD) is explored for the investigation of the electronic structure and magnetization of Co and Fe ions separately, in both diamagnetic and paramagnetic states. It has been established from susceptibility results that the switching between diamagnetic and paramagnetic phases emanates from electron transfer between low spin Fe(II) and Co(III), resulting in low spin Fe(III) (S = 1/2) and high spin Co(II) (S = 3/2).
View Article and Find Full Text PDFA new series of triangular-lattice magnets, Na(2)BaMV(2)O(8) (M = Ni, Co, and Mn), are reported. These three compounds crystallize with the Ag(2)BaMnV(2)O(8) type structure, where the magnetic M(2+) ions form a two-dimensional triangular lattice. The magnitude of the exchange interactions in these compounds is moderate because the nonmagnetic VO(4) tetrahedra interrupt direct connections between MO(6) octahedra.
View Article and Find Full Text PDFWe present a pulsed-magnet system that enables x-ray single-crystal diffraction in addition to powder and spectroscopic studies with the magnetic field applied on or close to the scattering plane. The apparatus consists of a single large-bore solenoid, cooled by liquid nitrogen. A second independent closed-cycle cryostat is used for cooling samples near liquid helium temperatures.
View Article and Find Full Text PDFTwo new copper(II) compounds of chloranilate and 2,2':6',2' '-terpyridine have been synthesized, and the structures have been solved by the single-crystal X-ray diffraction method. The crystal structure of [[Cu(2)(CA)(terpy)(2)][Cu(CA)(2)]](n)(1), where H(2)CA = chloranilic acid and terpy = 2,2':6',2' '-terpyridine, consists of two modules, the dimer unit [Cu(2)(CA)(terpy)(2)](2+) and the anionic mononuclear unit [Cu(CA)(2)](2)(-), forming an alternated chain. The chain is stabilized by semicoordinating and additional but efficient secondary bonding interactions.
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