Dissolved organic matter promotes photocatalytic degradation of refractory organic pollutants in water by forming hydrogen bonding with photocatalyst.

Removing refractory organic pollutants in real water using photocatalysis is a great challenge because coexisting dissolved organic matter (DOM) can quench photogenerated holes and thus prevent generation of reactive oxygen species (ROS). Herein, for the first time, we develop a hydrogen bonding strategy to avoid the scavenging of photoexcited holes, by which DOM even promotes photocatalytic degradation of refractory organic pollutants. Theoretical calculations combined with experimental studies reveal the formation of hydrogen bonding between DOM and a hydroxylated S-scheme heterojunction photocatalyst (Mo-Se/OHNT) consisting of hydroxylated nitrogen doped TiO (OHNT) and molybdenum doped selenium (Mo-Se).