Growing ZIF-8 Seeds on Charged COF Substrates toward Efficient Propylene-Propane Separation Membranes.

We report a covalent organic framework (COF) induced seeding strategy to fabricate metal-organic framework (MOF) membranes. Contrary to graphene oxide nuclei-depositing substrate, COF substrate has uniform pore size, high microporosity and abundant functional groups. We designed a series of charged COF nanosheets to induce the formation of ZIF-8@COF nanosheet seeds with high aspect ratio over 150, which were readily processed into a compact and uniform seed layer.

Engineering HOF-Based Mixed-Matrix Membranes for Efficient CO Separation.

Hydrogen-bonded organic frameworks (HOFs) have emerged as a new class of crystalline porous materials, and their application in membrane technology needs to be explored. Herein, for the first time, we demonstrated the utilization of HOF-based mixed-matrix membrane for CO separation. HOF-21, a unique metallo-hydrogen-bonded organic framework material, was designed and processed into nanofillers via amine modulator, uniformly dispersing with Pebax polymer.

Coordination-driven structure reconstruction in polymer of intrinsic microporosity membranes for efficient propylene/propane separation.

Polymers of intrinsic microporosity (PIMs), integrating unique microporous structure and solution-processability, are one class of the most promising membrane materials for energy-efficient gas separations. However, the micropores generated from inefficient chain packing often exhibit wide pore size distribution, making it very challenging to achieve efficient olefin/paraffin separations. Here, we propose a coordination-driven reconstruction (CDR) strategy, where metal ions are incorporated into amidoxime-functionalized PIM-1 (AO-PIM) to generate coordination crosslinking networks.

Missing-linker Defects in Covalent Organic Framework Membranes for Efficient CO Separation.

Covalent organic framework (COF) membranes with tunable ordered channels and free organic groups hold great promise in molecular separations owing to the synergy of physical and chemical microenvironments. Herein, we develop a defect engineering strategy to fabricate COF membranes for efficient CO separation. Abundant amino groups are in situ generated on the COF nanosheets arising from the missing-linker defects during the reactive assembly of amine monomer and mixed aldehyde monomers.

MOF-COF "Alloy" Membranes for Efficient Propylene/Propane Separation.

Molecular-sieving membranes from metal-organic frameworks (MOFs) are promising candidates for separating olefin/paraffin mixtures, a critical demand in sustainable chemical processes and a grand challenge in molecular separation. Currently, the inherent lattice flexibility of MOFs severely compromises their precise sieving ability. Here, a proof-of-concept of "alloy" membranes (AMs), which are fabricated by incorporating quaternary ammonium (QA)-functionalized covalent organic frameworks (COFs) into a zeolitic imidazolate framework-8 (ZIF-8) matrix is demonstrated.

Oil-Water-Oil Triphase Synthesis of Ionic Covalent Organic Framework Nanosheets.

Ionic covalent organic framework nanosheets (iCOFNs) with long-range ordered and mono-dispersed ionic groups hold great potential in many advanced applications. Considering the inherent drawbacks of oil-water biphase method, herein, we explore an oil-water-oil triphase method based on phase engineering strategy for the bottom-up synthesis of iCOFNs. The middle water phase serves as a confined reaction region, and the two oil phases are reservoirs for storing and supplying monomers to the water phase.

Organic molecular sieve membranes for chemical separations.

Molecular separations that enable selective transport of target molecules from gas and liquid molecular mixtures, such as CO2 capture, olefin/paraffin separations, and organic solvent nanofiltration, represent the most energy sensitive and significant demands. Membranes are favored for molecular separations owing to the advantages of energy efficiency, simplicity, scalability, and small environmental footprint. A number of emerging microporous organic materials have displayed great potential as building blocks of molecular separation membranes, which not only integrate the rigid, engineered pore structures and desirable stability of inorganic molecular sieve membranes, but also exhibit a high degree of freedom to create chemically rich combinations/sequences.

Membrane-Based Olefin/Paraffin Separations.

Efficient olefin/paraffin separation is a grand challenge because of their similar molecular sizes and physical properties, and is also a priority in the modern chemical industry. Membrane separation technology has been demonstrated as a promising technology owing to its low energy consumption, mild operation conditions, tunability of membrane materials, as well as the integration of physical and chemical mechanisms. In this work, inspired by the physical mechanism of mass transport in channel proteins and the chemical mechanism of mass transport in carrier proteins, recent progress in channel-based and carrier-based membranes toward olefin/paraffin separations is summarized.

Channel-facilitated molecule and ion transport across polymer composite membranes.

Biological membranes possess hierarchical channels and thus exhibit ultrahigh permselectivity for molecules and ions. Intrigued by the delicate structure and transport mechanisms in biochannels, polymer composite membranes with selective transport channels are successfully fabricated for diverse energy- and environment-related applications. This tutorial review aims to present the latest progress in the design and construction of selective molecule/ion transport channels within polymer composite membranes with emphasis on the regulation of the physical and chemical microenvironments of these channels.