Manipulating key intermediates and suppressing the hydrogen evolution reaction dual roles of Bi for high-efficiency nitrate to ammonia and energy conversion.

The nitrate reduction reaction (NORR) is a promising technology for simultaneous treatment of NO wastewater and synthetic ammonia. However, the NORR involves multiple electron and proton transfer processes, and the ammonia selectivity and yield are highly susceptible to the evolution of key intermediate (*NO) and the competing hydrogen evolution reaction (HER). In this study, bismuth (Bi), with a high hydrogen overpotential, is used as an inhibitor of the HER.

Organocatalytic allylic alkylation of alkyne-substituted MBH carbonates: access to quaternary carbon-containing 1,4-enynes.

A DABCO-catalyzed allylic alkylation of tertiary propargylic alcohol-derived MBH carbonates with nitromethane was developed. A series of substituted 1,4-enynes with an all-carbon quaternary stereocenter were efficiently obtained in moderate to high yields. The synthetic utility of the product was demonstrated by facile synthesis of 1,4-enyne-embedded 2-pyrrolidinones.

Cross-linked polyaniline for production of long lifespan aqueous iron||organic batteries with electrochromic properties.

Aqueous iron batteries are appealing candidates for large-scale energy storage due to their safety and low-cost aspects. However, the development of aqueous Fe batteries is hindered by their inadequate long-term cycling stability. Here, we propose the synthesis and application as positive electrode active material of cross-linked polyaniline (C-PANI).

Electro-oxidation induced O-S cross-coupling of quinoxalinones with sodium sulfinates for synthesizing 2-sulfonyloxylated quinoxalines.

The functionalization of quinoxalinones is synthetically and biologically appealing, however, C2 functionalized quinoxalinones is not reported environmentally friendly approach. Herein, we disclosed C2-O sulfonylation of quinoxalinones our developed electrochemical oxidative O-S coupling strategy for synthesizing 2-sulfonyloxylated quinoxalines. Applying this protocol, quinoxalin-ones and sodium sulfinates as the starting materials, a wide range of 2-sulfonyloxyl quinoxaline derivatives were obtained in moderate to good yields with good functional-group tolerance under mild conditions without additional oxidants.

Synergistic mechanism of Ni(OH)/NiMoS heterostructure electrocatalyst with crystalline/amorphous interfaces for efficient hydrogen evolution over all pH ranges.

Designing and fabricating efficient electrocatalysts is a practical step toward the commercial application of the efficient hydrogen evolution reaction (HER) over all pH ranges. Herein, novel Ti@Ni(OH)-NiMoS heterostructure with interface between crystalline Ni(OH) and amorphous NiMoS was rationally designed and fabricated on Ti mesh (denoted as Ti@Ni(OH)-NiMoS). Acid etching and calcination experiments helped in accurate elucidation of the synergistic mechanism as well as the vital role on crystalline Ni(OH) and amorphous NiMoS.

Ethylenediamine-assisted hydrothermal synthesis of NiCoO absorber with controlled morphology and excellent absorbing performance.

In recent years, developing excellent electromagnetic wave (EMW) absorbers with small thickness and large bandwidth is an effective strategy to deal with the seriously EMW interferes in military and civil field. The morphology of absorbers has profound effects on their EMW absorption performance. Herein, ethylenediamine (EDA) was applied to EMW absorbing field as morphology control agent for the first time (as far as we know) for the synthesis of nickel cobaltate (NiCoO) absorber, and the effect of EDA content on the morphology and EMW absorbing performance was also investigated elaborately.

Dendritic fibrous nano-silica & titania (DFNST) spheres as novel cataluminescence sensing materials for the detection of diethyl ether.

Selective and controllable cataluminescence (CTL) sensors for volatile organic compounds (VOCs) are significant for chemical safety, environmental monitoring, health effects on human beings, and so forth. Most of the exploited CTL-based sensors suffer relatively low response and poor selectivity because of their high sensitivities to interferential substances. In this investigation, dendritic fibrous nano-silica & titania (DFNST) spheres have been synthesized as novel sensing materials and the corresponding DFNST-based CTL sensor has been fabricated to detect diethyl ether with high selectivity a method of utilizing one 440 nm bandpass filter.

Biomimetic Hydroxyapatite on Graphene Supports for Biomedical Applications: A Review.

Hydroxyapatite (HA) has been widely used in fields of materials science, tissue engineering, biomedicine, energy and environmental science, and analytical science due to its simple preparation, low-cost, and high biocompatibility. To overcome the weak mechanical properties of pure HA, various reinforcing materials were incorporated with HA to form high-performance composite materials. Due to the unique structural, biological, electrical, mechanical, thermal, and optical properties, graphene has exhibited great potentials for supporting the biomimetic synthesis of HA.

Improving the size uniformity of dendritic fibrous nano-silica by a facile one-pot rotating hydrothermal approach.

Dendritic fibrous nano-silica (DFNS), also well-known as KCC-1, possesses three-dimensional center-radial nanochannels and hierarchical nanopores. Compared with conventional mesoporous materials like SBA-15, these special structural characteristics endow DFNS with more accessible internal space, higher specific surface area, larger pore volume, Even though great progress has been achieved, the as-prepared KCC-1 nanospheres exhibit extremely non-uniform diameters and their sizes differ enormously in almost all available traditional synthesis approaches. Herein, a facile and low-cost one-pot rotating hydrothermal approach is adopted to improve the size uniformity of dendritic fibrous nano-silica.

Crystallization-Induced Emission Enhancement of a Deep-Blue Luminescence Material with Tunable Mechano- and Thermochromism.

Organic luminescent materials with the ability to reversibly switch the luminescence when subjected to external stimuli have attracted considerable interest in recent years. However, the examples of luminescent materials that exhibit multiresponsive properties are rarely reported. In this work, a new stimuli-responsive dye P1 is designed and synthesized with two identical chromophores of naphthalimide, one at each side of an amidoamine-based spacer.

A 1,2-propylene oxide sensor utilizing cataluminescence on CeO2 nanoparticles.

A simple and sensitive gas sensor was proposed for the determination of 1,2-propylene oxide (PO) based on its cataluminescence (CTL) by oxidation in the air on the surface of CeO2 nanoparticles. The luminescence characteristics and optimal conditions were investigated in detail. Under optimized conditions, the linear range of the CTL intensity versus the concentration of PO was 10-150 ppm, with a correlation coefficient (r) of 0.

Low temperature CO sensor based on cataluminescence from plasma-assisted catalytic oxidation on Ag doped alkaline-earth nanomaterials.

Based on cataluminescence from plasma-assisted catalytic oxidation, a low temperature CO sensor was fabricated. With Ag doped alkaline-earth catalyst as sensing element, air as discharge gas, carrier gas and oxidant supplier, significant cataluminescence was achieved at low temperature, demonstrating a potential low-consumption and portable sensor of CO.

A chemiluminescence sensor array for discriminating natural sugars and artificial sweeteners.

In this paper, we report a chemiluminescence (CL) sensor array based on catalytic nanomaterials for the discrimination of ten sweeteners, including five natural sugars and five artificial sweeteners. The CL response patterns ("fingerprints") can be obtained for a given compound on the nanomaterial array and then identified through linear discriminant analysis (LDA). Moreover, each pure sweetener was quantified based on the emission intensities of selected sensor elements.

Development of an analytical method for the determination of beta2-agonist residues in animal tissues by high-performance liquid chromatography with on-line electrogenerated [Cu(HIO6)2]5- -luminol chemiluminescence detection.

A novel method was developed for the simultaneous determination of beta2-agonist residues such as terbutaline, salbutamol, and clenbuterol by high-performance liquid chromatography (HPLC) coupled with chemiluminescence (CL) detection. The procedure was based on the enhancement effect of beta2-agonists on the CL reaction between luminol and the complex of trivalent copper and periodate ([Cu(HIO6)2]5-), which was on-line electrogenerated by constant current electrolysis. The HPLC separation used a Nucleosil RP-C18 column (250 mm x 4.

Determination of propylthiouracil and methylthiouracil in human serum using high-performance liquid chromatography with chemiluminescence detection.

Based on the sensitizing effect of formaldehyde on the chemiluminescence (CL) reaction of propylthiouracil (PTU) and methylthiouracil (MTU) with acidic potassium permanganate and the combination technique of high-performance liquid chromatography (HPLC), a sensitive, selective and simple post-column CL detection method for determining PTU and MTU is described. The optimal conditions for the CL detection and HPLC separation were carried out. The linear ranges were 0.

Detection of glucocorticoid residues in pig liver by high-performance liquid chromatography with on-line electrogenerated [Cu(HIO6)2](5-)--luminol chemiluminescence detection.

A novel method was developed for the simultaneous determination of glucocorticoid residues such as triamcinolone (TR), prednisolone (PR), hydrocortisone (HC), cortisone (CO), methylprednisolone (MP), dexamethasone (DE) and triamcinolone acetonide (TA) by high-performance liquid chromatography (HPLC) coupled with chemiluminescence (CL) detection. The procedure was based on the enhancement effect of glucocorticoids on the chemiluminescence reaction between luminol and the complex of trivalent copper and periodate ([Cu(HIO6)2]5-), which was on-line electrogenerated by constant current electrolysis. The HPLC separation used a Nucleosil RP-C18 column (250 mmx4.

Detection of indomethacin by high-performance liquid chromatography with in situ electrogenerated Mn(III) chemiluminescence detection.

The determination of indomethacin (INM) in pharmaceutical and biological samples by means of high-performance liquid chromatography (HPLC) with in situ electrogenerated Mn(III) chemiluminescence (CL) detection was proposed. The method was based on the direct CL reaction of INM and Mn(III), which was in situ electrogenerated by constant current electrolysis. The chromatographic separation was carried out on Nucleosil RP-C(18) column (250 mm x 4.

Development and optimization of an analytical method for the determination of Sudan dyes in hot chilli pepper by high-performance liquid chromatography with on-line electrogenerated BrO- -luminol chemiluminescence detection.

The determination of four Sudan dyes by means of high-performance liquid chromatography (HPLC) with chemiluminescence (CL) detection was proposed. The method was based on the enhancement effect of Sudan dyes on the chemiluminescence reaction between luminol and BrO-, which was on-line electrogenerated by constant current electrolysis. The separation was carried out on Nucleosil RP-C18 column (250 mm x 4.