Boosting Zinc Storage Performance of Li VO Cathode Material for Aqueous Zinc Ion Batteries via Carbon-Incorporation: A Study Combining Theory and Experiment.

In the search for sustainable cathode materials for aqueous zinc ion batteries (AZIBs), vanadium (V)-based materials have garnered interest, primarily due to their abundance and multiple oxidation states. Among the contenders, Li VO (LiVO) stands out for its affordability, high specific capacity, and elevated ionic conductivity. However, its limited electrical conductivity results in significant resistance polarization, limiting its rate capability, especially under high currents.

Polypyrrole-Doped NH V O with Oxygen Vacancies as High-Performance Cathode Material for Aqueous Zinc-Ion Batteries.

The inherent slow diffusion dynamics of aqueous zinc-ion batteries (AZIBs) act as a significant hindrance to their universal utilization as energy storage systems, largely attributed to the scarcity of superior cathode materials. In this study, a novel method that amalgamates oxygen defect engineering and polymer intercalation, guided by theoretical computations, to confront this challenge, is introduced. This approach begins with density functional theory calculations, demonstrating that the shielding effect rendered by polypyrrole (PPy) between NH V O (NVO) layers, along with the cooperative influence of oxygen defects (O ), optimizes the kinetic transport of Zn .

Coaxial spinning fabricated high nitrogen-doped porous carbon walnut anchored on carbon fibers as anodic material with boosted lithium storage performance.

Commercial graphite with low theoretical capacity cannot meet the ever-increasing requirement demands of lithium-ion batteries (LIBs) caused by the rapid development of electric devices. Rationally designed carbon-based nanomaterials can provide a wide range of possibilities to meet the growing requirements of energy storage. Hence, the porous walnut anchored on carbon fibers with reasonable pore structure, N-self doping (10.

A green approach to prepare hierarchical porous carbon nanofibers from coal for high-performance supercapacitors.

A green method is designed to obtain hierarchical porous carbon nanofibers from coal. In the work, deionized water, coal, polyvinyl alcohol and Pluronic F127 are used as the aqueous solution, carbon source, spinning assistant and soft template for spinning, respectively. As electrode materials for supercapacitors, the obtained hierarchical porous carbon nanofibers exhibit a high specific capacitance of 265.