Low pressure modified polyamide 6 membrane for effective fractionation of dyes and NaCl.

A co-polymer (SPAA6) of 5-sulfoanthranilic acid (5SAA) and ε-caprolactam was used to prepare membrane through nonsolvent induced phase separation (NIPS) method. The micro-structure of membrane was adjusted by small molecules to improve mechanic strength and performance, involving 7 commercial ionic surfactant and a self-synthesized one, S20. S20 showed the best compatibility with SPAA6, which converted spherical phase into network of strip-like units in micro-structure of membrane.