Protein-resistance performance enhanced by formation of highly-ordered perfluorinated alkyls on fluorinated polymer surfaces.

In this paper, the relationship between the surface structure of fluorinated polymers and their protein-resistant property was studied by preparing films of poly(n-alkyl methacrylate) end-capped with 2-perfluorooctylethyl methacrylate (FMA) (PFMA(y)-ec-PnAMA(x)-ec-PFMA(y)) with various ordered structures of perfluorinated alkyls. These fluorinated polymers were synthesized via a controlled/living atom-transfer radical polymerization (ATRP) method. Both the surface free energy and the CF(3)/CF(2) ratio obtained by X-ray photoelectron spectroscopy (XPS) were employed to scale the ordered structures of the perfluorinated alkyls.