Modular Assembly Drives Synthesis of High-Energy Linked/Fused Molecules.

In this study, we propose a "modular assembly" strategy to synthesize a series of new trinitromethyl high-energy molecules. For a typical molecule 1, this approach reduces the number of synthetic steps from 7 to 2 and improves the yield from 1.0% to 48.

Attaining the Utmost Stability and Energy of Carbonyl Azides by the Synergistic Improvement of Conjugation and H-bonding.

Carbonyl azides are important precursors to isocyanates and are used as energetic compounds. However, the further development of these compounds is limited by their inherently poor stability. In this study, we present a new family of carbonyl azides, 5-nitro-1H-1,2,4-triazol-3-yl-carbamoyl-azide (NTCA), which was synthesized through in situ oxidation cleavage of amino-tetrazole.

Unraveling bilayer interfacial features and their effects in polar polymer nanocomposites.

Polymer nanocomposites with nanoparticles dispersed in polymer matrices have attracted extensive attention due to their significantly improved overall performance, in which the nanoparticle-polymer interface plays a key role. Understanding the structures and properties of the interfacial region, however, remains a major challenge for polymer nanocomposites. Here, we directly observe the presence of two interfacial polymer layers around a nanoparticle in polar polymers, i.