An organic-inorganic hybrid ferroelastic with a near-room-temperature phase transition.

Organic-inorganic hybrid metal halides (OIMHs) with ferroelastic phase transition properties have recently attracted great attention due to their widespread application prospects in the fields of energy storage, sensors, switches, . However, most of the hybrid ferroelastics exhibit phase transition points () far beyond room temperature, which may limit their applications in mechanical switches and energy storage for daily working requirements. Herein, we synthesized a new zinc halide OIMH ferroelastic (,)-[BPHD]ZnBr (BPHD = 1,6-bis(piperidine-1-yl) hexa-2,4-diene diamide), which experiences a 2/1̄ type paraelastic-ferroelastic phase transition at a near-room-temperature of 285 K.

A chiral two-dimensional perovskite-like lead-free bismuth(III) iodide hybrid with high phase transition temperature.

Bismuth(III) iodide perovskites have attracted great attention as lead-free hybrid semiconductors, but they mainly show zero- and one-dimensional structures. Herein, we report the first two-dimensional chiral perovskite-like bismuth(III) iodide hybrid [()-3-aminopyrrolidinium I]BiI () with a high phase transition temperature of 408.8 K, higher than most of the reported chiral lead-free hybrid semiconductors.

A photoluminescent chiral lead-free hybrid ferroelastic semiconductor with switchable second-harmonic generation.

Chiral organic-inorganic hybrid semiconductors (COIHSs) dominated by lead halides have recently gained tremendous interest. Here, we report a lead-free photoluminescent COIHS [-3-hydroxylpiperidinium]SbCl with a bandgap of 3.14 eV.