ACS Appl Mater Interfaces
January 2025
This paper focuses on a four-capacitor flexible sensor composed of two electrode materials; also, the decoupling method and sensing performance for multimodal sensing of spatial forces and dynamic humidity are described. In previous work, decoupling of multimode sensors is mostly done by monitoring the types of signals, numerical differences of the same signal, and stacking multiple parameter-sensitive materials. This paper mainly uses the different characteristics of the two electrode materials; in the simulation and experiment of humidity, the moisture-sensitive electrode quickly wets from the outside to the inside and expands, and the contact angle quickly decreases from 58.
View Article and Find Full Text PDFHerein, ZIF-8 shell encapsulated Ag nanoparticles decorated cotton swab (CS@Ag@ZIF-8) was firstly designed and prepared for highly rapid and selective surface-enhanced Raman spectroscopy (SERS) analysis of glucose and lactic acid in human sweat. The CS not only act as support matrix for Ag modification and ZIF-8 encapsulation, but also provide great potential in-situ analysis of human sweat with low cost. The as-developed CS@Ag@ZIF-8 shows high SERS activity owing the good adsorption of ZIF-8 shell and electromagnetic enhancement of AgNPs.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2023
Stiffness variable polymers are an essential family of materials that have aroused considerable attention in soft actuators. Although lots of strategies have been proposed to achieve variable stiffness, it remains a formidable challenge to achieve a polymer with a wide stiffness range and fast stiffness change. Herein, a series of variable stiffness polymers with a fast stiffness change and wide stiffness range were successfully synthesized, and the formulas were optimized via Pearson correlation tests.
View Article and Find Full Text PDFFlexible power sources are crucial to developing flexible electronic systems; nonetheless, the current poor stretchability and stability of flexible power sources hinder their application in such devices. Accordingly, the stretchability and fatigue stability of flexible power sources are crucial for the practical application of flexible electronic systems. In this work, a flexible electrode with an arc-shaped star concave negative Poisson's ratio (NPR) structure is fabricated through the screen printing process.
View Article and Find Full Text PDFAs is well known, it is difficult to simultaneously improve both the strength and elongation at break of polymers filled with nanomaterials. This work obtained high-performance composites with enhanced strength and elongation at break cross-linking hydroxyl-terminated polybutadiene (HTPB) chains with hyperbranched-polyamide-modified graphene oxide (HGO), and the preparation, characterization, and mechanical properties of the composites serving as a composite solid-propellant binder have been described in detail. Compared with pure HTPB polyurethane (P-HTPB), the tensile strength and elastic modulus of the composite containing 0.
View Article and Find Full Text PDFSelf-healing efficiency and mechanical strength are always a pair of mechanical contradictions of a polymer. Herein, a series of novel mussel-inspired modified graphene oxide/polyurethane composites were successfully fabricated rational molecular design and introducing hyperbranched polymer-modified graphene oxide. The composites exhibit outstanding self-healing performances with a self-healing efficiency of 87.
View Article and Find Full Text PDFAlthough lots of methods have been developed for self-healing materials, it remains a formidable challenge to achieve a thermosetting material with water-insensitive and self-healing properties at room temperature. Nature always provides intelligent strategies for developing advanced materials with superior properties. Herein, a novel self-healable polyurea-urethane was rationally designed by combining mussel adhesive protein-mimetic structure and dynamic aromatic disulfide bonds.
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