Cathodoluminescence of MAPbCl Halide Perovskite Single Crystal.

Chloride perovskites are semiconductors with a near-ultraviolet bandgap that are promising for applications in optoelectronics and photonics. One of the most studied representatives of this family is the methylammonium lead chloride MAPbCl (MA = CHNH). Low-temperature luminescence spectroscopy of this material demonstrates a complex emission structure.

Target-Oriented Synthesis of Triphenylphosphine Functionalized Carbon Dots with Negative Charge for ROS Scavenging and Mitochondrial Targeting.

Triphenylphosphine functionalized carbon dots (TPP-CDs) showcase robust mitochondria targeting capacity owing to their positive electrical properties. However, TPP-CDs typically involve complicated synthesis steps and time-consuming postmodification procedures. Especially, the one-step target-oriented synthesis of TPP-CDs and the regulation of TPP linkage modes remain challenges.

Rapamycin functionalized carbon Dots: Target-oriented synthesis and suppression of vascular cell senescence.

Suppression of vascular cell senescence is of great significance in preventing cardiovascular diseases such as hypertension and atherosclerosis. The oxidative stress damage caused by reactive oxygen species (ROS) can lead to cellular senescence. Rapamycin (Rapa) is well known to suppress cell senescence via mammalian target of rapamycin (mTOR) pathway.

Photothermal Carbon Dots Chelated Hydroxyapatite Filler: High Photothermal Conversion Efficiency and Enhancing Adhesion of Hydrogel.

The synthesis of photothermal carbon/hydroxyapatite composites poses challenges due to the binding modes and relatively low photothermal conversion efficiency. To address these challenges, the calcium ions chelated by photothermal carbon dots (PTC-CDs) served as the calcium source for the synthesis of photothermal carbon dots chelated hydroxyapatite (PTC-HA) filler via the coprecipitation method. The coordination constant and chelation sites of PTC-HA were 7.

3D Nanocomposite with High Aspect Ratio Based on Polyaniline Decorated with Silver NPs: Synthesis and Application as Electrochemical Glucose Sensor.

In this paper, we present a new methodology for creating 3D ordered porous nanocomposites based on anodic aluminum oxide template with polyaniline (PANI) and silver NPs. The approach includes in situ synthesis of polyaniline on templates of anodic aluminum oxide nanomembranes and laser-induced deposition (LID) of Ag NPs directly on the pore walls. The proposed method allows for the formation of structures with a high aspect ratio of the pores, topological ordering and uniformity of properties throughout the sample, and a high specific surface area.

Laser-Induced Synthesis of Electrocatalytically Active Ag, Pt, and AgPt/Polyaniline Nanocomposites for Hydrogen Evolution Reactions.

We present an efficient and easily implemented approach for creating stable electrocatalytically active nanocomposites based on polyaniline (PANI) with metal NPs. The approach combines in situ synthesis of polyaniline followed by laser-induced deposition (LID) of Ag, Pt, and AgPt NPs. The observed peculiarity of LID of PANI is the role of the substrate during the formation of multi-metallic nanoparticles (MNP).

Doppler backscattering diagnostic with dual homodyne detection on the Globus-M compact spherical tokamak.

This article considers a four-frequency microwave Doppler backscattering (DBS) system in the compact spherical tokamak Globus-M. The hardware was adequate for the purposes of studying the peripheral plasma in the tokamak. The multichannel DBS system is based on duplication of a dual homodyne detection circuit for four incident Ka-band frequencies.

Laser-Induced Deposition of Plasmonic Ag and Pt Nanoparticles, and Periodic Arrays.

Surfaces functionalized with metal nanoparticles (NPs) are of great interest due to their wide potential applications in sensing, biomedicine, nanophotonics, etc. However, the precisely controllable decoration with plasmonic nanoparticles requires sophisticated techniques that are often multistep and complex. Here, we present a laser-induced deposition (LID) approach allowing for single-step surface decoration with NPs of controllable composition, morphology, and spatial distribution.

Helium focused ion beam irradiation with subsequent chemical etching for the fabrication of nanostructures.

In this paper we demonstrate a nanofabrication technique based on local ion irradiation of silicon dioxide with a focused helium ion beam. The wet etching of silicon dioxide irradiated with a focused helium ion beam is described in a two-dimensional case both numerically and experimentally. We suggest a model for the etching process based on the distribution of ion induced defects in the irradiated material.

Artificial Dense Lattices of Magnetic Skyrmions.

Multilayer Co/Pt films with perpendicular magnetic anisotropy are irradiated by focused a He ion beam to locally reduce the anisotropy value. The irradiated spots with the diameters of 100 and 200 nm are arranged in square lattices with the periods of 200 and 300 nm. The formation of nonuniform magnetic states within the spots was observed by magnetic force microscopy methods.

Modeling and optimization of the excitonic diffraction grating.

Periodical spatial modulation of the excitonic resonance in a quantum well could lead to the formation of a new highly directional and resonant coherent optical response-resonant diffraction. Such excitonic diffraction gratings were demonstrated in epitaxially grown quantum wells patterned by low-dose ion beam irradiation before or after the growth. In this paper we present a theoretical model of the resonant diffraction formation based on the step-by-step approximation of the Maxwell equation solution.

Microstructured Optical Waveguide-Based Endoscopic Probe Coated with Silica Submicron Particles.

Microstructured optical waveguides (MOW) are of great interest for chemical and biological sensing. Due to the high overlap between a guiding light mode and an analyte filling of one or several fiber capillaries, such systems are able to provide strong sensitivity with respect to variations in the refractive index and the thickness of filling materials. Here, we introduce a novel type of functionalized MOWs whose capillaries are coated by a layer-by-layer (LBL) approach, enabling the alternate deposition of silica particles (SiO) at different diameters-300 nm, 420 nm, and 900 nm-and layers of poly(diallyldimethylammonium chloride) (PDDA).

Tomography diagnostic of plasma radiated power on the spherical tokamak Globus-M.

A diagnostic system for plasma radiated power tomography on Globus-M was upgraded with a new linear array based on silicon photodiodes. The hardware of the diagnostic system based on a 256-channel tangential matrix array and a 24-channel linear array is described. The algorithm for 2D tomographic reconstruction of plasma emissivity is presented.

Interface-Assisted Synthesis of Single-Crystalline ScF Microtubes.

Scandium fluoride (ScF) microtubes with nanoscale wall thickness were for the first time successfully synthesized by an interface-assisted technique at the surface of a scandium nitrate aqueous solution without the addition of any surfactant as a result of interaction with hydrofluoric acid from the gaseous phase in only 30 min. X-ray diffraction analysis, scanning electron microscopy, helium ionic microscopy, transmission electron microscopy (TEM), and high-resolution TEM (HRTEM) were used to examine the morphology and crystal structure of ScF microtubes. The results show that the ScF microtube is single-crystalline and has a hexagonal structure.

Magnetic Force Microscopy of Nanostructured Co/Pt Multilayer Films with Perpendicular Magnetization.

We present the results of magnetic force microscopy investigations of domain structures in multilayer [Co (0.5 nm)/Pt (1 nm)]₅ thin film structures (denoted hereafter as Co/Pt) modified by additional Co capping layers and by ion irradiation. It is demonstrated that a Co capping layer essentially changes the domain structure and decreases the threshold of magnetization reversal, due to the formation of noncollinear magnetization in Co/Pt.

Solitary Nanostructures Produced by Ultrashort Laser Pulse.

Laser-produced surface nanostructures show considerable promise for many applications while fundamental questions concerning the corresponding mechanisms of structuring are still debated. Here, we present a simple physical model describing those mechanisms happened in a thin metal film on dielectric substrate irradiated by a tightly focused ultrashort laser pulse. The main ingredients included into the model are (i) the film-substrate hydrodynamic interaction, melting and separation of the film from substrate with velocity increasing with increase of absorbed fluence; (ii) the capillary forces decelerating expansion of the expanding flying film; and (iii) rapid freezing into a solid state if the rate of solidification is comparable or larger than hydrodynamic velocities.

Ion-beam-assisted spatial modulation of inhomogeneous broadening of a quantum well resonance: excitonic diffraction grating.

We propose a method of spatial modulation of inhomogeneous broadening of a quantum-well excitonic resonance based on local generation of defects produced by a focused ion beam. The method is applied to fabrication of excitonic diffraction grating in a single quantum-well InGaAs/GaAs structure by irradiating the sample with a beam of 35-keV He ions of exposure doses <10  cm. The spectrum of resonant diffraction on such a structure is narrower than that of reflectivity and decreases much faster with increasing temperature.

Scanning reflection ion microscopy in a helium ion microscope.

Reflection ion microscopy (RIM) is a technique that uses a low angle of incidence and scattered ions to form an image of the specimen surface. This paper reports on the development of the instrumentation and the analysis of the capabilities and limitations of the scanning RIM in a helium ion microscope (HIM). The reflected ions were detected by their "conversion" to secondary electrons on a platinum surface.

Laser-induced transformation of supramolecular complexes: approach to controlled formation of hybrid multi-yolk-shell Au-Ag@a-C:H nanostructures.

In the present work an efficient approach of the controlled formation of hybrid Au-Ag-C nanostructures based on laser-induced transformation of organometallic supramolecular cluster compound is suggested. Herein the one-step process of the laser-induced synthesis of hybrid multi-yolk-shell Au-Ag@a-C:H nanoparticles which are bimetallic gold-silver subnanoclusters dispersed in nanospheres of amorphous hydrogenated a-C:H carbon is reported in details. It has been demonstrated that variation of the experimental parameters such as type of the organometallic precursor, solvent, deposition geometry and duration of laser irradiation allows directed control of nanoparticles' dimension and morphology.

Transport of massless Dirac fermions in non-topological type edge states.

There are two types of intrinsic surface states in solids. The first type is formed on the surface of topological insulators. Recently, transport of massless Dirac fermions in the band of "topological" states has been demonstrated.