ACS Appl Mater Interfaces
July 2013
We report a hybrid, quantum dot (QD)-based, organic light-emitting diode architecture using a noninverted structure with the QDs sandwiched between hole transporting layers (HTLs) outperforming the reference device structure implemented in conventional noninverted architecture by over five folds and suppressing the blue emission that is otherwise observed in the conventional structure because of the excess electrons leaking towards the HTL. It is predicted in the new device structure that 97.44% of the exciton formation takes place in the QD layer, while 2.
View Article and Find Full Text PDFWe fabricated and demonstrated improved organic light emitting diodes (OLEDs) in a thin film architecture of indium tin oxide (ITO)/ molybdenum trioxide (MoO3) (20 nm)/N,N'-Di(naphth-2-yl)-N,N'-diphenyl-benzidine (NPB) (50 nm)/ tris-(8-hydroxyquinoline) (Alq3) (70 nm)/Mg:Ag (200 nm) using an oblique angle deposition technique by which MoO3 was deposited at oblique angles (θ) with respect to the surface normal. It was found that, without sacrificing the power efficiency of the device, the device current efficiency and external quantum efficiency were significantly enhanced at an oblique deposition angle of θ=60° for MoO3.
View Article and Find Full Text PDFAn asymmetric twistacene, 1',4'-diphenyl-naphtho-(2'.3':1.2)-pyrene-6'-nitro-7'-methyl carboxylate (tetracene 2), was synthesized by using benzyne-trapping chemistry.
View Article and Find Full Text PDFWe studied the quenching mechanisms responsible for the low efficiency of thin film phosphorescence by a specially designed organic light-emitting diode with an emission layer consisting of a few repeating cells made of a sequentially evaporated host and guest. Variation of the thickness of the guest layer in each cell enables the study of the effect of molecule aggregation on the quantum efficiency. On the other hand, variation of the thickness of the host layer reveals a new long-range quenching mechanism involving a Förster-like dipole-dipole interaction.
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