Automated Systems with Fluorescence Detection for Metal Determination: A Review.

Industrialization has led to environmental pollution with various hazardous chemicals including pollution with metals. In this regard, the development of highly efficient analytical methods for their determination has received considerable attention to ensure public safety. Currently, scientists are paying more and more attention to the automation of analytical methods, since it permits fast, accurate, and sensitive analysis with minimal exposure of analysts to hazardous substances.

An Innovative Vortex-Assisted Liquid-Liquid Microextraction Approach Using Deep Eutectic Solvent: Application for the Spectrofluorometric Determination of Rhodamine B in Water, Food and Cosmetic Samples.

A new green and highly sensitive method for the determination of rhodamine B (RhB) by deep eutectic solvent-based vortex-assisted liquid-liquid microextraction with fluorescence detection (DES-VALLME-FLD) was developed. The extraction efficiency of conventional solvents and different deep eutectic solvent (DES) systems composed of tetrabutylammonium bromide (TBAB) and an alcohol (hexanol, octanol, or decanol) in different ratios were compared. DFT calculations of intermolecular electrostatic and non-covalent interactions of the most stable RhB forms with DES and water explain the experimental DESs' extraction efficiency.

A non-extraction sequential injection method for determination of loratadine using formation of its ion-association complex with bromocresol purple in acetonitrile.

The formation of an ion-association complex (IA) between sulfonephthalein dye and basic nitrogen-containing compound in an organic solvent medium has been for the first time used to develop an automated SIA method. In highly polar aprotic solvents, the tautomeric equilibrium for such dyes is strongly shifted towards the colorless lactonic form. The addition of a basic nitrogen-containing substance leads to the formation of IA with a highly colored quinonoid form, which is accompanied by an increase in the absorbance of the dye band at approximately 400 nm.

Extraction-less green spectrofluorimetric method for determination of mercury using an Astra Phloxine fluorophore: Comprehensive experimental and theoretical studies.

A new sensitive and selective extraction-less method for the spectrofluorimetric determination of Hg has been developed using the polymethine dye Astra Phloxine (AP) with requirements for green analytical chemistry. The principle of this method for analytical use is the formation of an ion associate (IA) in the presence of mercury ions and AP, which causes a change in the electronic structure of the dye cation and its subsequent fluorescence quenching. The IA created during the process was sufficiently stable in aqueous solutions and did not require the use of surfactants or organic solvents, which are typically used for similar analytical systems.