Hubble Meets Webb: Image-to-Image Translation in Astronomy.

This work explores the generation of James Webb Space Telescope (JWSP) imagery via image-to-image translation from the available Hubble Space Telescope (HST) data. Comparative analysis encompasses the Pix2Pix, CycleGAN, TURBO, and DDPM-based Palette methodologies, assessing the criticality of image registration in astronomy. While the focus of this study is not on the scientific evaluation of model fairness, we note that the techniques employed may bear some limitations and the translated images could include elements that are not present in actual astronomical phenomena.

TURBO: The Swiss Knife of Auto-Encoders.

We present a novel information-theoretic framework, termed as TURBO, designed to systematically analyse and generalise auto-encoding methods. We start by examining the principles of information bottleneck and bottleneck-based networks in the auto-encoding setting and identifying their inherent limitations, which become more prominent for data with multiple relevant, physics-related representations. The TURBO framework is then introduced, providing a comprehensive derivation of its core concept consisting of the maximisation of mutual information between various data representations expressed in two directions reflecting the information flows.

Fine-Tuning of the Optical and Electrochemical Properties of Ruthenium(II) Complexes with 2-Arylbenzimidazoles and 4,4'-Dimethoxycarbonyl-2,2'-bipyridine.

A series of cyclometalated complexes of ruthenium (II) with four different substituents in the aryl fragment of benzimidazole was synthesized in order to study the effect of substituent donation on the electronic structure of the substances. The resulting complexes were studied using X-ray diffraction, NMR spectroscopy, MALDI mass spectrometry, electron absorption spectroscopy, luminescence spectroscopy, and cyclic voltammetry as well as DFT/TDDFT was also used to interpret the results. All the complexes have intense absorption in the range of up to 700 nm, the triplet nature of the excited state was confirmed by measurement of luminescence decay.

Influence of Ligand Environment Stoichiometry on NIR-Luminescence Efficiency of Sm, Pr and Nd Ions Coordination Compounds.

Six new complexes of the ligand HQ (-4-(cyclohexanecarbonyl)-5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one) and Ln ions with emission in the near-infrared (Nd) or visible and near-infrared (Sm, Pr) spectral regions were synthesized and characterized using various methods, including single crystal X-ray diffraction. The study demonstrated that both tris complexes [LnQ(HO)(EtOH)] and tetrakis-acids [HO][LnQ] can be synthesized by varying the synthetic conditions. The photochemical properties of the complexes were investigated experimentally and theoretically using various molecular spectroscopy techniques and Judd-Ofelt theory.

Pseudo-Qutrit Formed by Two Interacting Identical Spins (s = 1/2) in a Variable External Magnetic Field.

An analytical solution is obtained for the problem of two interacting, identical but separated spin 1/2 particles in a time-dependent external magnetic field, in a general case. The solution involves isolating the pseudo-qutrit subsystem from a two-qubit system. It is shown that the quantum dynamics of a pseudo-qutrit system with a magnetic dipole-dipole interaction can be described clearly and accurately in an adiabatic representation, using a time-dependent basis set.