Formation and biotoxicity of environmentally persistent free radicals in steelworks soil under thermal treatment.

Thermal treatment are commonly used to address organic contaminated soils. In particular, the pyrolysis of organic substances can result in the creation of environmentally persistent free radicals (EPFRs). We investigated a steelworks site in Chongqing (China) to observe changes in EPFRs before and after thermal treatment.

Variations of different PAH fractions and bacterial communities during the biological self-purification in the soil vertical profile.

Wild PAH-contaminated sites struggle to provide continuous and stable monitoring, resulting in the potential risks of contaminated soil utilization could not be evaluated effectively. This work provided a 9-months laboratory simulation which was close to the natural ecological process. These results believed that PAH-degrading bacteria (PDB) preferred to degrade organic extracted PAH (PAH_OS) and fresh bound-PAH (79.

Distribution of bound-PAH residues and their correlations with the bacterial community at different depths of soil from an abandoned chemical plant site.

The situ pollutant residue and microbial characteristics in contaminated environments are crucial for ecological restoration and soil utilization. This work reported the variation of polycyclic aromatic hydrocarbon (PAH) residues and the bacterial community at different depths in an aged-abandoned site. These results unveiled that over 90% of low molecular weight (LMW) and medium molecular weight (MMW), 52.

Enhanced transformation capability towards benzo(a)pyrene by Fe(III)-modified manganese oxides.

Manganese oxides (Mn oxides) are ubiquitous and may coexist with Fe(III) ions in soil environments. In this study, acid birnessite, alkaline birnessite, cryptomelane, pyrolusite, manganite, and their Fe(III)-modified analogues were synthesized and used for benzo(a)pyrene transformation. Fe-modified Mn oxides show a markedly enhanced transformation capability towards benzo(a)pyrene.

Formation of environmentally persistent free radicals from photodegradation of triclosan by metal oxides/silica suspensions and particles.

Metal oxides play an essential role in the photocatalysis of contaminants and substantially increase in the environment by the engineering production. However, whether emerging contaminants will be produced during photocatalysis of contaminants remains unclear. Here, triclosan (TCS) photodegradation in metal oxides/silica suspensions and particles, simulated as the states of metal oxides in water and soil environments, were studied.

Humidity induces the formation of radicals and enhances photodegradation of chlorinated-PAHs on Fe(III)-montmorillonite.

Chlorinated-PAHs (ClPAHs) are widely detected in the soil surface and atmospheric particles. However, the underlying mechanisms of their photodegradation are not well understood. In the present study, the formation of radicals on ClPAHs-contaminated clay minerals was quantitatively monitored via electron paramagnetic resonance (EPR) spectroscopy, and the impact of relative humidity (RH) was systematically explored.