Optical phase matching involves establishing a proper phase relationship between the fundamental excitation and generated waves to enable efficient optical parametric processes. It is typically achieved through birefringence or periodic polarization. Here, we report that the interlayer twist angle in two-dimensional (2D) materials creates a nonlinear geometric phase that can compensate for the phase mismatch, and the vertical assembly of the 2D layers with a proper twist sequence generates a nontrivial "twist-phase-matching" (twist-PM) regime.
View Article and Find Full Text PDFNonlinear optical crystals lie at the core of ultrafast laser science and quantum communication technology. The emergence of 2D materials provides a revolutionary potential for nonlinear optical crystals due to their exceptionally high nonlinear coefficients. However, uncontrolled stacking orders generally induce the destructive nonlinear response due to the optical phase deviation in different 2D layers.
View Article and Find Full Text PDFThis study investigated the hepatoprotective effects of various mulberry ( L.) leaf extracts (MLEs), including mulberry ethanol extract (MEE), aqueous extract (MAE) and a combination extract (MCE) against D-galactosamine (D-GalN)/lipopolysaccharide (LPS)-induced acute liver injury in rats. It aimed to explore the possible molecular mechanism of the liver-protecting function of mulberry leaves and provide a reference for choosing the appropriate extraction method.
View Article and Find Full Text PDFIn crystal engineering, it is an effective and controllable approach to modify the electronic band structure and optimize crystal performances using rational chemical cosubstitution in a classic structure model. Herein, the noncentrosymmetric (NCS) rare-earth borate fluoride LaBOF was designed and synthesized successfully based on the extraordinarily stable MBOX (M = Ca, Sr, Ba, Sn, Pb, and Eu; X = Cl, Br, and I) template. Moreover, all 70 rare-earth borate halides were discussed, and the ratio of crystallization in NCS group is only 17.
View Article and Find Full Text PDFMaximizing the optical anisotropy in birefringent materials has emerged as an efficient route for modulating the polarization-dependent light propagation. Currently, the generation of deep-ultraviolet (deep-UV) polarized light below 200 nm is essential but challenging due to the interdisciplinary significance and insufficiency of high-performing birefringent crystals. Herein, by introducing multiple heteroanionic units, the first sodium difluorodihydroxytriborate-boric acid Na[B O F (OH) ]⋅[B(OH) ] has been characterized as a novel deep-UV birefringent crystal.
View Article and Find Full Text PDFBackground: Camellia sinensis 'Huangjinju' is an albino tea variety developed recently in China. Young leaves of 'Huangjinju' demonstrate bright yellow when cultivated under natural sunlight, but regreens under reduced light intensity. To elucidate the physiological and molecular mechanisms of this light-sensitive albinism, we compared leaf pigmentation, metabolites, cellular ultrastructure and transcriptome between plants cultured under natural sunlight and shade.
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