Insights into sulfur migration and transformation during the magnetization roasting of iron tailings and textile dyeing sludge.

Magnetization roasting of iron tailings (IT) is an effective method to recovery fine iron concentrate (IC) from refractory IT. However, the migration and transformation of sulfur during the roasting process remain unclear, impacting iron quality if sulfur content exceeds the allowable limit value. This study investigates the sulfur release and fixation during magnetization roasting of textile dyeing sludge (TDS) and IT, elucidating the sulfur migration and transformation processes.

The enrichment and transformation mechanism of Pb and Cu in suspension magnetization roasting and magnetic separation from iron tailings.

Magnetic iron concentrate (MIC) and nonmagnetic tailings (NT) are obtained from magnetization roasting of iron tailings (IT). MIC containing Pb adversely affects blast furnace ironmaking, while Cu in NT poses leaching risks. This study utilizes fast pyrolysis-suspension magnetization roasting to recover iron from IT.

Isomer-specific analysis of nonylphenol and their transformation products in environment: A review.

Nonylphenols (NPs) are crucial fine chemicals widely employed in producing industrial and consumer surfactants that ultimately enter the environment through various pathways, leading to environmental pollution. NPs are suspected endocrine-disrupting chemicals that may accumulate in the body over time, resulting in unusual reproductive function. Due to limitations in analytical methods, NPs have typically been quantified as a whole in some studies.

Oxidation of simulated wastewater by Fe-catalyzed system: The selective reactivity of chlorine radicals and the oxidation pathway of aromatic amines.

Aromatic amines (AAs), a characteristic pollutant with electron-donating groups in textile industry, having high reactivity with reactive chlorine free radicals, is probably the precursor of chlorinated aromatic products in advanced oxidation treatment. In this study, Fe2+/peroxydisulfate (PDS)/Cl- and Fe2+/H2O2/Cl-systems were used to treat four kinds of AAs (5-Nitro-o-toluidine (NT), 4-Aminoazobenzol (AAB), O-Aminoazotoluene (OAAT), 4,4'-Methylene-bis(2-chloroaniline) (MBCA)) in simulated wastewater, and the selectivity of various reactive species to AAs, the oxidation law and pathway of AAs were explored. The results showed that dichloride anion radical (Cl2·-) could effectively oxidize four AAs, and chlorine radical (·Cl) was strongly reactive to AAB and MBCA, especially MBCA.

Recovery of iron from iron tailings by suspension magnetization roasting with biomass-derived pyrolytic gas.

A major industrial solid waste, iron tailings occupy a large area and pose long-term pollution risks. The pyrolysis gas of biomass was used as reducing agent to suspension magnetize and roast iron tailings to recover iron in this study. The process conditions, phase transformation and microstructure evolution of the iron tailings, pyrolysis gas production, and reaction regulations were investigated to explain the mechanism of iron recovery by suspension magnetization roasting (SMR) under the action of biomass pyrolysis gas.

Formation of organic chloride in the treatment of textile dyeing sludge by Fenton system.

In the oxidation treatment of textile dyeing sludge, the quantitative and transformation laws of organic chlorine are not clear enough. Thus, this study mainly evaluated the treatment of textile dyeing sludge by Fenton and Fenton-like system from the aspects of the influence of Cl, the removal of polycyclic aromatic hydrocarbons (PAHs) and organic carbon, and the removal and formation mechanism of organic chlorine. The results showed that the organic halogen in sludge was mainly hydrophobic organic chlorine, and the content of adsorbable organic chlorine (AOCl) was 0.

Biomass waste as a clean reductant for iron recovery of iron tailings by magnetization roasting.

The magnetization roasting with coal as primary reductants adds cost and causes environmental pollution. Therefore, it is of great importance to investigate the biomass application as a reductant for magnetization roasting to recover iron from low-utilization iron tailings for emission mitigation and green utilization. This study systematically investigated the impact of biomass (pyrolysis gas from agricultural and forestry waste) as a reductant on the conversion of iron tailings to magnetite in magnetization roasting.

Redox properties of nano-sized biochar derived from wheat straw biochar.

Nano-sized biochar (NBC) has received increasing attention due to its unique physicochemical characteristics and environmental behaviour, but an understanding of its redox properties is limited. Herein, the redox properties of NBC derived from wheat straw were investigated at two pyrolysis temperatures (400 and 700 °C). These NBC materials were prepared from bulk-biochar by grinding, ultrasonication and separation treatments.

Nitrogen-enriched micro-mesoporous carbon derived from polymers organic frameworks for high-performance capacitive deionization.

Nitrogenization is an effective method for improving the capacitive deionization (CDI) performance of porous carbon materials. In particular, polymer organic frameworks with heteroatom doping, containing an ordered pore structure and excellent electrochemical stability, are ideal precursors for carbon materials for high-performance CDI. In this study, a nitrogen-enriched micro-mesoporous carbon (NMC) electrode was fabricated by carbonizing a Schiff base network-1 at 500, 600, and 700 °C.

Treatment of simulated textile sludge using the Fenton/Cl system: The roles of chlorine radicals and superoxide anions on PAHs removal.

The main content of this work is to investigate the removal of polycyclic aromatic hydrocarbons (PAHs: phenanthrene, anthracene, and fluoranthene) from simulated sludge solid phase employing an Fenton/Cl system under various Cl contents and pH values. The steady-state concentrations of the hydroxyl, chlorine, and dichloride anion radicals ([·OH], [·Cl], and [Cl]) in heterogeneous system were first measured using tert-butanol, nitrobenzene, and benzoic acid. The outcomes exhibited that increasing the Cl content from 50 to 2000 mg/L (pH = 3.

Simultaneous reduction of antibiotics and antibiotic resistance genes in pig manure using a composting process with a novel microbial agent.

In recent years, in order to promote animal growth and reduce the risk of disease, a variety of antibiotics are frequently added to the animal feed of livestock and poultry. However, these antibiotics can not be fully digested by animals and most of them are excreted with feces, consequently causing the enrichment of antibiotic resistance genes (ARGs) and huge environmental risks. Nowadays, composting is a better option to solve these problems.

Comparison of the Fe/HO and Fe/PMS systems in simulated sludge: Removal of PAHs, migration of elements and formation of chlorination by-products.

In this study, polycyclic aromatic hydrocarbons (PAHs) at practical concentrations in the simulated sludge treated by the Fe/HO and Fe/peroxymonosulfate (PMS) systems were evaluated in terms of the PAHs (phenanthrene, anthracene, fluoranthene) removal, element migration, Cl effect, and chlorination by-product formation. The results indicated that according to the removal rate of PAHs, the optimal dosage of the Fe/PMS system (∑PAHs removal rate was 64.66 ± 2.

Current situation and forecast of environmental risks of a typical lead-zinc sulfide tailings impoundment based on its geochemical characteristics.

The potential environmental implications of a Pb (Lead)-Zn (Zinc) sulfide tailing impoundment were found to be dependent on its geochemical characteristics. One typical lead-zinc sulfide tailing impoundment was studied. Ten boreholes were set with the grid method and 36 tailings were sampled and tested.

Ion-exchange polymers modified bacterial cellulose electrodes for the selective removal of nitrite ions from tail water of dyeing wastewater.

Ion-exchange polymer and modified carbonization bacterial cellulose (CBC) electrodes were fabricated using varying amounts of cation-exchange polymers (glutaric acid (GA) and sulfosuccinic acid (SSA)) and assembled within an asymmetric capacitive deionization unit (p-CDI). The performance of selective NO electro-adsorption was studied. The AC/CBC-SSA group showed a better salt adsorption capacity (14.

Algal toxicity induced by effluents from textile-dyeing wastewater treatment plants.

This research aimed to evaluate the alga Scenedesmus obliquus toxicity induced by textile-dyeing effluents (TDE). The toxicity indicator of TDE in alga at the physiological (algal growth), biochemical (chlorophyll-a (Chl-a) synthesis and superoxide dismutase (SOD) activity) and structural (cell membrane integrity) level were investigated. Then we further study the relationship among toxicity indicators at physiological and biochemical level, and supplemented by research on algal biomacromolecules.

Chlorobenzene levels, component distribution, and ambient severity in wastewater from five textile dyeing wastewater treatment plants.

Chlorobenzenes (CBs) present in synthetic dyes are discharged into natural waters during the treatment of textile dyeing wastewater, which may have adverse effects on human and environment. In this study, the existence and removal of 12 CBs in different units of five treatment plants were examined. The ecological risk of CBs in textile dyeing wastewater was assessed by ambient severity (AS) and risk quotients (RQs).

Peptide-induced super-assembly of biocatalytic metal-organic frameworks for programmed enzyme cascades.

Despite the promise of metal-organic frameworks (MOFs) as functional matrices for enzyme stabilization, the development of a stimulus-responsive approach to induce a multi-enzyme cascade reaction in MOFs remains a critical challenge. Here, a novel method using peptide-induced super-assembly of MOFs is developed for programmed enzyme cascade reactions on demand. The super-assembled MOF particles containing different enzymes show remarkable 7.

Consequence of replacing nitrogen with carbon dioxide as atmosphere on suppressing the formation of polycyclic aromatic hydrocarbons in catalytic pyrolysis of sawdust.

This study evaluates the effect of replacement of N with CO as atmosphere in catalytic pyrolysis of waste lignocellulosics with acidic and metal-modified zeolites, respectively, on the 16 EPA priority pollutant polycyclic aromatic hydrocarbons (PAHs) in bio-oils. By coupling solid phase extraction pretreatment with single ion monitoring detection, it is found that the replacement alleviates PAHs in bio-oil concerning synchronously abating the 16 PAHs with low, medium and high molecular weights, and the benzo[a]pyrene equivalent toxicity of bio-oil decreases. Meanwhile, CO decreases the content of small oxygenates, e.

Effect of sintering temperature on mineral composition and heavy metals mobility in tailings bricks.

In this study, the mixing mechanism and phase transition process of different metals during the sintering of tailings bricks with four different metal oxides (CuO, PbO, ZnO, and CdO) at temperatures ranging from 700 to 1100 °C for 2 h were investigated. The properties of the sintered product was characterized and analyzed, and the results showed that the main crystalline phases are quartz, cristobalite, hematite, and mullite while the metal oxides are ascribed to copper ferrite spinel (CuFeO), gahnite (ZnAlO), zinc ferrite spinel (ZnFeO), lead feldspar (PbAlSiO), and cadmium feldspar (CdAlSiO). Further analysis indicates that the heavy metals were transited into spinel or silicate structures with favorable efficiency.

Treatment of 3,3'-dimethoxybenzidine in sludge by advance oxidation process: Degradation products and toxicity evaluation.

Studies on the oxidation products of organic pollutants and their toxicity in textile dyeing sludge after the sludge was treated by the advance oxidation processes were limited, since textile dyeing sludge was a complicated mixture. For the first time, simulated sludge was used to study the degradation mechanism of 3,3'-dimethoxybenzidine (DMB) during the combined ultrasound-Mn(VII) treatment. The toxicity of DMB and its products was also evaluated.

Treatment of a simulated sludge by ultrasonic zero-valent iron/EDTA/Air process: Interferences of inorganic salts in polyaromatic hydrocarbon removal.

Understanding the occurrence states of persistent organic pollutants such as polycyclic aromatic hydrocarbons (PAHs) in textile dyeing sludge is the key to their further treatment and disposal. Here, the effects of inorganic salts (silicate, sulfate, phosphate, hydroxide, and iron salts) that were typically rich in textile dyeing sludge on PAH adsorption by sludge and PAH degradation by an ultrasound (US) combined zero-valent iron/EDTA/Air (ZEA) system were studied in a simulated sludge system. The results showed that the simulated sludge containing inorganic salts had a larger specific surface area, which was beneficial for the adsorption of PAHs.

Sono-advanced Fenton-like degradation of aromatic amines in textile dyeing sludge: efficiency and mechanisms.

In this paper, a novel strategy integrating ultrasound (US) with a Fenton-like (zero-valent iron/EDTA/air, ZEA) process was proposed for the removal of the refractory and carcinogenic aromatic amines (AAs) in textile dyeing sludge for the first time. The operating condition was optimized as 1.08 W/cm ultrasonic density, 15 g/L ZVI, and 1.

The agricultural use potential of the detoxified textile dyeing sludge by integrated Ultrasound/Fenton-like process: A comparative study.

Enhancing industrial sludge detoxification is of scientific and practical significance in confronting urban development and stringent environmental regulations. A strategy combining ultrasound (US) with the zero-valent iron/EDTA/Air (ZEA) process was proven to be eco-friendly, being efficient in the removal of toxic compounds from textile dyeing sludge in our previous studies. In this paper, therefore, the detoxification effects of three advanced oxidation processes (US, ZEA, US/ZEA) on textile dyeing sludge were comparatively evaluated for the first time through alteration of the sludge's physico-chemical parameters (e.

Enhanced oxytetracycline removal coupling with increased power generation using a self-sustained photo-bioelectrochemical fuel cell.

Photo-bioelectrochemical fuel cell (PBFC) represents a promising technology for enhancing removal of antibiotic pollutants while simultaneously sustainable transformation of organic wastes and solar energy into electricity. In this study, simultaneous antibiotic removal and bioelectricity generation were investigated in a PBFC with daily light/dark cycle using oxytetracycline (OTC) as a model compound of antibiotic. The specific OTC removal rate increased by 61% at an external resistance of 50 Ω compared to that in the open-circuit control, which was attributed to bioelectrochemically enhanced co-metabolic degradation in the presence of the bioanode.