Constructing a bilayer structure has not been reported as a method to mitigate the adverse effect of water poisoning on oxide chemiresistors while simultaneously enhancing gas selectivity and sensitivity. To address this challenge, pyrochlore-BiSnO has been first utilized as an overlayer on a ZnO sensing layer for constructing a bilayer acetone chemiresistor, leading to remarkable improvement in the performance for trace-level (500 p-p-b) acetone detection under high humidity (80% relative humidity). In addition, owing to the catalytic predecompositions of ethanol across the overlayer, an outstanding acetone gas selectivity (/ = 2.
View Article and Find Full Text PDFHerein, the few-layer TiCT nanosheets loaded zeolitic imidazolate framework-67 nanoplates (TiCT-ZIF-67) with a unique structure has been synthesized by surfactant control method, and then is employed as the core of precursor. A thin layer of polydopamine as the shell of precursor covered TiCT-ZIF-67 forms a micro-nano reactor, leading to the confinement carbonization process. Consequently, a novel sensing material that few-layer TiCT nanosheets loaded Co nanoparticles coated N-doped carbon (TiCT-Co@NC) is obtained for the non-enzymatic determination of glucose.
View Article and Find Full Text PDFIt is critical to identify and detect hazardous, flammable, explosive, and poisonous gases in the realms of industrial production and medical diagnostics. To detect and categorize a range of common hazardous gasses, we propose an attention-based Long Short term memory Full Convolutional network (ALSTM-FCN) in this paper. We adjust the network parameters of ALSTM-FCN using the Sparrow search algorithm (SSA) based on this, by comparison, SSA outperforms Particle Swarm Optimization (PSO) Algorithm, Genetic Algorithm (GA), Gray Wolf Optimization (GWO) Algorithm, Cuckoo Search (CS) Algorithm and other traditional optimization algorithms.
View Article and Find Full Text PDFUnderstanding the effect of substitutional doping on gas-sensing performances is essential for designing high-activity sensing nanomaterials. Herein, formaldehyde sensors based on gallium-doped InO inverse opal (IO-(Ga In)O) microspheres were purposefully prepared by a simple ultrasonic spray pyrolysis method combined with self-assembled sulfonated polystyrene sphere templates. The well-aligned inverse opal structure, with three different-sized pores, plays the dual role of accelerating the diffusion of gas molecules and providing more active sites.
View Article and Find Full Text PDFJ Colloid Interface Sci
October 2018
Yolk-shell nanomaterials with controlled morphology have received great attention because of their promising applications in gas sensing. Here, we reported the facile synthesis of pure and 1-5 mol% Sn doped CoO yolk-shell nanostructures by calcinating the Co based metal-organic framework (MOF, ZIF-67) prepared from hydrothermal method. The morphologies of the as-obtained samples were characterized by various experimental techniques.
View Article and Find Full Text PDFThe lower gas sensitivity, humidity dependence of the gas sensing properties, and long recovery times of room-temperature gas sensors severely limit their applications. Herein, to address these issues, a series of 3D inverse opal (IO) InO-ZnO heterogeneous composite microspheres (HCMs) are fabricated by ultrasonic spray pyrolysis (USP) employing self-assembled sulfonated polystyrene (S-PS) spheres as a sacrificial template. The 3D IO InO-ZnO HCMs possess highly ordered 3D inverse opal structures and bimodal (meso-scale and macro-scale) pores, which can provide large accessible surface areas and rapid mass transfer, resulting in enhanced gas sensing characteristics.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2018
In this work, ethanol gas sensor with high performance was fabricated successfully with hierarchical CoO/SnO heterojunction by two-steps hydrothermal method. The response value of CoO/SnO sensor is up to 145 at 250 °C when exposed to 100 ppm ethanol gas, which is much higher than that (13.5) of SnO sensor.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2018
The great demand for gas sensors in practical applications has stimulated tremendous attention in this area due to its important significance in real life. A facile synthesis of WO nanoplates and their subsequent Sn doping strategy by using a hydrothermal method was investigated to enhance gas sensing performance for NO gas, one of the gases toxic to human beings and the environment. Various techniques were used to characterize all the products.
View Article and Find Full Text PDFIndium tungsten oxide ellipsoidal nanospheres were prepared with different In/W ratios by using a simple hydrothermal method without any surfactant for the first time. Sensors based on different In/W ratios samples were fabricated, and one of the samples exhibited better response to methanol compared with others. High content of defective oxygen (Ov) and proper output proportion of In to W might be the main reasons for the better gas sensing properties.
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