Effect of biodegradable microplastics and Cd co-pollution on Cd bioavailability and plastisphere in soil-plant system.

Biodegradable plastics (BPs) are regarded as ecomaterials and are emerging as a substitute for traditional non-degradable plastics. However, the information on the interaction between biodegradable microplastics (BMPs) and cadmium (Cd) in agricultural soil is still limited. Here, lettuce plants were cultured in BMPs (polylactic acid (PLA) MPs and poly(butylene-adipate-co-terephthalate) (PBAT) MPs) and Cd co-polluted soil for 35 days.

Water-dependent effects of biodegradable microplastics on arsenic fractionation in soil: Insights from enzyme degradation and synchrotron-based X-ray analysis.

The abundance of biodegradable microplastics (BMPs) is increasing in soil due to the widespread use of biodegradable plastics. However, the influence of BMPs on soil metal biogeochemistry, especially arsenic (As), under different water regimes is still unclear. In this study, we investigated the effects of two types of BMPs (PLA-MPs and PBAT-MPs) on As fractionation in two types of soils (black soil and fluvo-aquic soil) under three water regimes including drying (Dry), flooding (FL), and alternate wetting and drying (AWD).

Organic matters adsorbed on goethite inhibited the heterogeneous aggregation and adsorption of CdSe quantum dots: Experiments and extended DLVO theory.

The widespread use of Cd-based quantum dots (Cd-QDs) has led to their inevitable release into the environment, and the prevalent iron oxides and natural organic matter (NOM) are the key factors affecting the environmental behavior and fate of Cd-QDs. However, the impact of NOM adsorbed on iron oxides on the behavior of Cd-QDs with iron oxides and the mechanism of its interaction are not clear. In this study, two kinds of water-soluble QDs (CdSe QDs and core-shell CdSe/ZnS QDs) were selected to study the aggregation and adsorption behavior on goethite (Goe) and goethite-humic acid/fulvic acid composites (Goe-HA/FA).

Microplastics alter Cr accumulation and fruit quality in Cr(VI) contaminated soil-cucumber system during the lifecycle: Insight from rhizosphere bacteria and root metabolism.

Both microplastics and Cr(VI) potentially threaten soil and crops, but little is known about their interaction in the soil-plant system. This study investigated the effect and mechanism of polyethylene (PE), polyamide (PA), and polylactic acid (PLA) microplastics on Cr bioaccumulation and toxicity in a Cr(VI) contaminated soil-cucumber system during the lifecycle. The results show that microplastics had a greater effect on Cr accumulation in cucumber roots, stems, and leaves than in fruits.

Response mechanism of lettuce (Lactuca sativa L.) under combined stress of Cd and DBDPE: An integrated physiological and metabolomics analysis.

DBDPE and Cd are representative contaminants commonly found in electronic waste (e-waste), which tend to be gradually discharged and accumulated in the environment during e-waste dismantling, resulting in frequent outbreaks and detection of these pollutants. The toxicity of both chemicals to vegetables after combined exposure has not been determined. The accumulation and mechanisms of phytotoxicity of the two compounds, alone and in combination, were studied using lettuce.

Effect of polyethylene, polyamide, and polylactic acid microplastics on Cr accumulation and toxicity to cucumber (Cucumis sativus L.) in hydroponics.

Microplastics (MPs) in farmland soil may affect the environmental fate and toxicity of heavy metals; however, how non-biodegradable and biodegradable MPs change the accumulation and phytotoxicity of Cr(VI) to the plants is still unknown. In this study, we explored the impacts of Cr(VI) concentrations (0, 20, 50, 100, 200, and 500 μmol/L), MP types (polyethylene (PE), polyamide (PA), and polylactic acid (PLA)), sizes (13, 48, and 500 µm), and concentrations (40, 200, and 1000 mg/L) on the Cr accumulation and toxicity to cucumber (Cucumis sativus L.) under hydroponic conditions for 14 days.

Polyamide microplastics as better environmental vectors of Cr(VI) in comparison to polyethylene and polypropylene microplastics.

The adsorption, desorption, and their influence factors of Cr(VI) by microplastics (MPs) in the solution was investigated in this study. The results demonstrated that UV aging promoted adsorption, while the increase of salinity and natural organic matter (NOM) inhibited adsorption. The particle size affected the total Cr(VI) active adsorption sites on MPs, while the pH changed the electrostatic force.

Simultaneous stabilization of Pb, Cd, and As in soil by rhamnolipid coated sulfidated nano zero-valent iron: Effects and mechanisms.

Sulfidation effectively improves the electron transfer efficiency of nanoscale zero-valent iron (nZVI), but decreases the specific surface area of nZVI. In this study, sulfidated nZVI (S-nZVI) coated with rhamnolipid (RL-S-nZVI) was synthesized and used to stabilize Pb, Cd, and As in combined polluted soil. The stabilization efficiency of 0.

Exogenous iron alters uptake and translocation of CuO nanoparticles in soil-rice system: A life cycle study.

The abundant iron in farmland soil may affect the environmental fate of metal-based nanoparticles (MNPs). In this study, the effect of FeSO and nano-zero-valent iron (nZVI) as exogenous iron on the uptake and translocation of CuO nanoparticles (NPs) in soil-rice system was performed in a life cycle study. The results show that exogenous iron basically elevated the soil pH and electrical conductivity but lowered the redox potential.