Fabrication of microplastic-free biomass-based masks: Enhanced multi-functionality with all-natural fibers.

With the coronavirus-2019 epidemic, disposable surgical masks have become a common personal protective necessity. However, off-the-shelf masks have low filtration efficiency and short service life and can only physically isolate pathogens, easily leading to secondary infection and cross-infection between users. Additionally, they produce debris and microplastics, which can be inhaled by the human body and cause serious diseases.

Locally Injectable, ROS-Scavenging, and ROS-/pH-Responsive Polymeric-Micelles-Embedded Hydrogels for Precise Minimally Invasive and Long-Lasting Rheumatoid Therapy.

Rheumatoid arthritis (RA) is a chronic autoimmune disease characterized by synovitis, bone-erosion, and joint-destruction. Here, we developed a locally injectable, ROS-scavenging, and ROS-/pH-responsive drug-delivery platform (HC@PTM) by bio-compositing of aldolizing hyaluronic acid (HA) crosslinked with chitosan (CS), and ROS-triggered/eliminated micelles (PTM) coupled with the drug methotrexate(MTX). The PTM efficiently eradicate excessive ROS in RA-joints, precisely triggering drug-release within inflamed arthritic-sites and further confer exceptional antioxidant origins to HC@PTM.

Engineered environment-friendly multifunctional food packaging with superior nonleachability, polymer miscibility and antimicrobial activity.

This study was conducted primarily to develop an environment-friendly food packaging boasting several advantages, including good water vapor barrier, UV resistance, antimicrobial activity, non-leachability, and polymer miscibility. Initially, the starch-based antimicrobial agent (OCSI) was synthesized through a simple esterification reaction between oxidized corn starch (OCS) and indoleacetic acid (IAA). Subsequently, OCSI was further blended separately with environmentally-friendly materials (PVA, PBAT, PCL), and a series of environment-friendly packaging films were successfully prepared.

Leather-Based Shoe Soles for Real-Time Gait Recognition and Automatic Remote Assistance Using Machine Learning.

Real-time monitoring of gait characteristics is crucial for applications in health monitoring, patient rehabilitation feedback, and telemedicine. However, the effective and stable acquisition and automatic analysis of gait information remain significant challenges. In this study, we present a flexible sensor based on a carbon nanotube/graphene composite conductive leather (CGL), which uses collagen fiber with a three-dimensional network structure as the flexible substrate.

Preparation of natural adhesives with high-strength and low temperature fast-curing properties.

The development of natural adhesives to substitute petroleum-based products is crucial for sustainable progress. However, the bond strength of most existing natural adhesives still falls short of that of commercially available adhesives and the curing process often demands prolonged high-temperature treatment. Herein, we prepared pure natural adhesives using gelatin (GE), tung oil (TO), and dopamine (DA) as the main raw materials.

2-dimensional impact-damping electrostatic actuators with elastomer-enhanced auxetic structure.

Biomimetic robots yearn for compliant actuators that are comparable to biological muscle in both functions and structural properties. For that, electrostatic actuators have been developed to imitate bio-muscle in features of fast response, high power, energy-efficiency, etc. However, those actuators typically lack impact damping performance, making them vulnerable and unstable in real applications.

Nanoengineered Nonenzymatic Paper-Based Fluorescent Platform for Pre-Dilution-Free and Visual Real-Time Home Monitoring of Urea for Early Warning of Abnormal Nitrogen-Based Unhealthy Issues.

Distorted urea levels indicate several liver, kidney, or metabolic diseases; however, traditional clinical urea detection relies on urease-based methods enslaved to well-known limitations of high-price, unstable properties, complicated sample pretreatment and analysis procedures, and difficult visual real-time monitoring. Herein, nonenzymatic paper-based fluorescent materials (UFP-BP) are strategically integrated with an on-demand fluorescent-sensor (UFP) self-aggregated nanoparticle on commercial filter paper for pre-dilution-free and visual real-time urea monitoring. The UFP is synthesized and self-aggregated into the fluorescent nanoparticles for selective urea recognition.

Progress in synthesis, modification, characterization and applications of hyperbranched polyphosphate polyesters.

Hyperbranched polyphosphate polyesters (HPPs) as a special class of hyperbranched polymers have attracted increased interest and have been intensively studied, because of peculiar structures, excellent biocompatibility, flexibility in physicochemical properties, biodegradability, water soluble, thermal stability, and mechanical properties. HPPs can be divided into phosphates as monomers and phosphates as end groups. In this article, the classification, general synthesis, modifications, and applications of HPP are reviewed.

Advances in the preparation and application of cellulose-based antimicrobial materials: A review.

The rise of polymer materials in modern life has drawn attention to renewable, easily biodegradable, environmentally-friendly bio-based polymers. Notably, significant research has been dedicated to creating green antimicrobial functional materials for the biomedical field using natural polymer materials. Cellulose is a rich natural biomass organic polymer material.

One-step approach to fabricating amphoteric polymer fatliquors for chrome-free tanned leather eco-manufacturing.

The leather manufacturing industry is increasingly embracing chrome-free tanning methods to promote environmental sustainability. However, the transition to chrome-free tanning systems presents a notable obstacle: the incompatibility of traditional anionic wet finishing materials with chrome-free tanned leather due to differences in surface electrical behavior. Herein, an amphoteric polymer, referred to P(AA-co-DMAEMA-co-DA), was synthesized through a simple one-step free radical copolymerization using acrylic acid (AA), dimethylaminoethyl methacrylate (DMAEMA), and dodecyl acrylate (DA).

Discarded enoki mushroom root-derived multifunctional chrome-free chitosan-based tanning agent for eco-leathers manufacturing: Tanning-dyeing, non-acid soaking, and non-basifying.

The aim of this study was to develop new discarded enoki mushroom root-derived multifunctional chrome-free chitosan-based tanning agents that can be used for eco-leather manufacturing. In this study, oligochitosan (OCS) was prepared from chitosan extracted from the enoki mushrooms and chemically modified using reactive dye R19 and epichlorohydrin (ECH) to prepare chromium-free tanning agent (OCS-R19-ECH) with both tanning and dyeing functions. FT-IR, XRD, and NMR (H) confirmed the successful synthesis of the product.

Extraction of chitin from flammulina velutipes waste: A low-concentration acid pretreatment and aspergillus Niger fermentation approach.

In recent years, with the booming of the edible mushroom industry, chitin production has become increasingly dependent on fungi and other non-traditional sources. Fungal chitin has advantages including superior performance, simpler separation processes, abundant raw materials, and the absence of shellfish allergens. As a kind of edible mushroom, flammulina velutipes (F.

Reversible immobilization of cellulase on gelatin for efficient insoluble cellulose hydrolysis.

Immobilized enzymes are one of the most common tools used in enzyme engineering, as they can substantially reduce the cost of enzyme isolation and use. However, efficient catalysis of solid substrates using immobilized enzymes is challenging, hydrolysis of insoluble cellulose by immobilized cellulases is a typical example of this problem. In this study, inspired by bees and honeycombs, we prepared gelatin-modified cellulase (BEE) and gelatin hydrogels (HONEYCOMB) to achieve reversible recycling versus release of cellulase through temperature-responsive changes in the triple-stranded helix-like interactions between BEE and HONEYCOMB.

Biocompatible and Biodegradable 3D Graphene/Collagen Fiber Hybrids for High-Performance Conductive Networks and Sensors.

Polymer-based flexible conductive materials are crucial for wearable electronics, electronic skin, and other smart materials. However, their development and commercial applications have been hampered by the lack of strain tolerance in the conductive network, poor bonding with polymers, discomfort during wear, and a lack of biocompatibility. This study utilized oil-tanned leather with a natural network structure, high toughness, and high tensile deformation recovery as a structural template.

Atomic-scale Ru anchored on chromium-shavings as a precursor for a pH-universal hydrogen evolution reaction electrocatalyst.

In the leather manufacturing industry, the management of substantial quantities of solid waste containing chrome shavings remains a formidable challenge. Concurrently, there is a pressing need for the development of pH-universal and economically viable electrocatalysts for the hydrogen evolution reaction (HER). In response to these intertwined challenges, this study proposes an innovative approach wherein the amino groups present on the surface of chrome shavings are utilized to immobilize single ruthenium atoms during pyrolysis, thereby facilitating the synthesis of hydrogen evolution electrocatalysts.

New plant polyphenol-derived tannic acid-based chromium-free tanning agent for sustainable and clean leather production.

This study aimed to prepare a new bio-based chromium-free tanning agent. The green epoxide monocase ethylene glycol diglycidyl ether (EGDE) was grafted with tannic acid (TA) derived from natural plant using the one-pot method to synthesize new plant polyphenol-derived tannic acid-based chromium-free tanning agents (TA-EGDE) with abundant terminal epoxides. FTIR, H NMR, XPS, GPC, SEM, and other analytical techniques were used to characterize tanning agents.

Biomimetic Exogenous "Tissue Batteries" as Artificial Power Sources for Implantable Bioelectronic Devices Manufacturing.

Implantable bioelectronic devices (IBDs) have gained attention for their capacity to conformably detect physiological and pathological signals and further provide internal therapy. However, traditional power sources integrated into these IBDs possess intricate limitations such as bulkiness, rigidity, and biotoxicity. Recently, artificial "tissue batteries" (ATBs) have diffusely developed as artificial power sources for IBDs manufacturing, enabling comprehensive biological-activity monitoring, diagnosis, and therapy.

Development of an activatable Lysosome-targeted fluorescent probe for the detection of endogenous ONOO levels.

The liver plays a crucial role in several important processes in the human body, including metabolism, detoxification, and immune function. When the liver experiences acute injury, it can cause significant harm and requires prompt detection. Traditional biomarkers lack specificity and cannot detect changes in real-time, making them unsuitable for monitoring pathological processes.

Engineering eco-friendly and biodegradable biomass-based multifunctional antibacterial packaging films for sustainable food preservation.

The study presents a new class of eco-friendly and biodegradable biomass-based multifunctional antibacterial packaging films (G-OCSI) based on oxidized corn starch-based nonionic biopolymer (OCSI) and gelatin (Gel), and investigates the effects of different OCSI contents on the properties of G-OCSI. The results demonstrated that G-OCSI 0.25 had good water vapor barrier properties, antioxidant activity (DPPH RSA: 85.

A temperature and pressure dual-responsive, stretchable, healable, adhesive, and biocompatible carboxymethyl cellulose-based conductive hydrogels for flexible wearable strain sensor.

The study aimed to develop a novel temperature and pressure dual-responsive conductive hydrogel with self-healing, self-adhesive, biocompatible, and stretchable properties, for the development of multifunctional anti-counterfeiting and wearable flexible electronic materials. A conductive hydrogel based on carboxymethyl cellulose (CMC) was synthesized by simple "one pot" free radical polymerization of CMC, acrylamide (AAm) and acrylic acid (AAc). The hydrogel displayed temperature responsiveness and possessed an upper critical solution temperature (UCST) value.

Eco-Friendly Cellulose-Based Nonionic Antimicrobial Polymers with Excellent Biocompatibility, Nonleachability, and Polymer Miscibility.

This study aims to prepare natural biomass-based nonionic antimicrobial polymers with excellent biocompatibility, nonleachability, antimicrobial activity, and polymer miscibility. Two new cellulose-based nonionic antimicrobial polymers (MIPA and MICA) containing many terminal indole groups were synthesized using a sustainable one-pot method. The structures and properties of the nonionic antimicrobial polymers were characterized using nuclear magnetic resonance hydrogen spectroscopy (H NMR), infrared spectroscopy (FTIR), wide-angle X-ray diffractometry (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), gel chromatography (GPC), and other analytical techniques.

High-value utilization of Cr-containing sludge: Eco-friendly and ultra-low-cost electrocatalyst for efficient OER in alkaline media from Cr-containing sludge.

Economically sustainable development requires more viable waste recycling solutions. In this context, we address the problem of utilizing chromium-containing sludge, a prevalent and environmentally hazardous waste. Meanwhile, sustainable energy development must develop ecology-friendly and low-cost electrocatalysts for the oxygen evolution reaction (OER) in alkaline media.

Engineering Self-Adaptive Multi-Response Thermochromic Hydrogel for Energy-Saving Smart Windows and Wearable Temperature-Sensing.

Buildings account for ≈40% of the total energy consumption. In addition, it is challenging to control the indoor temperature in extreme weather. Therefore, energy-saving smart windows with light regulation have gained increasing attention.

Paper-based fluorescent materials containing on-demand nanostructured brain-cells-inspired AIE self-assembles for real-time visual monitoring of seafood spoilage.

Biogenic amines containing NH are important indicators for conducting full-scale appraisal of food spoilage and disease diagnosis. However, the currently-used detection methods of NH have several limitations such as time-consuming high cost, and inability to provide visual real-time monitoring. Therefore, researchers have attempted to explore strategies for quantitative real-time monitoring of NH for food spoilage has attracted widespread attentions.