[Studies on fluorescence properties of a novel acylhydrazone ligands and its Sn metal complexes].

The molecular structure and spectral properties of a novel acylhydrazone ligands 2-hydroxy-naphthaldehyde-5-chloro-salicyloylhydrazone (H3L) and its Sn metal complexes [(n-Bu2)Sn(HL)] in solution, crystal and thin films were investigated by using steady state and time resolved fluorescence spectrum. The experimental results show that for H3L, compared with it in solution, the fluorescence intensity is enhanced as it is crystal and thin films, the fluorescence peak is red-shift, and the excited state lifetime is longer. The transition energies of the unimolecule is 240.

[Influence of substituents on Langmuir-Blodgett films and spectral properties of thulium bisphthalocyanine derivatives].

The aggregation and spectral properties of three sandwich thulium bisphthalocyanine compounds in chloroform solution and LB films were investigated by using UV-Vis absorption spectra. The experimental results indicated that the three sandwich thulium bisphthalocyanine molecules formed H-aggregates in the chloroform solution, but the absorption spectra of the three sandwich thulium bisphthalocyanine compounds display strong absorption peaks of monomer when the concentration of the sandwich thulium bisphthalocyanine solutions was 10(-7) mol x L(-1). The addition of substitutent --OC8H17 not only decreased the aggregation behaviors of the sandwich thulium bisphthalocyanine, but also leaded to red-shift of the absorption peaks, and it had a biggish influence on the intensity of absorption spectra.

[Spectrum properties of Thulium bisphthalocyanine Langmuir-Blodgett films].

The configuration state and spectral properties of sandwiched thulium bisphthalocyanine (TmPc2) molecule in Langmuir films and Langmuir-Blodgett (LB) films were investigated by using the surface pressure-area (pi-A) isotherm and UV-Vis absorption spectra. The experimental results indicated that the sandwiched thulium bisphthalocyanine molecules form well-ordered stable monolayer films on the water/air interface, and the sandwiched thulium bisphthalocyanine molecules take the face to face orientation for the macrocycles and edge-on configuration in pure films, with the collapse pressure being 56 mN x m(-1). But the sandwiched thulium bisphthalocyanine molecules take the face-on configuration in the sandwiched thulium bisphthalocyanine films mixed with arachidic acid (AA), and the collapse pressure is more than 60 mN x m(-1).