Facile Preparation of Raspberry-Like SiO@Polyurea Microspheres with Tunable Wettability and Their Application for Oil-Water Separation.

Raspberry-like microspheres have been widely used as superhydrophobic materials, photonic crystals, drug carriers, etc. Nevertheless, their preparation methods, usually consisting of multiple steps, are generally time- and energy-consuming. Herein raspberry-like SiO@polyurea microspheres (SiO@PUM) are readily prepared via a one-step precipitation polymerization of isophorone diisocyanate in a HO/acetone mixture with the presence of SiO particles.

Boosting catalytic efficiency of lipase by regulating amphiphilic microenvironment through reversible addition-fragmentation chain transfer polymerized modifications on polyacrylonitrile fiber.

Lipases are increasingly attracting attention in green and sustainable biodiesel production. Currently, the research emphasis lies in immobilizing unstable lipase onto carriers to enhance its performance. Polyacrylonitrile fiber (PANF) is considered to be a promising material for lipase immobilization due to its excellent properties.

Preparation of fluorescent polyurethane microspheres and their applications as reusable sensor for 4-nitrophenol detection and as microplastics model for visualizing polyurethane in cells and zebrafish.

Fluorescent microspheres are of significant interests due to their wide applications in biotechnology fields. However, their preparation presents several challenges, such as the need for dye labeling, the complexity of materials and often sophisticated preparation conditions. Here a simple process for hydrophilic and crosslinked polyurethane (CPU) microspheres, with carboxyl groups on the surface via one-step precipitation polymerization in 40 min, is presented.

Triple-Responsive, Multimodal, Visual Electronic Skin toward All-in-One Health Management for Gestational Diabetes Mellitus.

Gestational diabetes mellitus (GDM) is one of the most common metabolic disorders during pregnancy, leading to serious complications for pregnant women and a threat to life safety of infants. Therefore, it is particularly important to establish a multipurpose monitoring pathway to important physiological indicators of pregnant women. In this work, three kinds of double network hydrogels are prepared with poly(vinyl alcohol) (PVA), borax, and cellulose ethers with varying substituents of methyl (methyl cellulose, MC), hydroxypropyl (hydroxypropyl cellulose, HPC), or both (hydroxypropyl methyl cellulose, HPMC), respectively.

Full Green Detection of Antibiotic Tetracyclines Using Fluorescent Poly(ethylene glycol) as the Sensor and the Mechanism Study.

Tetracyclines are well-known antibiotics and widely used against a variety of bacterial infections. Their monitoring and detection have been an important issue. To this end, a vast number of methods have been developed; fluorescence sensing is one of the most reported.

Fluorescent linear polyurea based on toluene diisocyanate: Easy preparation, broad emission and potential applications.

In contrast to conventional fluorescent polymers featured by large conjugation structures, a new class of fluorescent polymers without above conjugations are gaining constant interest owing to their significant academic importance and promising applications in diverse fields. These unconventional fluorescent polymers are in general composed of heteroatoms (e.g.

Highly Uniform and Porous Polyurea Microspheres: Clean and Easy Preparation by Interface Polymerization, Palladium Incorporation, and High Catalytic Performance for Dye Degradation.

Owing to their high specific surface area and low density, porous polymer materials are of great importance in a vast variety of applications, particularly as supports for enzymes and transition metals. Herein, highly uniform and porous polyurea microspheres (PPM), with size between 200 and 500 μm, are prepared by interfacial polymerization of toluene diisocyanate (TDI) in water through a simple microfluidic device composed of two tube lines, in one of which TDI is flowing and merged to the other with flowing aqueous phase, generating therefore TDI droplets at merging. The polymerization starts in the tube while flowing to the reactor and completed therein.

Pickering Emulsion Formation of Paraffin Wax in an Ethanol-Water Mixture Stabilized by Primary Polymer Particles and Wax Microspheres Thereof.

Stable dispersions of paraffin wax droplets and their nano- and microspheres have broad applications. Despite intensive efforts, the production of uniform wax spheres remains a challenge. For their preparation, abundant surfactants and other additives are commonly used to stabilize the dispersions.