Step-by-Step Modulation of Crystalline Features and Exciton Kinetics for 19.2% Efficiency Ortho-Xylene Processed Organic Solar Cells.

With plenty of popular and effective ternary organic solar cells (OSCs) construction strategies proposed and applied, its power conversion efficiencies (PCEs) have come to a new level of over 19% in single-junction devices. However, previous studies are heavily based in chloroform (CF) leaving behind substantial knowledge deficiencies in understanding the influence of solvent choice when introducing a third component. Herein, we present a case where a newly designed asymmetric small molecular acceptor using fluoro-methoxylated end-group modification strategy, named BTP-BO-3FO with enlarged bandgap, brings different morphological evolution and performance improvement effect on host system PM6:BTP-eC9, processed by CF and ortho-xylene (o-XY).

Tunable Donor Aggregation Dominance in a Ternary Matrix of All-Polymer Blends with Improved Efficiency and Stability.

Using two structurally similar polymer acceptors in constructing high-efficiency ternary all-polymer solar cells is a widely acknowledged strategy; however, the focus thus far has not been on how polymer acceptor(s) would tune the aggregation of polymer donors, and furthermore film morphology and device performance (efficiency and stability). Herein, it is reported that matching of the celebrity acceptor PY-IT and the donor PBQx-TCl results in enhanced H-aggregation in PBQx-TCl, which can be finely tuned by controlling the amount of the second acceptor PY-IV. Consequently, the efficiency-optimized PY-IV weight ratio (0.